Mn(pyterpy)(H2O)(N3)(NO3) | 1204834-12-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Mn(pyterpy)(H2O)(N3)(NO3)
• 英文别名: Mn(4'-(4-pyridyl)-2,2':6',2''-terpyridine)(H2O)(N3)(NO3)
• CAS: 1204834-12-7
• 化学式: C₂₀H₁₆MnN₈O₄
• 分子量: 487.336
• InChiKey: LEEOMJKNAOIASU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Mn(pyterpy)(H2O)(N3)(NO3) 以 further solvent(s) 为溶剂， 生成 manganese oxide
  参考文献：
  名称：

  Synthesis and characterization of Mn3O4 nanoparticles via thermal decomposition of a new synthesized hydrogen bonded polymer

  摘要：

  A new Mn(II) compound, [Mn(pyterpy)(H2O)(N-3)(NO3)] (1) [pyterpy = 4'-(4-pyridyl)-2,2',6',2 ''-terpyridine], was synthesized by the reaction of pyterpy and mixtures of manganese(II) nitrate and sodium azide using heat gradient method. The compound I characterized by IR spectroscopy, elemental analyses and X-ray crystallography. The crystal structure of compound I was determined by single-crystal X-ray diffraction. The potentially tetradentate pyterpy ligand acts as a tridentate donor. The noncoordinated pyridyl group interacts via O-H center dot center dot N hydrogen bonds with adjacent Molecules. Mn3O4 nanoparticles were obtained by thermalyses of compound I in oleic acid at 320 degrees C under air atmosphere. The Mn3O4 nanoparticles were characterized by X-ray diffraction (XRD). scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and thermogravimetric analysis (TGA). (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.08.032
• 作为产物：
  描述：

  4'-(4-吡啶基)-2,2':6',2''-三联吡啶 、 manganese(II) nitrate 、 sodium azide 以 甲醇 为溶剂， 以50%的产率得到Mn(pyterpy)(H2O)(N3)(NO3)
  参考文献：
  名称：

  Synthesis and characterization of Mn3O4 nanoparticles via thermal decomposition of a new synthesized hydrogen bonded polymer

  摘要：

  A new Mn(II) compound, [Mn(pyterpy)(H2O)(N-3)(NO3)] (1) [pyterpy = 4'-(4-pyridyl)-2,2',6',2 ''-terpyridine], was synthesized by the reaction of pyterpy and mixtures of manganese(II) nitrate and sodium azide using heat gradient method. The compound I characterized by IR spectroscopy, elemental analyses and X-ray crystallography. The crystal structure of compound I was determined by single-crystal X-ray diffraction. The potentially tetradentate pyterpy ligand acts as a tridentate donor. The noncoordinated pyridyl group interacts via O-H center dot center dot N hydrogen bonds with adjacent Molecules. Mn3O4 nanoparticles were obtained by thermalyses of compound I in oleic acid at 320 degrees C under air atmosphere. The Mn3O4 nanoparticles were characterized by X-ray diffraction (XRD). scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and thermogravimetric analysis (TGA). (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.08.032