N-methyl-dec-9-ynanilide | 109734-34-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-methyl-dec-9-ynanilide
• 英文别名: N-methyl-dec-9-ynanilide；N-Methyl-dec-9-inanilid
• CAS: 109734-34-1
• 化学式: C₁₇H₂₃NO
• 分子量: 257.376
• InChiKey: WGKPZLWICVBPSV-UHFFFAOYSA-N

物化性质

• 沸点：
  373.0±25.0 °C(Predicted)
• 密度：
  1.001±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.01
• 重原子数：
  19.0
• 可旋转键数：
  8.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  20.31
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  N-methyl-dec-9-ynanilide 在 四氢呋喃 、 lithium aluminium tetrahydride 、 乙醚 、 硫酸 、 苯 作用下， 生成 octadeca-9,12,15-triynal
  参考文献：
  名称：

  The Frontier Mountain meteorite trap (Antarctica)

  摘要：

  Abstract— The Frontier Mountain blue ice field is an important Antarctic meteorite trap which has yielded 472 meteorite specimens since its discovery in 1984. Remote sensing analyses and field campaigns from 1993 to 1999 have furnished new glaciological data on ice flow, ice thickness, bedrock topography, ice ablation and surface mass transport by wind, along with detailed descriptions of the field situation at the trap. This solid set of data combined with an updated meteorite distribution map and terrestrial ages available from literature allows us to better describe the nature of the concentration mechanism. In particular, we observe that the meteorite trap forms in a blue ice field (1) located upstream of an absolute and a shallow sub‐ice barriers; (2) characterized by compressive ice flow with horizontal velocities decreasing from 100 to <10 cm/year on approaching the obstacle; (3) undergoing mean ablation rates of 6.5 cm/year; (4) nourished by a limited snow accumulation zone extending ˜20 km upstream of the blue ice area. We also draw the following conclusions: (1) the origin of the meteorite trap can be explained according to the present‐day glaciological situation; (2) the meteorite concentration develops according to the general principles of the “ice flow model”; (3) the accumulation model can be described as “stagnant ice or slow‐moving ice against an absolute and submerged barriers”, according to the descriptive schemes present in literature; (4) the Frontier Mountain ice field is an effective trap for meteorites weighing more than ˜200 g; for smaller masses, the combination of wind and glacial drift may remove meteorites in less than a few tens of thousands of years; (5) although the activation age of the Frontier Mountain trap is not yet constrained, we infer that one of the most important findsites may be as old as 50 ka, predating the last glacial maximum.

  DOI：

  10.1111/j.1945-5100.2002.tb01105.x
• 作为产物：
  描述：

  9-癸炔酸 在 吡啶 、 氯化亚砜 、 苯 作用下， 生成 N-methyl-dec-9-ynanilide
  参考文献：
  名称：

  The Frontier Mountain meteorite trap (Antarctica)

  摘要：

  Abstract— The Frontier Mountain blue ice field is an important Antarctic meteorite trap which has yielded 472 meteorite specimens since its discovery in 1984. Remote sensing analyses and field campaigns from 1993 to 1999 have furnished new glaciological data on ice flow, ice thickness, bedrock topography, ice ablation and surface mass transport by wind, along with detailed descriptions of the field situation at the trap. This solid set of data combined with an updated meteorite distribution map and terrestrial ages available from literature allows us to better describe the nature of the concentration mechanism. In particular, we observe that the meteorite trap forms in a blue ice field (1) located upstream of an absolute and a shallow sub‐ice barriers; (2) characterized by compressive ice flow with horizontal velocities decreasing from 100 to <10 cm/year on approaching the obstacle; (3) undergoing mean ablation rates of 6.5 cm/year; (4) nourished by a limited snow accumulation zone extending ˜20 km upstream of the blue ice area. We also draw the following conclusions: (1) the origin of the meteorite trap can be explained according to the present‐day glaciological situation; (2) the meteorite concentration develops according to the general principles of the “ice flow model”; (3) the accumulation model can be described as “stagnant ice or slow‐moving ice against an absolute and submerged barriers”, according to the descriptive schemes present in literature; (4) the Frontier Mountain ice field is an effective trap for meteorites weighing more than ˜200 g; for smaller masses, the combination of wind and glacial drift may remove meteorites in less than a few tens of thousands of years; (5) although the activation age of the Frontier Mountain trap is not yet constrained, we infer that one of the most important findsites may be as old as 50 ka, predating the last glacial maximum.

  DOI：

  10.1111/j.1945-5100.2002.tb01105.x