acrylic acid 2-butoxycarbonylamino-ethyl ester

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: acrylic acid 2-butoxycarbonylamino-ethyl ester
• 英文别名: 2-(Butoxycarbonylamino)ethyl prop-2-enoate
• 化学式: C₁₀H₁₇NO₄
• 分子量: 215.249
• InChiKey: ARVWGEMAOZHGDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  64.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  羟乙基氨基甲酸丁酯 、 丙烯酰氯 在 吡啶 作用下， 反应 6.0h， 生成 acrylic acid 2-butoxycarbonylamino-ethyl ester
  参考文献：
  名称：

  快速单体：影响光引发丙烯酸酯聚合中丙烯酸酯单体固有反应性的因素

  摘要：

  对分子结构对丙烯酸酯光引发聚合反应的影响进行了系统的研究。最初，研究的重点是氢键的作用，发现通过氢键进行的预组织可提高最大聚合速率（R p）。这种氢键促进的预组织也影响了所得聚合物的立构规整度。接下来，研究了由给定单体的计算偶极矩（μcalc）表示的极性影响。观察到R p与计算的玻尔兹曼平均偶极矩（μcalc）之间存在直接的线性关系。的[R p -μ计算值相关性适用于纯单体，单体混合物，甚至单体与惰性溶剂的混合物。这种相关性使得能够合理设计具有所需反应性的单体。另外，这些研究表明，聚合的传播步骤受氢键的影响，而偶极矩则影响终止速率常数。可以将这两种机理解释视为影响丙烯酸酯聚合速度的互补因素。

  DOI：

  10.1021/ma021785r

文献信息

• Resin composition for flexographic printing plate, laser-engraving type flexographic printing plate precursor and process for producing same, and flexographic printing plate and process for making same
  申请人：Fujifilm Corporation

  公开号：EP2617773A1

  公开（公告）日：2013-07-24

  Disclosed is a resin composition for a flexographic printing plate, comprising (Component A) a binder resin and (Component B) a compound represented by Formula (1) and/or Formula (2), Component B being contained at 1 to 50 parts by mass relative to 100 parts by mass of Component A, wherein in Formulae (1) and (2) R1 and R4 independently denote a hydrogen atom or a methyl group, R2 and R5 independently denote a divalent organic group having 1 to 20 carbons, and R3 and R6 independently denote a monovalent organic group having 1 to 20 carbons, R3 and R6 not comprising an ethylenically unsaturated group, a dialkoxysilyl group, or a trialkoxysilyl group.

  本发明公开了一种用于柔性版印刷的树脂组合物，该组合物由（A 组分）粘合剂树脂和（B 组分）由式（1）和/或式（2）表示的化合物组成，相对于 100 质量份的 A 组分，B 组分的含量为 1 至 50 质量份、 其中，在式 (1) 和 (2) 中，R1 和 R4 独立地表示氢原子或甲基，R2 和 R5 独立地表示具有 1 至 20 个碳原子的二价有机基团，R3 和 R6 独立地表示具有 1 至 20 个碳原子的一价有机基团，R3 和 R6 不包括乙烯基不饱和基团、二烷氧基硅烷基团或三烷氧基硅烷基团。
• HOCHSCHLAGZÄHES, TRANSPARENTES PROTHESENMATERIAL MIT NIEDRIGEM REST-MMA GEHALT
  申请人：Kulzer GmbH

  公开号：EP3373991B1

  公开（公告）日：2020-07-01
• Ink composition, ink jet recording method, method of producing planographic printing plate, and planographic printing plate
  申请人：Nakamura Ippei

  公开号：US20070060665A1

  公开（公告）日：2007-03-15

  The present invention provides an ink composition including a polymerization initiator and a monofunctional (meth)acrylate having a —CONH— bond in the molecule thereof. The present invention also provides an ink jet recording method and a planographic printing plate producing method using the ink composition, and a planographic printing plate prepared by the planographic printing plate producing method.
• Curable Composition Containing Thiol Compound
  申请人：Miyata Hideo

  公开号：US20090023831A1

  公开（公告）日：2009-01-22

  The present invention relates to a curable composition having high adhesiveness and transparency, comprising a thiol compound containing two or more groups represented by formula (1): wherein the symbols in the formula have the meanings as described in the specification; and an urethane compound containing an ethylenically unsaturated double bond represented by formula (2): wherein the symbols in the formula have the meanings as described in the specification.
• RESIN COMPOSITION FOR FLEXOGRAPHIC PRINTING PLATE, LASER-ENGRAVING TYPE FLEXOGRAPHIC PRINTING PLATE PRECURSOR AND PROCESS FOR PRODUCING SAME, AND FLEXOGRAPHIC PRINTING PLATE AND PROCESS FOR MAKING SAME
  申请人：Fujifilm Corporation

  公开号：US20130186292A1

  公开（公告）日：2013-07-25

  Disclosed is a resin composition for a flexographic printing plate, comprising (Component A) a binder resin and (Component B) a compound represented by Formula (1) and/or Formula (2), Component B being contained at 1 to 50 parts by mass relative to 100 parts by mass of Component A, wherein in Formulae (1) and (2) R 1 and R 4 independently denote a hydrogen atom or a methyl group, R 2 and R 5 independently denote a divalent organic group having 1 to 20 carbons, and R 3 and R 6 independently denote a monovalent organic group having 1 to 20 carbons, R 3 and R 6 not comprising an ethylenically unsaturated group, a dialkoxysilyl group, or a trialkoxysilyl group.