N4,N4’-二-1-萘基-N4,N4’-二-2-萘基-[1,1’-联苯]-4,4’-二胺 | 374592-88-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N4,N4’-二-1-萘基-N4,N4’-二-2-萘基-[1,1’-联苯]-4,4’-二胺
• 中文别名: N,N'-二-1-萘基-N,N'-二-2-萘基联苯胺；N4,N4'-二-1-萘基-N4,N4'-二-2-萘基-[1,1'-联苯]-4,4'-二胺；LT-N141
• 英文名称: 4,4'-bis[N-(1-naphthyl)-N-(2-naphthyl)amino]biphenyl
• 英文别名: α,β-TNB；N4,N4'-DI-1-Naphthalenyl-N4,N4'-DI-2-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine；N-naphthalen-1-yl-N-[4-[4-[naphthalen-1-yl(naphthalen-2-yl)amino]phenyl]phenyl]naphthalen-2-amine
• CAS: 374592-88-8
• 化学式: C₅₂H₃₆N₂
• 分子量: 688.871
• InChiKey: RYZPDEZIQWOVPJ-UHFFFAOYSA-N

物化性质

• 熔点：
  134℃
• 密度：
  1.244

计算性质

• 辛醇/水分配系数(LogP)：
  15
• 重原子数：
  54
• 可旋转键数：
  7
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4,4-二碘联苯 、 1,2'-二萘胺(升华精制品) 在 palladium diacetate 、 三叔丁基膦 sodium t-butanolate 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 4.0h， 以82.6%的产率得到N4,N4’-二-1-萘基-N4,N4’-二-2-萘基-[1,1’-联苯]-4,4’-二胺
  参考文献：
  名称：

  [EN] PROCESS FOR FORMING AN AROMATIC AMINE COMPOUND
  [FR] PROCEDE DE FORMATION D'UN COMPOSE AMINE AROMATIQUE

  摘要：

  一种形成芳香胺产品的方法，包括以下步骤：(a)在钯配合物和膦化合物催化剂的存在下，将芳香初级或次级胺与芳香卤代化合物结合形成混合物；(b)将混合物加热至至少60°C的第一温度；(c)向加热的混合物中加入碱性物质；(d)将混合物的温度保持在第一温度或以上一段足够的时间，以形成芳香初级或次级胺的芳香取代产物。该方法提供高纯度的产物收率良好。

  公开号：

  WO2006011879A1

文献信息

• [EN] COMPOUNDS HAVING ELECTROLUMINESCENT OR ELECTRON TRANSPORT PROPERTIES<br/>[FR] COMPOSÉS PRÉSENTANT DES PROPRIÉTÉS ÉLECTROLUMINESCENTES OU DE TRANSPORT DES ÉLECTRONS
  申请人：MERCK PATENT GMBH

  公开号：WO2009112854A1

  公开（公告）日：2009-09-17

  A compound of the formula R1 (CR3 =CR4 ) nAr(CR4 =CR3 ) nR2 wherein: n is 0 or 1; Ar represents aryl or heteroaryl having 1-5 aromatic rings which may be chain or fused or a combination of chain and fused, which may be substituted withalkoxy, fluoro, fluoroalkyl or cyano and which in the case of a 5-memnered ring nitrogen heteroatom may be N-substituted with aryl or substituted aryl optionally further substituted with alkoxy, fluoro, fluoroalkyl or cyano; R1 and R2 independently represent aryl or nitrogen, oxygen or sulphur-containing heteroaryl having two to four fused aromatic rings one of which may be 5-membered and optionally substituted by aryl or heteroaryl having 1-5 chain or fused aromatic rings which may be further substituted withalkoxy, fluoro, fluoroalkyl or cyano; and R3 and R4 independently represent hydrogen, methyl, ethyl or benzyl. Alsoprovided is a method of making a compound having electroluminescent and/or electroconductive properties, which comprises condensing an aromatic dialdehyde with a methyl-substituted heteroaryl compound having two to four fused rings which maybe unsubstituted ormay be further substituted by aryl or heteroaryl having from one to fouraromatic rings, said aryl or heteroaryl substituent or substituents optionally being substituted with one or more fluoro, fluoroalkyl orcyano substituents.The condensation may be carried out in acetic anhydride under reflux. The compounds may be incorporatede.g. as an electron transport layer into an optical light emitting diode,where embodiments can provide high electron mobility, low turn-on voltage and good lifetime,or into an electrostatic imaging member. Acompositionis provided comprising a compound as above and a second host or electron transport material and/or at leastone dopant.

