catena-poly[((N,N'-bis(acetylacetonato)ethylenediamine)iron(III))-μ-(1,3-bis(4-pyridyl)propane)] tetraphenylborate | 83555-99-1

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: catena-poly[((N,N'-bis(acetylacetonato)ethylenediamine)iron(III))-μ-(1,3-bis(4-pyridyl)propane)] tetraphenylborate
• CAS: 83555-99-1
• 化学式: C₂₄H₂₀B*C₂₅H₃₂FeN₄O₂
• 分子量: 795.635
• InChiKey: XDNYQSZJLDISAH-MZJUPKOXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4,4'-(1,3-丙二基)双吡啶 、 chloro(N,N'-bis(acetylacetonato)ethylenediamine)iron(III) 、 四苯硼钠 以 甲醇 为溶剂， 生成 catena-poly[((N,N'-bis(acetylacetonato)ethylenediamine)iron(III))-μ-(1,3-bis(4-pyridyl)propane)] tetraphenylborate
  参考文献：
  名称：

  1,3-双(4-吡啶基)丙烷轴向桥连的一维多核自旋交叉铁(III)配合物

  摘要：

  一维 (1D) 多核自旋交叉 FeIII 复合物，[FeIII(acacen)(bpyp)]n(BPh4)n，在约 10 的宽温度范围内显示出逐渐且完整的 SC。S = 5/2 和 S = 1 之间的 250 K...

  DOI：

  10.1246/cl.2006.502

文献信息

• Inter‐ and Intrachain Spin‐Transition Processes in One‐Dimensional Polynuclear Iron(III) Complexes of <i>N</i> , <i>N′</i> ‐Ethylenebis(acetylacetonylideneimine) Bridged by 1,3‐Bis(4‐pyridyl)propane and 1,4‐Bis(imidazolyl)butane
  作者：Shinya Imatomi、Shingo Hashimoto、Naohide Matsumoto

  DOI：10.1002/ejic.200800778

  日期：2009.2

  AbstractTwo one‐dimensional (1D) polynuclear iron(III) complexes, [FeIII(acacen)(bpyp)]BPh4 (1) and [FeIII(acacen)(bimb)]BPh4 (2), were synthesized [acacen = N,N′‐ethylenebis(acetylacetonylideneiminato); bpyp = 1,3‐bis(4‐pyridyl)propane; bimb = 1,4‐bis(imidazolyl)butane]. Complexes 1 and 2 show gradual spin‐crossover (SCO) behavior over a wide temperature range from 100 to 300 K and from 220 to higher than 350 K, respectively. The single‐crystal X‐ray structures of two complexes in the high‐spin (HS), low‐spin (LS), and the midpoint between HS and LS states were determined. Crystal structures of both complexes consist of two molecular units (Fe1 and Fe2), where complex 1 consists of two crystallographically independent 1D chains and complex 2 consists of one 1D chain involving two molecular units. At the temperature midway between the HS and LS states, the Fe–N bond lengths in the two units are different from each other. At the midpoint, complex 1 consists of alternately arrayed independent HS and LS chains, whereas complex 2 consists of alternately arrayed HS and LS units within a chain. The results demonstrate two different SCO mechanisms of a 1D complex, that is, SCO occurs in chain‐by‐chain fashion for 1 and in adjacent Fe units within a chain for 2. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)