(4-Dodecyloxy-phenoxy)-acetic acid | 55205-50-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-Dodecyloxy-phenoxy)-acetic acid
• 英文别名: [4-(Dodecyloxy)phenoxy]acetic acid；2-(4-dodecoxyphenoxy)acetic acid
• CAS: 55205-50-0
• 化学式: C₂₀H₃₂O₄
• 分子量: 336.472
• InChiKey: RQNUGFUIGCOMFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  24
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (4-Dodecyloxy-phenoxy)-acetic acid 在 草酰氯 、 N,N-二甲基甲酰胺 作用下， 以 氯仿 为溶剂， 反应 5.0h， 生成 2-(4-Dodecoxyphenoxy)acetyl chloride
  参考文献：
  名称：

  First Zipper-Featured Molecular Duplexes Driven by Cooperative Donor−Acceptor Interaction

  摘要：

  [GRAPHIC]The first class of zipper-shaped artificial duplexes, which are driven by multiple donor-acceptor interactions between electron-rich 1,5-dioxynaphthalene or 1,4-dioxybenzene and electron-deficient pyromellitic dimide units, have been studied in organic media by H-1 NMR, UV-vis, and vapor pressure osmometry. H-1 NMR binding investigations reveal substantial cooperativity of the donor-acceptor interaction in the duplexes.

  DOI：

  10.1021/ol034549p
• 作为产物：
  描述：

  4-十二烷氧基苯酚 在 sodium hydroxide 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 、 乙腈 为溶剂， 反应 12.0h， 生成 (4-Dodecyloxy-phenoxy)-acetic acid
  参考文献：
  名称：

  First Zipper-Featured Molecular Duplexes Driven by Cooperative Donor−Acceptor Interaction

  摘要：

  [GRAPHIC]The first class of zipper-shaped artificial duplexes, which are driven by multiple donor-acceptor interactions between electron-rich 1,5-dioxynaphthalene or 1,4-dioxybenzene and electron-deficient pyromellitic dimide units, have been studied in organic media by H-1 NMR, UV-vis, and vapor pressure osmometry. H-1 NMR binding investigations reveal substantial cooperativity of the donor-acceptor interaction in the duplexes.

  DOI：

  10.1021/ol034549p

文献信息

• US3973979A
  申请人：——

  公开号：US3973979A

  公开（公告）日：1976-08-10
• First Zipper-Featured Molecular Duplexes Driven by Cooperative Donor−Acceptor Interaction
  作者：Qi-Zhong Zhou、Xi-Kui Jiang、Xue-Bin Shao、Guang-Ju Chen、Mu-Xin Jia、Zhan-Ting Li

  DOI：10.1021/ol034549p

  日期：2003.5.1

  [GRAPHIC]The first class of zipper-shaped artificial duplexes, which are driven by multiple donor-acceptor interactions between electron-rich 1,5-dioxynaphthalene or 1,4-dioxybenzene and electron-deficient pyromellitic dimide units, have been studied in organic media by H-1 NMR, UV-vis, and vapor pressure osmometry. H-1 NMR binding investigations reveal substantial cooperativity of the donor-acceptor interaction in the duplexes.