1-p-tolyloxy-2-vinyloxy-ethane | 104037-31-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-p-tolyloxy-2-vinyloxy-ethane
• 英文别名: 1-p-Tolyloxy-2-vinyloxy-aethan；1-(2-Ethenoxyethoxy)-4-methylbenzene
• CAS: 104037-31-2
• 化学式: C₁₁H₁₄O₂
• 分子量: 178.231
• InChiKey: LRQKCQUXUKNBRP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(4-甲基苯氧基)乙醇 在 氢氧化钾 、 乙炔 作用下， 生成 1-p-tolyloxy-2-vinyloxy-ethane
  参考文献：
  名称：

  Reppe et al., Justus Liebigs Annalen der Chemie, 1956, vol. 601, p. 81,104

  摘要：

  DOI：

文献信息

• COATING COMPOSITIONS
  申请人：HOULIHAN Francis

  公开号：US20130236833A1

  公开（公告）日：2013-09-12

  Developable bottom antireflective coating compositions are provided.

  提供可开发的底部防反射涂层组合物。
• Cationic radiation curable compositions
  申请人：Agfa Graphics N.V.

  公开号：EP2199856A1

  公开（公告）日：2010-06-23

  A radiation curable composition comprising a cationic photoinitiator according to Formula (I) or (II): wherein : R1, R2 and R3 independently represent a group selected from the group consisting of an aryl group and a heteroaryl group, with the proviso that R1, R2 and R3 are each substituted by at least one substituent comprising at least one cationically polymerizable group selected from the group consisting of an alkenyl ether, an epoxide and an oxetane; P and Q independently represent the necessary atoms to form a substituted or unsubstituted 5 or 6-membered aromatic or heteroaromatic ring, with the proviso that at least one of P,Q and L is substituted by at least one substituent comprising at least one cationically polymerizable group, selected from the group consisting of an alkenyl ether, an epoxide and an oxetane; L represents a group selected from the group consisting of a direct bond, 0, S, SO, SO2, CR5R6, C(=O), S(=O), C(NR8) and NR7; R5 and R6 independently represent a group selected from the group consisting of a hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkaryl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heteroaryl group, a halogen, an alcohol, an ether, an ester, an amine, an amide, a carboxylic acid, a thiol and thioether; R5 and R6 may represent the necessary atoms to form a five or six membered ring; R7 and R8 independently represent a group selected from the group consisting of a hydrogen, an substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkaryl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heteroaryl group and an acyl group; and Y- represents a counter ion to compensate for the positive charge of the sulfonium compound.

  一种辐射固化组合物，包含符合式 (I) 或 (II) 的阳离子光引发剂： 其中 ： R1、R2 和 R3 独立地代表选自由芳基和杂芳基组成的组，但 R1、R2 和 R3 各自被至少一个取代基取代，该取代基包含选自由烯基醚、环氧化物和氧杂环丁烷组成的组的至少一个阳离子可聚合基团； P 和 Q 各自代表形成取代或未取代的 5 或 6 元芳香族或杂芳环所需的原子，但 P、Q 和 L 中至少有一个被至少一个取代基取代，该取代基包含至少一个可阳离子聚合的基团，该基团选自由烯基醚、环氧化物和氧杂环丁烷组成的组； L 代表选自由直接键、0、S、SO、SO2、CR5R6、C(＝O)、S(＝O)、C(NR8) 和 NR7 组成的组； R5 和 R6 独立地代表选自以下组别的基团：氢、取代或未取代的烷基、取代或未取代的烯基、取代或未取代的炔基、取代或未取代的芳烷基、取代或未取代的烷芳基、取代或未取代的芳基、取代或未取代的杂芳基、卤素、醇、醚、酯、胺、酰胺、羧酸、硫醇和硫醚； R5 和 R6 可代表形成五或六员环所需的原子； R7 和 R8 独立地代表选自以下组成的基团：氢、取代或未取代的烷基、取代或未取代的烯基、取代或未取代的炔基、取代或未取代的芳基、取代或未取代的烷芳基、取代或未取代的芳基、取代或未取代的杂芳基和酰基；以及 Y- 代表补偿锍化合物正电荷的反离子。
• Ink jet liquid composition, set, liquid cartridge, and ink jet recording method
  申请人：Canon Kabushiki Kaisha

