carbon monoxide;chromium;N-phenyl-1-[2-[2-(phenyliminomethyl)phenyl]phenyl]methanimine | 229315-73-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: carbon monoxide;chromium;N-phenyl-1-[2-[2-(phenyliminomethyl)phenyl]phenyl]methanimine
• CAS: 229315-73-5
• 化学式: C₂₉H₂₀CrN₂O₃
• 分子量: 496.485
• InChiKey: OSEOPJSSBFPBLL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.74
• 重原子数：
  35
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  carbon monoxide;chromium;N-phenyl-1-[2-[2-(phenyliminomethyl)phenyl]phenyl]methanimine 在 samarium diiodide 、 氯化铵 作用下， 以 四氢呋喃 、 水 为溶剂， 以86%的产率得到carbon monoxide;chromium;(9S,10S)-9-N,10-N-diphenyl-9,10-dihydrophenanthrene-9,10-diamine
  参考文献：
  名称：

  Enantiomerically Pure Cyclic trans-1,2-Diols, Diamines, and Amino Alcohols by Intramolecular Pinacol Coupling of Planar Chiral Mono-Cr(CO)3 Complexes of Biaryls

  摘要：

  Without any formation of stereoisomers, the intramolecular pinacol cyclization of 1-planar chiral mono-Cr(CO)3 complexes of 1,1'-biphenyls with carbonyl functionalities at the 2- and 2'-positions-with samarium diiodide gives cyclic trans-1,2-diols 2. Upon exposure to sunlight, the chromium-complexed diols 2 produce optically pure chromium-free trans-diols 3. Similarly, the corresponding enantiomerically pure trans-1,2-diamines and amino alcohols are obtained from the planar chiral chromium complexes of biphenyls with diimino or keto-imino functionalities. R1 =H, OMe; R2 =H, Me; R3 =H, Me.

  DOI：

  10.1002/(sici)1521-3773(19990503)38:9<1232::aid-anie1232>3.0.co;2-e
• 作为产物：
  描述：

  Carbon monoxide;chromium;2-(2-formylphenyl)benzaldehyde 、 苯胺 以 not given 为溶剂， 生成 carbon monoxide;chromium;N-phenyl-1-[2-[2-(phenyliminomethyl)phenyl]phenyl]methanimine
  参考文献：
  名称：

  Enantiomerically Pure Cyclic trans-1,2-Diols, Diamines, and Amino Alcohols by Intramolecular Pinacol Coupling of Planar Chiral Mono-Cr(CO)3 Complexes of Biaryls

  摘要：

  Without any formation of stereoisomers, the intramolecular pinacol cyclization of 1-planar chiral mono-Cr(CO)3 complexes of 1,1'-biphenyls with carbonyl functionalities at the 2- and 2'-positions-with samarium diiodide gives cyclic trans-1,2-diols 2. Upon exposure to sunlight, the chromium-complexed diols 2 produce optically pure chromium-free trans-diols 3. Similarly, the corresponding enantiomerically pure trans-1,2-diamines and amino alcohols are obtained from the planar chiral chromium complexes of biphenyls with diimino or keto-imino functionalities. R1 =H, OMe; R2 =H, Me; R3 =H, Me.

  DOI：

  10.1002/(sici)1521-3773(19990503)38:9<1232::aid-anie1232>3.0.co;2-e

文献信息

• Enantiomerically Pure Cyclic trans-1,2-Diols, Diamines, and Amino Alcohols by Intramolecular Pinacol Coupling of Planar Chiral Mono-Cr(CO)3 Complexes of Biaryls
  作者：Nobukazu Taniguchi、Takeshi Hata、Motokazu Uemura

  DOI：10.1002/(sici)1521-3773(19990503)38:9<1232::aid-anie1232>3.0.co;2-e

  日期：1999.5.3

  Without any formation of stereoisomers, the intramolecular pinacol cyclization of 1-planar chiral mono-Cr(CO)3 complexes of 1,1'-biphenyls with carbonyl functionalities at the 2- and 2'-positions-with samarium diiodide gives cyclic trans-1,2-diols 2. Upon exposure to sunlight, the chromium-complexed diols 2 produce optically pure chromium-free trans-diols 3. Similarly, the corresponding enantiomerically pure trans-1,2-diamines and amino alcohols are obtained from the planar chiral chromium complexes of biphenyls with diimino or keto-imino functionalities. R1 =H, OMe; R2 =H, Me; R3 =H, Me.