4,4'-(3,3'-bipyridine-6,6'-diyl)bis(N,N-diphenylaniline) | 1365756-80-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4,4'-(3,3'-bipyridine-6,6'-diyl)bis(N,N-diphenylaniline)
• 英文别名: 4,4'-(3,3'-bipyridine-6,6'-diyl)bis(N,N-diphenylaniline)4-(5-{6-[4-(diphenylamino)phenyl]pyridin-3-yl}pyridin-2-yl)-N,N-diphenylaniline；N,N-diphenyl-4-[5-[6-[4-(N-phenylanilino)phenyl]pyridin-3-yl]pyridin-2-yl]aniline
• CAS: 1365756-80-4
• 化学式: C₄₆H₃₄N₄
• 分子量: 642.803
• InChiKey: JEHBHISLDYSKLX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.2
• 重原子数：
  50
• 可旋转键数：
  9
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  32.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-硼酸三苯胺 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 四(三苯基膦)钯 potassium acetate 、 sodium carbonate 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 水 为溶剂， 反应 151.0h， 生成 4,4'-(3,3'-bipyridine-6,6'-diyl)bis(N,N-diphenylaniline)
  参考文献：
  名称：

  [EN] SUBSTITUTED BIPYRIDINES FOR USE IN ORGANIC LIGHT-EMITTING DEVICES
  [FR] BIPYRIDINES SUBSTITUÉES DESTINÉES À ÊTRE UTILISÉES DANS DES DISPOSITIFS ÉLECTROLUMINESCENTS ORGANIQUES

  摘要：

  可选地取代的联吡啶化合物、可选地取代的苯基联吡啶化合物，或可选地取代的双苯基联吡啶化合物可能在发光器件中有用。一些示例包括但不限于：可选地取代的4-(5-(6-(4-(二苯胺基)苯基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺，可选地取代的9-(4-(5-(6-(4-(9H-咔唑-9-基)苯基)吡啶-3-基)吡啶-2-基)苯基)-9H-咔唑，可选地取代的4-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺，可选地取代的4-(5-(6-(苯并[d]噁唑-2-基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺，可选地取代的N,N-二苯基-4-(5-(6-(1-苯基-1H-苯并[d]咪唑-2-基)吡啶-3-基)吡啶-2-基)苯胺，可选地取代的4-(5-(6-(4-(9H-咔唑-9-基)苯基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺，可选地取代的2-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)苯并[d]噻唑，可选地取代的2-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)苯并[d]噁唑，可选地取代的9-(4-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)苯基)-9H-咔唑，可选地取代的9-(4-(5-(6-(苯并[d]噁唑-2-基)吡啶-3-基)吡啶-2-基)苯基)-9H-咔唑，可选地取代的9-(4-(6'-(1-苯基-1H-苯并[d]咪唑-2-基)-3,3'-联吡啶-6-基)苯基)-9H-咔唑，以及6,6'-双(9-苯基-9H-咔唑-3-基)-3,3'-联吡啶。

  公开号：

  WO2012037269A1

文献信息

• SUBSTITUTED BIPYRIDINES FOR USE IN ORGANIC LIGHT-EMITTING DEVICES
  申请人：Sisk David T.

