tributylallylphosphonium ion | 71104-89-7

• 分子结构分类: 有机化合物 - 有机磷化合物 - 四烷基鏻化合物
• 英文名称: tributylallylphosphonium ion
• 英文别名: Tributyl(prop-2-en-1-yl)phosphanium；tributyl(prop-2-enyl)phosphanium
• CAS: 71104-89-7
• 化学式: C₁₅H₃₂P
• 分子量: 243.393
• InChiKey: FCUPWNWJWSFDMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E)-2-庚烯醛 、 tributylallylphosphonium ion 在 正丁基锂 作用下， 生成 (3E,5E)-Deca-1,3,5-triene
  参考文献：
  名称：

  Studies directed toward the synthesis of viridenomycin. Route 2: a second generation approach

  摘要：

  A second generation approach toward the synthesis of viridenomycin is described. Three key fragments of the molecule have been synthesized in stereochemically pure form. Initial studies toward the coupling of these fragments with the aim of assembling the macrocycle are detailed. Final efforts to reach the title compound are documented. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00701-8

文献信息

• Studies directed toward the synthesis of viridenomycin. Route 2: a second generation approach
  作者：Alex G Waterson、Albert W Kruger、A.I Meyers

  DOI：10.1016/s0040-4039(01)00701-8

  日期：2001.6

  A second generation approach toward the synthesis of viridenomycin is described. Three key fragments of the molecule have been synthesized in stereochemically pure form. Initial studies toward the coupling of these fragments with the aim of assembling the macrocycle are detailed. Final efforts to reach the title compound are documented. (C) 2001 Elsevier Science Ltd. All rights reserved.