9-(10-Methylanthryl)methyl methacrylate | 57504-09-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9-(10-Methylanthryl)methyl methacrylate
• 英文别名: Methacrylsaeure-10-methyl-9-anthrylmethylester；9-Methacryloyloxymethyl-10-methylanthrazen；9-(10-methyl)-anthrylmethylester of methacrylic acid；(10-Methylanthracen-9-YL)methyl 2-methylprop-2-enoate
• CAS: 57504-09-3
• 化学式: C₂₀H₁₈O₂
• 分子量: 290.362
• InChiKey: KWXRJCHEYQJZBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  10-甲基蒽-9-甲醛 在 sodium tetrahydroborate 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 生成 9-(10-Methylanthryl)methyl methacrylate
  参考文献：
  名称：

  Energy Migration and Excimer Formation in Quasi-Two-Dimensional Polymer Films As Revealed by the Time-Resolved Fluorescence Depolarization Measurement

  摘要：

  Excitation energy migration and subsequent energy transfer to excimer-forming sites occurring in a quasi-two-dimensional plane of poly(isobutyl methacrylate) Langmuir-Blodgett films were investigated through the time-resolved analyses of anthracene fluorescence. Fluorescence anisotropy decays showed that the energy migration occurred more efficiently as the anthracene fraction increased. A further increase of the anthracene gave rise to the excimer-forming sites acting as energy traps, and finally the anthracene fluorescence was markedly quenched from the energy transfer to the traps. The migration process was quantitatively analyzed by a computer simulation based on the Monte Carlo method, which allowed estimation of the number of hopping and the mean-square displacement of excitons. The initial growth of the mean-square displacement with time became gradually gentle, while the number of hopping linearly increased with time. This result shows that the excitons are not diffusive and tend to stay within a small cluster of chromophores, especially for small chromophore density at short times.

  DOI：

  10.1021/jp9840735

文献信息

• Glass sizing composition
  申请人：——

  公开号：US20040166313A1

  公开（公告）日：2004-08-26

  The present invention relates to a sizing composition for use on glass fibers which are used to reinforce plastic resins used in the formation of fiber-reinforced plastics (FRPs). The sizing composition comprises a copolymer formed from at least one functional monomer that is selected from the group consisting of hydroxy, phenyl and alkoxylated functional groups. The glass fibers sized with the sizing composition of the invention have excellent computability with resins used in forming FRPs, as seen by a low level of white glass.

  本发明涉及一种用于玻璃纤维的施胶组合物，玻璃纤维用于增强塑料树脂，以形成纤维增强塑料（FRP）。 该上浆组合物包括由至少一种功能单体形成的共聚物，该功能单体选自羟基、苯基和烷氧基化官能团组成的组。 用本发明的施胶组合物施胶的玻璃纤维与用于形成玻璃纤维增强塑料的树脂具有极佳的可计算性，这一点从白玻璃的含量较低就可以看出来。
• KRAKOVYAK M. G.; ANANIEVA T. D.; SKOROKHODOV S. S., SYNTH. COMMUNS, 1977, 7, NO 6, 397-404
  作者：KRAKOVYAK M. G.、 ANANIEVA T. D.、 SKOROKHODOV S. S.

  DOI：——

  日期：——
• GLASS SIZING COMPOSITION
  申请人：Celanese International Corporation

  公开号：EP1599427A1

  公开（公告）日：2005-11-30
• US7087302B2
  申请人：——

  公开号：US7087302B2

  公开（公告）日：2006-08-08
• [EN] GLASS SIZING COMPOSITION<br/>[FR] COMPOSITION D'APPRET POUR VERRE
  申请人：NAT STARCH CHEM INVEST

  公开号：WO2004076374A1

  公开（公告）日：2004-09-10

  The present invention relates to a sizing composition for use on glass fibers which are used to reinforce plastic resins used in the formation of fiber-reinforced plastics (FRPs). The sizing composition comprises a copolymer formed from at least one functional monomer that is selected from the group consisting of hydroxy, phenyl and alkoxylated functional groups. The glass fibers sized with the sizing composition of the invention have excellent computability with resins used in forming FRPs, as seen by a low level of white glass.