3-(4-(1,1-dimetyhlethan-1-yl)phenoxy)propane-1-thiol | 1040040-48-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(4-(1,1-dimetyhlethan-1-yl)phenoxy)propane-1-thiol
• 英文别名: 3-(4-Tert-butylphenoxy)propane-1-thiol
• CAS: 1040040-48-9
• 化学式: C₁₃H₂₀OS
• 分子量: 224.367
• InChiKey: VUIZUXWMJCYZHJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  10.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  allyl p-cymyl ether 在 盐酸 、 偶氮二异丁腈 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 40.0h， 生成 3-(4-(1,1-dimetyhlethan-1-yl)phenoxy)propane-1-thiol
  参考文献：
  名称：

  End-group-functionalized poly(N,N-diethylacrylamide) via free-radical chain transfer polymerization: Influence of sulfur oxidation and cyclodextrin on self-organization and cloud points in water

  摘要：

  在这项工作中，我们报道了基于N,N-二乙基丙烯酰胺（DEAAm）合成的热响应、氧化响应和环糊精（CD）响应末端基团官能化聚合物。在经典的自由基链转移聚合过程中，使用巯基官能化的4-烷基酚，即3-(4-(1,1-二甲基乙烷-1-基)苯氧基)丙烷-1-硫醇和3-(4-(2,4,4-三甲基戊烷-2-基)苯氧基)丙烷-1-硫醇，得到具有明确定义的疏水末端基团的聚(N,N-二乙基丙烯酰胺)（PDEAAm）。这些末端基团官能化聚合物显示不同的云点值，取决于聚合度和随机甲基化的β-环糊精（RAMEB-CD）的存在。此外，还研究了含硫醚键的氧化对云点的影响。结果表明，亲水磺氧化物在临界溶液温度（LCST）下显示更高的云点值。通过1H NMR、SEC、FTIR和MALDI-TOF测量证实了高度官能化。

  DOI：

  10.3762/bjoc.10.61

文献信息

• Method of producing magenta images in silver halide colour photographic materials
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0119741A2

  公开（公告）日：1984-09-26

  A silver halide photosensitive material is developed with a developing solution containing an aromatic amine in the presence of a coupler of the general formula: wherein R1, R2 and R3 each represents a hydrogen atom or a substituent group, and X represents a hydrogen atom or a coupling eliminable group; 46 specific couplers are shown, and four synthesis methods. An aromatic color stabilizer may be present. Magenta color image of high color purity is formed.

  用含有芳香胺的显影液在通式如下的耦合剂存在下对卤化银感光材料进行显影： 其中 R1、R2 和 R3 各代表一个氢原子或一个取代基团，X 代表一个氢原子或一个可消除偶联的基团；共显示了 46 种特定的偶联剂和四种合成方法。可能存在芳香族颜色稳定剂。形成高色纯度的品红色图像。
• Silver halide color photograhic materials
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0176804A1

  公开（公告）日：1986-04-09

  A silver halide color photographic material comprising a support having formed thereon at least one silver halide emulsion layer containing a pyrazoloazole series magenta coupler having at least one group expressed by the formula (S) below at a position other than the coupling active position. wherein A represents a substituted or unsubstituted alkylene group, a substituted or unsubstituted cycloalkylene group, a substituted or unsubstituted arylene group, or a substituted or unsubstituted aralkylene group, in which in the main chain of said alkylene group, cycloalkylene group, arylene group, or aralkylene group, -O-, -S-, -CO-, -CO2-, -OCO-, or - may be contained; L represents or B represents a hydrogen atom or a substituted or unsubstituted alkyl or aryl group which does not contain therein -SO2-; n is 0 or 1; and R and R' each represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group. In the above, in the case that the pyrazoloazole series magenta coupler is a 1H-pyrazolo[5,1-c] [1,2,4]triazole derivative, A does not represent an aralkylene group containing an arylene group directly connected to L. The silver halide color photographic light-sensitive material has improved coloring properties.

  一种卤化银彩色感光材料，它包括一个支撑体，支撑体上至少形成有一层卤化银乳剂，该层含有吡唑啉系列品红色偶联剂，该偶联剂在偶联活性位以外的位置上至少有一个由下式(S)表示的基团。 其中 A 代表取代或未取代的亚烷基、取代或未取代的环亚烷基、取代或未取代的亚芳基或取代或未取代的亚芳基，在所述亚烷基、环亚烷基、亚芳基或亚芳基的主链中，-O-、-S-、-CO-、-CO2-、-OCO-、 或 可包含； L 代表 或 B代表氢原子或取代或未取代的烷基或芳基，其中不包含-SO2-；n为0或1；R和R'各自代表氢原子、取代或未取代的烷基或取代或未取代的芳基。在上述中，在吡唑并唑系列品红色偶联剂是 1H-吡唑并[5,1-c] [1,2,4]triazole 衍生物的情况下，A 不代表含有与 L 直接连接的芳烷基的芳烷基。
• Silver halide color photographic materials
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0217353A2

