摩熵化学
数据库官网
小程序
打开微信扫一扫
首页 分子通 化学资讯 化学百科 反应查询 关于我们
请输入关键词

N-methyl-6-methyl-2-phenylbenzimidazole | 24780-87-8

中文名称
——
中文别名
——
英文名称
N-methyl-6-methyl-2-phenylbenzimidazole
英文别名
1,6-Dimethyl-2-phenylbenzimidazol;1,6-dimethyl-2-phenyl-1H-benzimidazole;1,6-dimethyl-2-phenyl-1H-benzoimidazole;1,6-dimethyl-2-phenylbenzimidazole
N-methyl-6-methyl-2-phenylbenzimidazole化学式
CAS
24780-87-8
化学式
C15H14N2
mdl
——
分子量
222.29
InChiKey
RYTDKLCIKNBCPX-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    3.5
  • 重原子数:
    17
  • 可旋转键数:
    1
  • 环数:
    3.0
  • sp3杂化的碳原子比例:
    0.13
  • 拓扑面积:
    17.8
  • 氢给体数:
    0
  • 氢受体数:
    1

反应信息

  • 作为产物:
    描述:
    1-benzyl-3,5-dimethyl-2-phenyl-2,3-dihydro-1H-benzoimidazole 生成 N-methyl-6-methyl-2-phenylbenzimidazole
    参考文献:
    名称:
    RAO, C. V. CHALAPATHI;REDDY, K. K.;RAO, N. V. SUBBA, INDIAN J. CHEM., 1980, 19, N 11, 967-969
    摘要:
    DOI:
点击查看最新优质反应信息