  一个化合物的结构式为R1（CR3=CR4）nAr（CR4=CR3）nR2，其中：n为0或1；Ar代表含有1-5个芳香环的芳基或杂芳基，可以是链状的、融合的或链状和融合的组合，可以被烷氧基、氟、氟烷基或氰基取代，在5-成员环氮杂原子的情况下，可能被芳基或取代芳基N-取代，可选择地进一步取代为烷氧基、氟、氟烷基或氰基；R1和R2独立地代表含有两到四个融合芳香环的芳基或氮、氧或硫杂杂芳基，其中一个可能是5-成员的，并且可选择地被芳基或含有1-5个链状或融合芳香环的杂芳基取代，这些芳基或杂芳基可能进一步被烷氧基、氟、氟烷基或氰基取代；R3和R4独立地代表氢、甲基、乙基或苄基。还提供了一种制备具有电致发光和/或电导性能的化合物的方法，包括将芳香二醛与一种具有两到四个融合环的甲基取代的杂芳基化合物缩合，该化合物可能未取代或可能进一步被含有一到四个芳香环的芳基或杂芳基取代，所述芳基或杂芳基取代物可选择地被一个或多个氟、氟烷基或氰基取代。缩合可以在乙酸酐中回流进行。这些化合物可以被用作电子传输层，例如用于光电发光二极管，其中实施例可以提供高电子迁移率、低开启电压和良好的寿命，或用于静电成像成员。提供了一种组合物，包括上述化合物和第二宿主或电子传输材料和/或至少一个掺杂剂。
• Phenanthrolines
  申请人：BASF SE

  公开号：EP2161272A1

  公开（公告）日：2010-03-10

  The present invention relates to phenanthroline compounds and to electroluminescent (EL) devices comprising the phenanthroline compounds. The phenanthroline compounds may function as electron transport layers, as hole blocking layers or as hosts for phosphorescent emitter materials to provide electroluminescent devices with improved efficiency, lifetime, operational stability and better spectral characteristics.

  本发明涉及菲啰啉化合物以及包括该菲啰啉化合物的电致发光（EL）器件。该菲啰啉化合物可以作为电子传输层、阻挡空穴层或者荧光发射材料的宿主，以提供具有改善效率、寿命、操作稳定性和更好光谱特性的电致发光器件。
• [EN] POLYCYCLIC COMPOUNDS FOR ELECTRONIC APPLICATIONS<br/>[FR] COMPOSÉS POLYCYCLIQUES POUR DES APPLICATIONS ÉLECTRONIQUES
  申请人：BASF SE

  公开号：WO2010046259A1

  公开（公告）日：2010-04-29

  The present invention relates to electronic devices, especially electroluminescent devices, comprising compounds of formula (I), and/or (II), especially as host for phosphorescent emitters, electron transporting materials, or emitter materials. The hosts may function with phosphorescent materials to provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.

  本发明涉及电子设备，特别是包含化合物(I)和/或(II)的电致发光器件，特别是作为磷光发射体、电子传输材料或发射材料的宿主。这些宿主可以与磷光材料配合使用，以提高电致发光器件的效率、稳定性、可制造性或光谱特性。
• LIGHT EMITTING DEVICE CONTAINING PHOSPHORESCENT COMPLEX
  申请人：Ren Xiaofan

  公开号：US20080020237A1

  公开（公告）日：2008-01-24

  An OLED device comprises a cathode, an anode, and has therebetween a light emitting layer comprising a phosphorescent emitter represented by Formula (I): L n M   (I) wherein each L is a cyclometallated ligand with at least one containing a coumarin group, M is Ir or Pt, and n is 3 when M is Ir and 2 when M is Pt. The invention also comprised the compound of formula (I).

  一种OLED器件包括阴极、阳极，并且在两者之间具有一个发光层，该发光层包括由式(I)表示的磷光发射体：LnM  (I)其中每个L是至少含有一个香豆素基团的环金属配体，M是Ir或Pt，当M为Ir时，n为3，当M为Pt时，n为2。该发明还包括式(I)的化合物。
• SULFONIC ACID ESTER COMPOUND AND USE THEREFOR
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US20190169120A1

  公开（公告）日：2019-06-06

  Provided is a sulfonic acid ester compound represented by formula (1). (In the formula, R 1 and R 2 each independently represent a hydrogen atom, or a straight-chain or branched monovalent aliphatic hydrocarbon group. R 3 represents a straight-chain or branched monovalent aliphatic hydrocarbon group. The sum of the carbon numbers of R 1 , R 2 and R 3 is 6 or greater. A 1 represents —O— or —S—. A 2 represents an aromatic group having a valence of (n+1). A 3 represents a hydrocarbon group which has a valence of m, and is unsubstituted or has a substituent that contains one or more aromatic rings. m represents an integer satisfying 2≤m≤4. n represents an integer satisfying 1≤n≤4.)

  提供的是由式（1）表示的磺酸酯化合物。（在该式中，R1和R2分别代表氢原子，或直链或支链的一价脂肪族碳氢基团。R3代表直链或支链的一价脂肪族碳氢基团。R1、R2和R3的碳原子数之和为6或更大。A1代表—O—或—S—。A2代表具有（n+1）价的芳香基团。A3代表具有m价的碳氢基团，未取代或具有含有一个或多个芳香环的取代基。m表示满足2≤m≤4的整数。n表示满足1≤n≤4的整数。）