  公开号：US20120179089A1

  公开（公告）日：2012-07-12

  Optionally substituted bipyridine compounds, optionally substituted phenylbipyridine compounds, or optionally substituted bis-phenylbipyridine compounds may be useful in light-emitting devices. Some examples include, but are not limited to, optionally substituted 4-(5-(6-(4-(diphenylamino)phenyl)pyridin-3-yl)pyridin-2-yl)-N,N-diphenylbenzenamine, optionally substituted 9-(4-(5-(6-(4-(9H-carbazol-9-yl)phenyl)pyridin-3-yl)pyridin-2-yl)phenyl)-9H-carbazole, optionally substituted 4-(5-(6-(benzo[d]thiazol-2-yl)pyridin-3-yl)pyridin-2-yl)-N,N-diphenylbenzenamine, optionally substituted 4-(5-(6-(benzo[d]oxazol-2-yl)pyridin-3-yl)pyridin-2-yl)-N,N-diphenylbenzenamine, optionally substituted N,N-diphenyl-4-(5-(6-(1-phenyl-1H-benzo[d]imidazol-2-yl)pyridin-3-yl)pyridin-2-yl)benzenamine, optionally substituted 4-(5-(6-(4-(9H-carbazol-9-yl)phenyl)pyridin-3-yl)pyridin-2-yl)-N,N-diphenylbenzenamine, optionally substituted 2-(5-(6-(benzo[d]thiazol-2-yl)pyridin-3-yl)pyridin-2-yl)benzo[d]thiazole, optionally substituted 2-(5-(6-(benzo[d]thiazol-2-yl)pyridin-3-yl)pyridin-2-yl)benzo[d]oxazole, optionally substituted 9-(4-(5-(6-(benzo[d]thiazol-2-yl)pyridin-3-yl)pyridin-2-yl)phenyl)-9H-carbazole, optionally substituted 9-(4-(5-(6-(benzo[d]oxazol-2-yl)pyridin-3-yl)pyridin-2-yl)phenyl)-9H-carbazole, optionally substituted 9-(4-(6′-(1-phenyl-1H-benzo[d]imidazol-2-yl)-3,3′-bipyridin-6-yl)phenyl)-9H-carbazole, and 6,6′-bis(9-phenyl-9H-carbazol-3-yl)-3,3′-bipyridine.

  可选取代的联吡啶化合物、可选取代的苯基联吡啶化合物或可选取代的双苯基联吡啶化合物可用于发光装置。一些例子包括但不限于可选取代的4-(5-(6-(4-(二苯胺)苯基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺、可选取代的9-(4-(5-(6-(4-(9H-咔唑-9-基)苯基)吡啶-3-基)吡啶-2-基)苯基)-9H-咔唑、可选取代的4-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺、可选取代的4-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺、可选取代的N,N-二苯基-4-(5-(6-(1-苯基-1H-苯并[d]咪唑-2-基)吡啶-3-基)吡啶-2-基)苯胺、可选取代的4-(5-(6-(4-(9H-咔唑-9-基)苯基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺、可选取代的2-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)苯并[d]噻唑、可选取代的2-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)苯并[d]噁唑、可选取代的9-(4-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)苯基)-9H-咔唑、可选取代的9-(4-(5-(6-(苯并[d]噁唑-2-基)吡啶-3-基)吡啶-2-基)苯基)-9H-咔唑、可选取代的9-(4-(6′-(1-苯基-1H-苯并[d]咪唑-2-基)-3,3′-联吡啶-6-基)苯基)-9H-咔唑和6,6′-双(9-苯基-9H-咔唑-3-基)-3,3′-联吡啶。
• Substituted bipyridines for use in organic light-emitting devices
  申请人：Sisk David T.