  公开号：EP2423271A1

  公开（公告）日：2012-02-29

  An ink jet liquid composition which is used with an ink containing a pigment and which contains an ABC triblock polymer formed from an A block having an aryl group, a B block having a unit represented by the general formula (1), and a C block having a unit represented by the general formula (2), wherein an acid value of the polymer is 20 mgKOH/g or more and less than 150 mgKOH/g, the ratio of the number average molecular weight of the polymer to the acid value is 50 or more and 200 or less, the proportion of the A block in the polymer is 20.0 percent by mass or more and 80.0 percent by mass or less and is 5.0 times or more and 15.0 times or less the proportion of units derived from all acidic monomers contained in the polymer.

  一种喷墨液体组合物，可与含有颜料的墨水一起使用，该组合物含有一种 ABC 三嵌段聚合物，该聚合物由具有芳基的 A 嵌段、具有通式（1）表示的单元的 B 嵌段和具有通式（2）表示的单元的 C 嵌段形成，其中聚合物的酸值为 20 mgKOH/g 或以上且小于 150 mgKOH/g，聚合物的平均分子量数与酸值之比为 50 或以上且小于 200，聚合物中 A 嵌段的比例为 20.0%（以质量计）以上和 80.0%（以质量计）以下，并且是聚合物中所含所有酸性单体衍生单元比例的 5.0 倍（含）以上和 15.0 倍（含）以下。
• Polymer,polymer-containing composition containing the same, ink composition, and ink applying method, image forming method and image forming apparatus which make use of ink composition
  申请人：Ikegami Masayuki

  公开号：US20050249925A1

  公开（公告）日：2005-11-10

  A polymer having a specific repeating structural unit having in the side chain at least one selected from a sulfonic acid, a sulfonic acid ester and a sulfonic acid salt and a specific repeating structural unit having in the side chain at least one selected from a carboxylic acid, a carboxylic acid ester and a carboxylic acid salt.

  一种聚合物，其特定重复结构单元的侧链中至少有一种选自磺酸、磺酸酯和磺酸盐，而特定重复结构单元的侧链中至少有一种选自羧酸、羧酸酯和羧酸盐。
• Block polymer, polymer-containing composition containing the same, ink composition and liquid applying method and liquid applying apparatus utilizing the polymer-containing composition
  申请人：Duda Sakae

  公开号：US20060047015A1

  公开（公告）日：2006-03-02

  A block polymer comprised of a polyalkenyl ether main chain comprises a first block segment having hydrophobicity; a second block segment having an upper limit hydration temperature exceeding 70° C.; and a third block segment having an ionic property. A polymer-containing composition comprises the block polymer, a solvent or a dispersing medium, and a functional substance. An ink composition comprises the polymer-containing composition wherein the functional substance is colorant. A liquid application method comprises the steps of preparing the polymer-containing composition; and applying the polymer-containing composition to a medium. A liquid application apparatus comprises a liquid application means which makes energy act on the polymer-containing composition to apply the composition; and a drive means which drives the liquid application means. The polymer compound is capable of satisfactorily dispersing a functional substance in a solvent.

  一种由聚烯醚主链组成的嵌段聚合物包括具有疏水性的第一嵌段、水化温度上限超过 70°C 的第二嵌段以及具有离子特性的第三嵌段。含聚合物的组合物包括嵌段聚合物、溶剂或分散介质以及功能物质。一种油墨组合物包含该含聚合物组合物，其中功能物质为着色剂。一种液体应用方法包括以下步骤：制备含聚合物的组合物；以及将含聚合物的组合物应用于介质。一种涂液装置包括一个涂液装置，该装置使能量作用于含聚合物的组合物，以涂抹组合物；以及一个驱动装置，该装置驱动涂液装置。该聚合物化合物能够在溶剂中令人满意地分散功能物质。