4,8-dihydroxy-1,5-diformylnaphthalene | 128038-46-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4,8-dihydroxy-1,5-diformylnaphthalene
• 英文别名: 4,8-dihydroxynaphthalene-1,5-dicarbaldehyde
• CAS: 128038-46-0
• 化学式: C₁₂H₈O₄
• 分子量: 216.193
• InChiKey: KSVFSJKOEWWVTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4,8-dihydroxy-1,5-diformylnaphthalene 在 偶氮二甲酸二异丙酯 、 间氯过氧苯甲酸 、 三苯基膦 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 生成 Formic acid 5-formyloxy-4,8-bis-((1R,3R)-4,4,4-trifluoro-3-hydroxy-1-methyl-butoxy)-naphthalen-1-yl ester
  参考文献：
  名称：

  Long-Range Electrostatic Effects in Synthesis: Dipole-Controlled Nucleophilic Addition to a Naphthoquinone Acetal in Model Studies toward Diepoxinσ

  摘要：

  DOI：

  10.1002/anie.199707641
• 作为产物：
  描述：

  1,5-二甲氧基萘 在 三溴化硼 、 四氯化钛 作用下， 以 二氯甲烷 、 1,2-二氯乙烷 为溶剂， 生成 4,8-dihydroxy-1,5-diformylnaphthalene
  参考文献：
  名称：

  Long-Range Electrostatic Effects in Synthesis: Dipole-Controlled Nucleophilic Addition to a Naphthoquinone Acetal in Model Studies toward Diepoxinσ

  摘要：

  DOI：

  10.1002/anie.199707641

文献信息

• Tregub, N. G.; Knyazev, A. P.; Mezheritskii, V. V., Journal of Organic Chemistry USSR (English Translation), 1990, vol. 26, # 1.2, p. 143 - 146
  作者：Tregub, N. G.、Knyazev, A. P.、Mezheritskii, V. V.

  DOI：——

  日期：——
• Spectral and quantum-chemical investigation of ortho- and peri-hydroxy-substituted mono- and diformyl derivatives of 1,5-naphthalenediol
  作者：V. V. Mezheritskii、M. S. Korobov、O. M. Golyanskaya、N. I. Omelichkin、L. G. Minyaeva、G. S. Borodkin、A. A. Milov、A. V. Tsukanov、A. D. Dubonosov

  DOI：10.1134/s1070428012020233

  日期：2012.2

  Spectral and quantum-chemical investigation of ortho- and peri-hydroxy-substituted aldehydes, 1,5-naphthalenediol derivatives, was carried out. An unusual spin-spin coupling through an intramolecular hydrogen bond was discovered in the molecule of 1,5-dihydroxynaphthalene-4,8-dicarbaldehyde. It was shown that this dialdehyde is involved into the ring-chain tautomerism. The position of this equilibrium was examined depending on the temperature and the solvent polarity. The effect of the solvent polarity on the benzoid-quinoid tautomerism in the dihydroxynaphthalene-2,6-dicarbaldehyde was established. By the method of quantum-chemical calculations the relative energy stability and conformational structure of dialdehydes were revealed.
• TREGUB, N. G.;KNYAZEV, A. P.;MEZHERITSKIJ, V. V., ZH. ORGAN. XIMII, 26,(1990) N, S. 168-172
  作者：TREGUB, N. G.、KNYAZEV, A. P.、MEZHERITSKIJ, V. V.

  DOI：——

  日期：——
• Structure of 4,8-dihydroxynaphthalene-1,5-dicarbaldehyde by the data of 1H NMR Spectroscopy. Spin-spin coupling through a hydrogen bond
  作者：V. V. Mezheritskii、O. M. Golyanskaya、N. I. Omelichkin、L. G. Minyaeva、M. S. Korobov

  DOI：10.1134/s1070428011080276

  日期：2011.8
• HETEROPYRENE-BASED SEMICONDUCTOR MATERIALS FOR ELECTRONIC DEVICES AND METHODS OF MAKING THE SAME
  申请人：Shukla Deepak

  公开号：US20090001353A1

  公开（公告）日：2009-01-01

  A thin layer of organic semiconductor material comprising a comprising an organic semiconductor thin film material is disclosed in which the thin film material substantially comprises a heteropyrene compound or derivative. In one embodiment, a thin film transistor comprises a layer of the organic semiconductor material. Further disclosed is a process for fabricating an organic thin-film transistor device, preferably by relative low-temperature sublimation or solution-phase deposition onto a substrate.