(2-tert-Butyl-phenyl)-eth-(E)-ylidene-amine | 257953-69-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-tert-Butyl-phenyl)-eth-(E)-ylidene-amine
• 英文别名: N-(2-tert-butylphenyl)ethanimine
• CAS: 257953-69-8
• 化学式: C₁₂H₁₇N
• 分子量: 175.274
• InChiKey: FYTWTZSHRLDQCK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (2-tert-Butyl-phenyl)-eth-(E)-ylidene-amine 在 三乙胺 作用下， 以 甲苯 、 乙腈 为溶剂， 生成 N-(2-tert-Butyl-phenyl)-N-((2S,3S)-2-phenyl-oxetan-3-yl)-acetamide
  参考文献：
  名称：

  Diastereoselective photocycloaddition of an axial chiral enamide

  摘要：

  The axial chiral enamide 3 was prepared from 2-t-butylaniline in two steps (58% overall yield). Its photocycloaddition to benzaldehyde yielded the oxetane 4a as the major product (62% de), the structure of which was elucidated by single X-ray crystallography. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01933-4
• 作为产物：
  描述：

  2-叔丁基苯胺 、 乙醛 以85%的产率得到(2-tert-Butyl-phenyl)-eth-(E)-ylidene-amine
  参考文献：
  名称：

  Diastereoselective photocycloaddition of an axial chiral enamide

  摘要：

  The axial chiral enamide 3 was prepared from 2-t-butylaniline in two steps (58% overall yield). Its photocycloaddition to benzaldehyde yielded the oxetane 4a as the major product (62% de), the structure of which was elucidated by single X-ray crystallography. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01933-4

文献信息

• Diastereoselective photocycloaddition of an axial chiral enamide
  作者：Thorsten Bach、Jürgen Schröder、Klaus Harms

  DOI：10.1016/s0040-4039(99)01933-4

  日期：1999.12

  The axial chiral enamide 3 was prepared from 2-t-butylaniline in two steps (58% overall yield). Its photocycloaddition to benzaldehyde yielded the oxetane 4a as the major product (62% de), the structure of which was elucidated by single X-ray crystallography. (C) 1999 Elsevier Science Ltd. All rights reserved.