文献信息

  • PHENANTHRENE DERIVATIVE, AND MATERIAL FOR ORGANIC EL ELEMENT
    申请人:Kawamura Masahiro
    公开号:US20100331585A1
    公开(公告)日:2010-12-30
    A phenanthrene derivative is represented by a formula (1) below. In the formula (1), Ar 1 and Ar 2 each represent an aromatic hydrocarbon ring group having 6 to 18 carbon atoms for forming the ring. The aromatic hydrocarbon ring group contains none of anthracene skeleton, pyrene skeleton, aceanthrylene skeleton and naphthacene skeleton. R 1 represents a substituent, the number of which may be 0, 1 or more. R 1 may be bonded in any position of the phenanthrene skeleton. n and m each represent an integer of 1 to 3. k represents an integer of 0 to 8.
    一个菲的衍生物由下面的公式(1)表示。在公式(1)中,Ar1和Ar2分别代表含有6到18个碳原子形成环的芳香烃环基团。芳香烃环基团不包含蒽骨架、芘骨架、乙酰芘骨架和萘骨架。R1代表一个取代基,其数量可以是0、1或更多。R1可以连接在菲的骨架的任何位置。n和m分别代表1到3的整数。k代表0到8的整数。
  • NAPHTHALENE DERIVATIVE, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE, AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
    申请人:Kawamura Masahiro
    公开号:US20090008605A1
    公开(公告)日:2009-01-08
    A naphthalene derivative represented by the following formula (1) is provided. In the formula, Ar 1 to Ar 4 each represent an aromatic hydrocarbon cyclic group having 6 to 18 carbon atoms forming a ring. The aromatic hydrocarbon cyclic group has none of anthracene skeleton, pyrene skeleton, aceanthrylene skeleton and naphthacene skeleton. n, m and 1 each represent an integer in a range of 1 to 5. p represents an integer in a range of o to 5. When n, m, 1 and p each are 2 or more, a plurality of Ar 1 to Ar 4 may be mutually the same or different.
    提供以下公式(1)表示的萘衍生物。在该公式中,Ar1至Ar4分别表示具有6至18个碳原子形成环的芳香烃环族。芳香烃环族不包含蒽骨架、芘骨架、蒽芘骨架和萘芘骨架。n、m和l分别表示范围在1到5的整数。p表示范围在0到5的整数。当n、m、l和p均为2或更多时,Ar1至Ar4的多个可能相互相同或不同。
  • Reactivity-Controlled Regioselectivity: A Regiospecific Synthesis of 1,2-Disubstituted Benzimidazoles
    作者:Xiaohu Deng、Neelakandha S. Mani
    DOI:10.1002/ejoc.200901056
    日期:2010.2
    combination of N 1 /N 2 chemoselectivity on the amidine and reactivity-controlled X 1 /X 2 chemoselectivity on the 1,2-dihaloarene. This reaction proves to be fairly general for the regiospecific synthesis of 1,2-substituted benzimidazoles.
    我们在 1,2-分化二卤代芳烃和 N-取代脒之间的串联胺化反应中展示了卓越的区域选择性。这种CuI催化反应的区域化学结果是通过脒的N 1 /N 2 化学选择性和1,2-二卤代芳烃的反应性控制的X 1 /X 2 化学选择性的组合实现的。该反应证明对于 1,2-取代苯并咪唑的区域特异性合成是相当普遍的。
  • ORGANIC ELECTROLUMINESCENCE DEVICE AND MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE
    申请人:Nishimura Kazuki
    公开号:US20090045730A1
    公开(公告)日:2009-02-19
    An organic electroluminescence device includes: a cathode; an anode; and a single-layered or multilayered organic thin-film layer provided between the cathode and the anode. The organic thin-film layer includes at least one emitting layer. The at least one emitting layer contains at least one phosphorescent material and a host material represented by the following formula (1). Ra-Ar 1 -Rb  (1) In the formula, Ar 1 , Ra and Rb each represent a substituted or unsubstituted benzene ring or a condensed aromatic hydrocarbon ring selected from a substituted or unsubstituted naphthalene ring, a substituted or unsubstituted chrysene ring, a substituted or unsubstituted fluoranthene ring, a substituted or unsubstituted phenanthrene ring, a substituted or unsubstituted benzophenanthrene ring, a substituted or unsubstituted dibenzophenanthrene ring, a substituted or unsubstituted triphenylene ring, a substituted or unsubstituted benzo[a]triphenylene ring, a substituted or unsubstituted benzochrysene ring, a substituted or unsubstituted benzo[b]fluoranthene ring and a substituted or unsubstituted picene ring. Substituents for Ra and Rb are not aryl groups.
    有机电致发光器件包括:阴极;阳极;以及设置在阴极和阳极之间的单层或多层有机薄膜层。有机薄膜层包括至少一个发光层。该至少一个发光层包含至少一种磷光材料和由以下式(1)表示的主体材料。Ra-Ar1-Rb  (1)在该式中,Ar1、Ra和Rb各自表示取代或未取代的苯环或选自取代或未取代的萘环、取代或未取代的蒽环、取代或未取代的芴环、取代或未取代的菲环、取代或未取代的苯并菲环、取代或未取代的二苯并菲环、取代或未取代的三苯基烷环、取代或未取代的苯并三苯基烷环、取代或未取代的苯并蒽环、取代或未取代的苯并芴环和取代或未取代的苊环的缩合芳香烃环。Ra和Rb的取代基不是芳基基团。
  • MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT, AND ORGANIC ELECTROLUMINESCENT ELEMENT
    申请人:Takashima Yoriyuki
    公开号:US20110315965A1
    公开(公告)日:2011-12-29
    An organic electroluminescence device and a material for producing the organic electroluminescence device. The organic electroluminescence device includes an organic thin film layer between a cathode and an anode, the organic thin film layer including one or more layers, in which the organic thin film layer includes one or more light emitting layers and at least one of the light emitting layers includes a phosphorescent material and a host material. The host material has an essential structure in which a naphthalene ring is bonded to a fluorene skeleton, dibenzofuran skeleton, or dibenzothiophene skeleton. The organic electroluminescence device is a phosphorescent device having high efficiency and long lifetime.
    一种有机电致发光器件和制备该有机电致发光器件的材料。该有机电致发光器件包括在阴极和阳极之间的有机薄膜层,该有机薄膜层包括一个或多个层,其中有机薄膜层包括一个或多个发光层,至少一个发光层包括磷光材料和主体材料。主体材料具有一个必要的结构,其中萘环连接到芴骨架、二苯并呋喃骨架或二苯并噻吩骨架。该有机电致发光器件是一种具有高效率和长寿命的磷光器件。
查看更多