benzyltris(dimethylamino)phosphonium chloride | 36636-04-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzyltris(dimethylamino)phosphonium chloride
• 英文别名: Benzyltris(dimethylaminato)phosphorus(1+) chloride；benzyl-tris(dimethylamino)phosphanium;chloride
• CAS: 36636-04-1
• 化学式: C₁₃H₂₅N₃P*Cl
• 分子量: 289.788
• InChiKey: YFZFPCHXUXSTTM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.36
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  benzyltris(dimethylamino)phosphonium chloride 在 氢氧化钾 作用下， 以79%的产率得到N,N,N',N'-tetramethyldiamide of phenylmethanephosphonic acid
  参考文献：
  名称：

  Mizrakh, L. I.; Polonskaya, L. Yu., Journal of general chemistry of the USSR, 1989, vol. 59, p. 1299

  摘要：

  DOI：
• 作为产物：
  描述：

  氯化苄 、 三(二甲胺基)膦 生成 benzyltris(dimethylamino)phosphonium chloride
  参考文献：
  名称：

  Process of preparing organic phosphorus compounds

  摘要：

  公开号：

  US02703814A1

文献信息

• [EN] HYDROXY-FUNCTIONALIZED TRIAZINE COMPOUNDS. CURABLE FLUOROPOLYMER COMPOSITIONS COMPRISING SUCH COMPOUNDS AND CURED ARTICLES THEREFROM<br/>[FR] COMPOSÉS DE TRIAZINE À FONCTION HYDROXY, COMPOSITIONS FLUOROPOLYMÈRES DURCISSABLES COMPRENANT DE TELS COMPOSÉS ET ARTICLES DURCIS OBTENUS À PARTIR DE CELLES-CI
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2020261088A1

  公开（公告）日：2020-12-30

  Described herein are compounds according to Formula (I) wherein each Rf is independently selected from a perfluorinated divalent group comprising 2 to 12 carbon atoms; and m is an integer independently selected from 1 to 3. A method of making the compound from a hydroxy-containing vinyl ether and excess ammonia is disclosed. In one embodiment, the hydroxy-ftmctionalized triazine compound is used in a curable fluoropolymer composition and cured to form articles.

  本文描述了符合公式（I）的化合物，其中每个Rf独立地选自包含2至12个碳原子的全氟双价基团；而m是独立地选自1至3的整数。还公开了一种通过含羟基的乙烯醚和过量氨制备该化合物的方法。在一种实施例中，羟基功能化三嗪化合物用于可固化的氟聚合物组合物中，并经过固化形成物品。
• Fluoroelastomer composition having excellent processability
  申请人：——

  公开号：US20020002248A1

  公开（公告）日：2002-01-03

  Fluoroelastomers which contain copolymerized units of a fluoroolefin cure site monomer of the general formula R f —(CH 2 CF 2 ) n —CH═CF 2 , wherein R f is a C 1 -C 6 perfluoroalkyl group or a C 1 -C 6 perfluoroalkoxy group and n is an integer from 1-3, exhibit excellent physical properties and processability when cured with polyhydroxy compounds.

  含有通式为Rf—(CH2CF2)n—CH═CF2的含有氟烯烃固化位单体的共聚单位的氟橡胶，其中Rf是C1-C6全氟烷基或C1-C6全氟烷氧基，n为1-3的整数，当与多羟化合物固化时，表现出优异的物理性能和加工性。
• Fluoroelastomer composition
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0335705A1

  公开（公告）日：1989-10-04

  A fluoroelastomer composition curable in reactive admixture with an acid acceptor that includes an elastomeric gum consisting essentially of vinylidene fluoride, tetrafluoroethylene, and copolymerizable hydrocarbon olefin and a combination of (A) polyhydroxy compound, and (B) organo-onium compound, and process of curing the elastomeric copolymer with an admixture of (A) and (B) and an acid acceptor, and the resulting shaped or formed, cured articles are described.

  一种可与酸接受体反应性混合固化的氟橡胶组合物，其中包括一种主要由偏氟乙烯、四氟乙烯和可共聚的烃类烯烃组成的弹性胶，以及以下物质的混合物 (A) 多羟基化合物 (B) 有机铵化合物、 以及用（A）和（B）的混合物和酸接受体固化弹性共聚物的工艺，以及由此产生的成型或成形的固化物品。
• Fluoroelastomer composition with improved bonding properties
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0404411A1

  公开（公告）日：1990-12-27

  A curable fluoroelastomer composition comprising: (A) fluoroelastomer gum comprising interpolymerized, repeating units derived from vinylidene fluoride, tetrafluoroethylene, and copolymerizable hydrocarbon olefin, (B) polyhydroxy compound, (C) organo-onium compound, and (D) fluoroaliphatic sulfonyl compound adhesion promoter, where the amount of fluoroaliphatic sulfonyl compound in the elastomeric composition is sufficient to result in greater adhesion of the elastomeric composition, after curing, to an inorganic surface coated with a primer composition comprising aminosilane compound, than can be achieved between an elastomeric composition comprising (A), (B), and (C), after curing, and an inorganic surface coated with said primer composition comprising aminosilane compound.

  一种可固化的氟橡胶组合物，包括(A)氟弹性体胶，包括由偏氟乙烯、四氟乙烯和可共聚的烃类烯烃衍生的互聚重复单元；(B)多羟基化合物；(C)有机铵化合物；和(D)氟脂肪族磺酰化合物粘合促进剂，其中弹性体组合物中氟脂肪族磺酰化合物的量足以使弹性体组合物产生更大的粘合力、固化后的弹性体组合物与涂有包含氨基硅烷化合物的底涂组合物的无机表面之间的粘附力大于固化后的包含(A)、(B)和(C)的弹性体组合物与涂有上述包含氨基硅烷化合物的底涂组合物的无机表面之间的粘附力。
• Polymer blend composition
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0432911A1

  公开（公告）日：1991-06-19

  A blend composition comprising (a) 50 to about 90% of fluorinated elastomer, (b) 10 to about 50% of essentially fluorine-free thermoplastic polymer having a melt temperature or glass transition temperature greater than about 150 C (preferably greater than about 180 C). A curing agent can be mixed with the elastomer when the thermoplastic polymer is blended with the elastomer at an elevated temperature. Articles produced from the cured composition exhibit a continuous service temperature of at least 150 C (preferably at least 180 C) and a volume swell of less than about 150% in methanol and hydrocarbon fuels and oils. The composition and cured articles are reprocessable.

  一种共混组合物，包括：(a) 50%至约 90%的含氟弹性体；(b) 10%至约 50%的基本上不含氟的热塑性聚合物，其熔融温度或玻璃化转变温度大于约 150 摄氏度（最好大于约 180 摄氏度）。在高温下将热塑性聚合物与弹性体混合时，可将固化剂与弹性体混合。由固化组合物制成的制品的连续使用温度至少为 150 摄氏度（最好至少为 180 摄氏度），在甲醇和烃类燃料及油中的体积膨胀率小于约 150%。该组合物和固化物品均可再加工。