(R)-2-Phenyl-butyric acid tri-pyridin-4-yl-methyl ester

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (R)-2-Phenyl-butyric acid tri-pyridin-4-yl-methyl ester
• 英文别名: tripyridin-4-ylmethyl (2R)-2-phenylbutanoate
• 化学式: C₂₆H₂₃N₃O₂
• 分子量: 409.488
• InChiKey: NWIFWEZEOBSXKN-XMMPIXPASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  31
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  65
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  cis-[Pt(II)(PEt)₃(trifluoromethane-sulfonate)₂] 、 (R)-2-Phenyl-butyric acid tri-pyridin-4-yl-methyl ester 以 丙酮 为溶剂， 以91%的产率得到[((triethylphosphine)2Pt)6(1,1,1-tris(4-pyridyl)COC(O)CH(Ph)Et)4](trifluoromethylsulfonate)12
  参考文献：
  名称：

  Self-Assembly of a Nanoscopic Platinum(II) Double Square Cage

  摘要：

  Self-assembly of a rigid tripyridyl linker with a bidentate 90 degrees Pt(II) acceptor yielded a somewhat unusual double square cage, representing the first example of Pt(II) cage of such shape. Multinuclear NMR as well as single-crystal structure analysis characterized the cage.

  DOI：

  10.1021/om0701571
• 作为产物：
  描述：

  tris(4-pyridyl)methanol 、 (R)-(-)-2-phenylbutyric acid chloride 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 以25%的产率得到(R)-2-Phenyl-butyric acid tri-pyridin-4-yl-methyl ester
  参考文献：
  名称：

  Rational Design of Chiral Nanoscale Adamantanoids

  摘要：

  Utilizing coordination as a motif, the self-organization of six ditopic and four tritopic building blocks leads to the formation of nanoscale adamantanoid frameworks.

  DOI：

  10.1021/ol005781n

文献信息

• Rational Design of Chiral Nanoscale Adamantanoids
  作者：Manuela Schweiger、S. Russell Seidel、Marion Schmitz、Peter J. Stang

  DOI：10.1021/ol005781n

  日期：2000.5.1

  Utilizing coordination as a motif, the self-organization of six ditopic and four tritopic building blocks leads to the formation of nanoscale adamantanoid frameworks.
• Self-Assembly of a Nanoscopic Platinum(II) Double Square Cage
  作者：Sushobhan Ghosh、Stuart R. Batten、David R. Turner、Partha Sarathi Mukherjee

  DOI：10.1021/om0701571

  日期：2007.6.1

  Self-assembly of a rigid tripyridyl linker with a bidentate 90 degrees Pt(II) acceptor yielded a somewhat unusual double square cage, representing the first example of Pt(II) cage of such shape. Multinuclear NMR as well as single-crystal structure analysis characterized the cage.