  公开（公告）日：1987-04-08

  A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, said silver halide emulsion layer containing a pyrazoloazole series magenta coupler represented by general formula [I] wherein, R' and R2 each represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a releasing group which is released at the reaction with the oxidation product of an aromatic primary amine developing agent; at least one of said R' and R2 is an alkyl group having a secondary or tertiary carbon atom directly bonded to the skeleton, at least one of said R, and R2 is a sulfonamidoalkyl group or a sulfamoylalkyl group; and the magenta coupler may form a dimer or more polymer at the position of said R', R2 or X. By the combined use of high boiling point organic solvent and ultraviolet absorbent, light fastness and coloring property are markedly improved.

  一种卤化银彩色感光材料，包括一个支撑体，支撑体上至少有一层卤化银乳剂层，所述卤化银乳剂层含有通式[I]表示的吡唑啉系列品红耦合剂 其中，R'和 R2 各代表一个氢原子或一个取代基；X 代表一个氢原子或一个释放基团，该释放基团在与芳香族伯胺显色剂的氧化产物反应时被释放；所述 R' 和 R2 中至少有一个是烷基，该烷基具有直接键合到骨架上的仲碳原子或叔碳原子，所述 R，和 R2 中至少有一个是磺酰胺基烷基或磺酰基烷基；洋红偶联剂可在所述 R'、R2 或 X 的位置上形成二聚体或更多的聚合物。 通过同时使用高沸点有机溶剂和紫外线吸收剂，耐光牢度和着色性能得到明显改善。
• Magenta dye-forming coupler
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0294785A2

  公开（公告）日：1988-12-14

  There are provided 1H-pyrazolo[1,5-b]-1,2,4-triazole magenta couplers or 1H-pyrazolo[5,1-c]-1,2,4-triazole magenta couplers characterized by having at the 6-position a phenoxy group, on the ortho-position of which is an alkoxy group or an aryloxy group. A photographic material comprising the magenta coupler is excellent in color reproducibility and exhibits superior photographic characteristics in any of sensitivity, gradation, and color density.

  本发明提供了 1H-吡唑并[1,5-b]-1,2,4-三唑洋红色耦合剂或 1H-吡唑并[5,1-c]-1,2,4-三唑洋红色耦合剂，其特征是在 6 位上有一个苯氧基，其正交位上有一个烷氧基或芳氧基。包含品红耦合剂的感光材料具有极佳的色彩再现性，并在感光度、色阶和色彩密度方面表现出卓越的感光特性。
• Silver halide colour photographic material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0447921A2

  公开（公告）日：1991-09-25

  A silver halide color light-sensitive material including a support having thereon at least one hydrophilic colloidal layer is disclosed, wherein the hydrophilic colloidal layer contains a DIR coupler represented by formula (I): wherein R¹ represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic group; R² represents an organic group; X and Y each represent -N= or wherein R³ represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, an amino group, an acyl group, an acylamino group, a carbamoyl group, a carbamoylamino group, a sulfonyl group, a sulfonylamino group, a sulfamoyl group, a sulfamoylamino group, an alkoxy group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, a hydroxyl group, a sulfenyl group, a sulfinyl group, an aliphatic group, an aromatic group, or a heterocyclic group; and Z represents a releasable group which is released on reacting with an oxidation product of an aromatic primary amine developing agent to become a development inhibitor or a precursor thereof and which diffuses into a color developing solution and then decomposes to a compound having no substantial influence on photographic properties.

  本发明公开了一种卤化银彩色光敏材料，该材料包括一个支架，支架上至少有一个亲水胶体层，其中亲水胶体层含有由式（I）表示的 DIR 耦合剂： 其中 R¹ 代表氢原子、脂肪族基团、芳香族基团或杂环基团；R² 代表有机基团；X 和 Y 各自代表-N= 或 其中 R³ 代表氢原子、卤素原子、氰基、硝基、氨基、酰基、酰氨基、氨基甲酰基、 氨基酰胺基、磺酰基、磺酰氨基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基磺酰胺基、烷氧基、芳氧基、烷氧羰基、芳氧羰基、羟基、亚磺酰基、亚硫酰基、脂肪族基、芳香族基或杂环基；Z 代表可释放基团，该基团与芳香族伯胺显影剂的氧化产物反应后释放，成为显影抑制剂或其前体，并扩散到显色溶液中，然后分解为对感光性能无实质性影响的化合物。