  公开号：US09328086B2

  公开（公告）日：2016-05-03

  Optionally substituted bipyridine compounds, optionally substituted phenylbipyridine compounds, or optionally substituted bis-phenylbipyridine compounds may be useful in light-emitting devices. Some examples include, but are not limited to, optionally substituted 4-(5-(6-(4-(diphenylamino)phenyl)pyridin-3-yl)pyridin-2-yl)-N,N-diphenylbenzenamine, optionally substituted 9-(4-(5-(6-(4-(9H-carbazol-9-yl)phenyl)pyridin-3-yl)pyridin-2-yl)phenyl)-9H-carbazole, optionally substituted 4-(5-(6-(benzo[d]thiazol-2-yl)pyridin-3-yl)pyridin-2-yl)-N,N-diphenylbenzenamine, optionally substituted 4-(5-(6-(benzo[d]oxazol-2-yl)pyridin-3-yl)pyridin-2-yl)-N,N-diphenylbenzenamine, optionally substituted N,N-diphenyl-4-(5-(6-(1-phenyl-1H-benzo[d]imidazol-2-yl)pyridin-3-yl)pyridin-2-yl)benzenamine, optionally substituted 4-(5-(6-(4-(9H-carbazol-9-yl)phenyl)pyridin-3-yl)pyridin-2-yl)-N,N-diphenylbenzenamine, optionally substituted 2-(5-(6-(benzo[d]thiazol-2-yl)pyridin-3-yl)pyridin-2-yl)benzo[d]thiazole, optionally substituted 2-(5-(6-(benzo[d]thiazol-2-yl)pyridin-3-yl)pyridin-2-yl)benzo[d]oxazole, optionally substituted 9-(4-(5-(6-(benzo[d]thiazol-2-yl)pyridin-3-yl)pyridin-2-yl)phenyl)-9H-carbazole, optionally substituted 9-(4-(5-(6-(benzo[d]oxazol-2-yl)pyridin-3-yl)pyridin-2-yl)phenyl)-9H-carbazole, optionally substituted 9-(4-(6′-(1-phenyl-1H-benzo[d]imidazol-2-yl)-3,3′-bipyridin-6-yl)phenyl)-9H-carbazole, and 6,6′-bis(9-phenyl-9H-carbazol-3-yl)-3,3′-bipyridine.

  可选取代的联吡啶化合物、可选取代的苯基联吡啶化合物或可选取代的双苯基联吡啶化合物可用于发光装置中。一些例子包括但不限于：可选取代的4-(5-(6-(4-(二苯胺基)苯基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺、可选取代的9-(4-(5-(6-(4-(9H-咔唑-9-基)苯基)吡啶-3-基)吡啶-2-基)苯基)-9H-咔唑、可选取代的4-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺、可选取代的4-(5-(6-(苯并[d]噁唑-2-基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺、可选取代的N,N-二苯基-4-(5-(6-(1-苯基-1H-苯并[d]咪唑-2-基)吡啶-3-基)吡啶-2-基)苯胺、可选取代的4-(5-(6-(4-(9H-咔唑-9-基)苯基)吡啶-3-基)吡啶-2-基)-N,N-二苯基苯胺、可选取代的2-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)苯并[d]噻唑、可选取代的2-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)苯并[d]噁唑、可选取代的9-(4-(5-(6-(苯并[d]噻唑-2-基)吡啶-3-基)吡啶-2-基)苯基)-9H-咔唑、可选取代的9-(4-(5-(6-(苯并[d]噁唑-2-基)吡啶-3-基)吡啶-2-基)苯基)-9H-咔唑、可选取代的9-(4-(6′-(1-苯基-1H-苯并[d]咪唑-2-基)-3,3′-联吡啶-6-基)苯基)-9H-咔唑和6,6′-双(9-苯基-9H-咔唑-3-基)-3,3′-联吡啶。
• Pyridines and derivatives thereof as components for use in optoelectronic components
  申请人：CYNORA GMBH

  公开号：US10544361B2

  公开（公告）日：2020-01-28

  The invention relates to an organic molecule comprising a structure of formula 1 and to the use thereof in optoelectronic components. wherein: X is SO2, CO or a C—C single bond; m is 0 or 1; n is 1, 2 or 3; r is 0 or 1; s is 0 or 1; LG is a divalent linker group, selected from: or LG is an element-element single bond.

  本发明涉及一种包含式 1 结构的有机分子及其在光电元件中的应用。 其中 X 是 SO2、CO 或 C-C 单键； m 是 0 或 1 n 是 1、2 或 3 r 为 0 或 1 s 为 0 或 1； LG 是二价连接基团，选自以下各项 或 LG 是元素-元素单键。
• AMBIPOLAR HOST IN ORGANIC LIGHT EMITTING DIODE
  申请人：Nitto Denko Corporation

  公开号：EP2393900A1

  公开（公告）日：2011-12-14
• PYRIDINE UND DEREN DERIVATE ALS BAUSTEINE ZUR VERWENDUNG IN OPTOELEKTRONISCHEN BAUELEMENTEN
  申请人：CYNORA GMBH

  公开号：EP3247771B1

  公开（公告）日：2020-06-10