4,6-diisopropylresorcinol | 69040-63-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,6-diisopropylresorcinol
• 英文别名: 4.6-Dioxy-1.3-diisopropyl-benzol；4,6-Diisopropyl-resorcin；4,6-diisopropylbenzene-1,3-diol；4,6-di(propan-2-yl)benzene-1,3-diol
• CAS: 69040-63-7
• 化学式: C₁₂H₁₈O₂
• 分子量: 194.274
• InChiKey: ATSSDICPUSGNHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,5-二氟-2,4-二硝基苯 、 4,6-diisopropylresorcinol 在 cesium fluoride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以40%的产率得到1(4),1(6),5(4),5(6)-tetraisopropyl-3(4),3(6),7(4),7(6)-tetranitro-2,4,6,8-tetraoxa-1,3,5,7-tetrabenzenacyclooctaphane
  参考文献：
  名称：

  The influence of heteroatoms on the conformational properties of heteracalix[4]arenes. Comparison of oxygen-, sulfur-, and nitrogen-bridged [14]metacyclophanes

  摘要：

  Oxygen- and sulfur-bridged calix[4]arenes have been synthesized by the nucleophilic aromatic substitution of 1,5-difluoro-2,4-dinitrobenzene with 4,6-diisopropylresorcinol or 4,6-diisopropyl-1,3-benzene-dithiol. X-ray crystal structure analyses revealed that the oxacalix[4]arene 2 adopts an unsymmetrical 1,3-alternate Conformation and that the dinitrobenzene rings strongly conjugate with the bridging oxy, en atoms. On the other hand, the thiacalix[4]arene 3 adopts a heavily twisted unsymmetrical 1,3-alternate conformation, and the conjugation is very weak. In the H-1 NMR spectrum (CDCl3, 30 degrees C) both compounds display a pair of diastereotopic methyl signals for the isopropyl groups in agreement with the frozen 1,3-alternate conformation on the NMR time scale. The free energies of activation (Delta G(298)(#)) of the macrocyclic inversion for 2 and 3 were determined to be 69.5 kJ mol (1) and 74.9 kJ mol(-1), respectively, by variable temperature NMR spectroscopy. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.06.111
• 作为产物：
  描述：

  异丙醇 、 间苯二酚 在 硫酸 作用下， 生成 4-异丙基苯-1,3-二醇 、 4,6-diisopropylresorcinol
  参考文献：
  名称：

  Meyer,H.; Bernhauer, Monatshefte fur Chemie, 1929, vol. 53/54, p. 728

  摘要：

  DOI：

文献信息

• MODIFIER FOR AROMATIC POLYESTER AND AROMATIC POLYESTER RESIN COMPOSITION COMPRISING THE SAME
  申请人：TABATA Masayoshi

  公开号：US20110224343A1

  公开（公告）日：2011-09-15

  The present invention provides a modifier for aromatic polyesters which enhances the melt fluidity of aromatic polyesters without a significant decrease in the heat resistance of the aromatic polyesters, and an aromatic polyester resin composition including the modifier for aromatic polyesters. The present invention relates to a modifier for aromatic polyesters comprising polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof, and the modifier comprises a material having a structure composed of a first residue selected from the group consisting of divalent residues represented by Formula (I): —Ar—W 1 x —Ar— and by Formula (II): —Ar—, the first residues being bonded to two identical or different second residues selected from the group consisting of monovalent residues represented by Formula (III): and monovalent residues represented by Formula (IV): —O—C(O)—R 7 —.

  本发明提供了一种用于芳香族聚酯的改性剂，可以增强芳香族聚酯的熔融流动性，而不明显降低芳香族聚酯的耐热性，以及包括该改性剂的芳香族聚酯树脂组合物。本发明涉及一种用于芳香族聚酯的改性剂，包括多羟基酚残基和芳香族多羧酸、酸卤或其酸酐残基，该改性剂包括具有以下结构的材料：第一残基，选择自由式(I)所代表的二价残基：—Ar—W1x—Ar—和自由式(II)所代表的：—Ar—，第一残基与选择自由式(III)所代表的单价残基：和自由式(IV)所代表的单价残基：—O—C(O)—R7—的两个相同或不同的第二残基结合。
• Carbonate ester stabilizers for polymers
  申请人：Argus Chemical Corporation

  公开号：US04104217A1

  公开（公告）日：1978-08-01

  This invention relates to a new class of polyhydric phenol carbonate esters and to synthetic resin stabilizer compositions comprising these esters as well as to synthetic resins stabilized with such esters and with stabilizer compositions comprising these esters along with known polymer stabilizers.

  本发明涉及一种新型的多羟基酚碳酸酯类化合物，以及包含这些酯类化合物的合成树脂稳定剂组合物，以及使用这些酯类化合物和稳定剂组合物稳定的合成树脂。同时，这些稳定剂组合物还包含已知的聚合物稳定剂。
• [EN] PROCESS FOR THE PREPARATION OF A COSMETIC ACTIVE<br/>[FR] PROCEDE POUR PREPARER UNE SUBSTANCE COSMETIQUE ACTIVE
  申请人：UNILEVER PLC

  公开号：WO2004052814A1

  公开（公告）日：2004-06-24

  A process for the preparation of one or more compounds of formula (I), wherein R1 is hydrogen or iso-alkyl and R2 is an iso-alkyl group; comprising the single step of reacting resorcinol with at least one secondary alcohol in the presence of a proton donor acid catalyst wherein the reaction is carried out in a water removing system.

  一种制备式(I)化合物的方法，其中R1为氢或异构烷基，R2为异构烷基；包括在去水系统中，在存在质子供体酸催化剂的情况下，通过将间苯二酚与至少一种二级醇反应的单一步骤来制备一种或多种化合物。
• Benzoic Acid Derivatives that are Modulators or Agonists of GlyR
  申请人：Gyback Helena

  公开号：US20090192190A1

  公开（公告）日：2009-07-30

  Compounds of formula I, wherein R1, Z, Y, M and R2 are as defined in the specification, pharmaceutically acceptable salts thereof, pharmaceutical composition containing the same, methods of using the same for therapeutic purposes and methods of making the same.

  公式I的化合物，其中R1、Z、Y、M和R2的定义如规范所述，其药学上可接受的盐，包含相同的制药组合物，使用相同的治疗目的的方法以及制造相同的方法。
• AROMATIC POLYESTER
  申请人：Muroran Institute of Technology

  公开号：EP2479203A1

  公开（公告）日：2012-07-25

  The present invention provides an aromatic polyester which is substantially free from the occurrence of coloration and retains significantly high transparency even after being thermally processed at high temperature and which has high flowability. The aromatic polyester contains a polyhydric phenol residue and a residue of any one of aromatic polycarboxylic acid, halide thereof, and anhydride thereof, and terminals of the aromatic polyester have a structure represented by the formula -C(O)-R. The aromatic polyester has an end-capping rate of 90% or higher and a weight average molecular weight (Mw) ranging from 3,000 to 1,000,000.

  本发明提供了一种芳香族聚酯，该聚酯基本上不会发生着色，即使在高温热加工后仍能保持明显的高透明度，并且具有高流动性。芳香族聚酯含有多羟基苯酚残留物和芳香族多羧酸、其卤化物和其酸酐中任意一种的残留物，芳香族聚酯的端基具有式 -C(O)-R 所代表的结构。芳香族聚酯的端盖率为 90% 或更高，重量平均分子量（Mw）为 3,000 至 1,000,000 之间。