2,2-bis(3-methyl-4-(4-aminophenoxy)phenyl)propane | 79282-12-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis(3-methyl-4-(4-aminophenoxy)phenyl)propane
• 英文别名: 4-[4-[2-[4-(4-Aminophenoxy)-3-methylphenyl]propan-2-yl]-2-methylphenoxy]aniline
• CAS: 79282-12-5
• 化学式: C₂₉H₃₀N₂O₂
• 分子量: 438.569
• InChiKey: ALFOPRUBEYLKCR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  70.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4,4'-(1-甲基亚乙基)双(2-甲基苯酚) 在 sodium carbonate 、 溶剂黄146 、 锌 作用下， 生成 2,2-bis(3-methyl-4-(4-aminophenoxy)phenyl)propane
  参考文献：
  名称：

  Smolinski,S.; Halasa,E., Roczniki Chemii, 1974, vol. 48, p. 1459 - 1468

  摘要：

  DOI：

文献信息

• Olefin block copolymers processes for producing the same and uses thereof
  申请人：——

  公开号：US20030055179A1

  公开（公告）日：2003-03-20

  The present invention provides polymers having any one of properties including affinity for metals or polar resins, impact resistance, mar resistance, heat resistance, rigidity, oil resistance, transparency, anti-fogging properties, electric insulating properties, high breakdown voltage, coating properties, low-temperature flexibility, moldability, environmental degradation, fluidity and dispersibility, and provides a process for preparation thereof. The olefin block copolymers (A-1) of the invention are represented by the formula (I) PO 1 —g 1 —B 1 (I) (wherein PO 1 is a segment composed of repeating units derived from an olefin having 2 to 20 carbon atoms, g 1 is an ester, ether, amide, imide, urethane, urea, silylether or carbonyl linkage, and B 1 is a segment containing an unsaturated hydrocarbon or a hetero atom). The olefin block copolymers are suitable for uses in adhesives; various molded articles such as construction and civil engineering materials, automobile interior and exterior materials, gasoline tanks, electric and electronic parts, medical care and sanitation materials, materials of miscellaneous goods, resin materials having environmental degradation properties, films and sheets; modifiers and dispersions.

  本发明提供了具有以下任一性质的聚合物，包括对金属或极性树脂的亲和性，抗冲击性，抗刮伤性，耐热性，刚度，耐油性，透明性，防雾性能，电绝缘性能，高击穿电压，涂料性能，低温柔性，可塑性，环境降解性，流动性和分散性，并提供其制备方法。本发明的烯烃嵌段共聚物（A-1）由公式（I）表示：PO1-g1-B1（I）（其中PO1是由具有2至20个碳原子的烯烃衍生的重复单元组成的片段，g1是酯，醚，酰胺，亚胺，脲，硅醚或羰基连接，B1是含有不饱和碳氢化合物或杂原子的片段）。烯烃嵌段共聚物适用于粘合剂；各种成型品，如建筑和土木工程材料，汽车内外饰料，汽油箱，电子和电气零件，医疗保健和卫生材料，杂货物料，具有环境降解性能的树脂材料，薄膜和片材；改性剂和分散剂。
• Ether imides and process for producing the same
  申请人：Hitachi, Ltd.

  公开号：EP0032745A2

  公开（公告）日：1981-07-29

  An ether imide of the formula: wherein R1, R2, R3, R4, R5, R6 and D are as defined in the specification produced by reacting a diamine with an ethylenically unsaturated dicarboxylic acid can give a composition together with one or more unsaturated polyesters, epoxy compounds, amines, and the like to give shaped ar- ticies excellent in flexibility and heat resistance.

  式中的醚酰亚胺 其中 R1、R2、R3、R4、R5、R6 和 D 如说明书中所定义，由二元胺与乙烯基不饱和二羧酸反应而制得，可与一种或多种不饱和聚酯、环氧化合物、胺等一起制成一种组合物，从而得到具有优异柔韧性和耐热性的成型材料。
• Organic-solvent soluble polyimide and production thereof
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP0336536A2

  公开（公告）日：1989-10-11

  A solvent-soluble polyimide obtained from an exo-form dicarboxylic acid anhydride of formula (I) wherein X is S or SO₂, with an aromatic diamine in a polar solvent, followed by dehydration ring closure with an aromatic diamine, e.g. 2,2,-bis[4-(4-aminophenoxy)phenyl]­propase has improved film-forming properties and transparency, and is particularly suitable for producing an orientation controlling film in a liquid crystal display device.

  由式（I）（其中 X 为 S 或 SO₂）的外型二羧酸酐与芳香族二胺在极性溶剂中反应，然后与芳香族二胺（如 2,2,-双[4-(4-氨基苯氧基)苯基]丙酸酯）脱水封环得到的溶剂可溶聚酰亚胺具有更好的成膜性能和透明度，特别适合用于生产液晶显示设备中的定向控制膜。
• Curable resins, their preparation, and protective coatings for electronic parts
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP0448359A1

  公开（公告）日：1991-09-25

  A curable resin comprising a resin of the formula wherein R¹ and R² each are substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, R³ is a divalent organic group having 1 to 10 carbon atoms, X is a tetravalent organic group having an aromatic ring, Y is a divalent organic group, m is an integer of 1 to 3, and n is an integer of at least 1. The resin is prepared by reacting a polyimide with an aminosilicon compound and can be cured through relatively mild heating into coatings having enhanced substrate adherence and solvent resistance.

  一种可固化树脂，由以下式子的树脂组成 其中 R¹ 和 R² 分别是具有 1 至 10 个碳原子的取代或未取代的一价烃基，R³ 是具有 1 至 10 个碳原子的二价有机基团，X 是具有芳香环的四价有机基团，Y 是二价有机基团，m 是 1 至 3 的整数，n 是至少 1 的整数。该树脂是通过聚酰亚胺与氨基硅化合物反应制备的，可通过相对温和的加热固化成具有更强基材附着力和耐溶剂性的涂层。
• Photosensitive polymer composition
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP0505161A1

  公开（公告）日：1992-09-23

  A photosensitive polymer composition comprising, in admixture, a polymer predominantly comprising a recurring unit of the formula ( I ): wherein X is a tri- or tetravalent organic group, Y is a divalent organic group, and n is equal to 1 or 2 and a compound having a urea bond of the formula ( II ): wherein R¹ is a group having a functional group capable of forming a dimer or polymer upon exposure to radiation, R² and R³ are independently a hydrogen atom or a monovalent organic group is shelf stable and applicable as relatively thick coatings having sufficient photosensitivity to form semiconductor element surface protective films.

  一种光敏聚合物组合物，包括主要由式 ( I ) 循环单元组成的聚合物： 其中 X 是三价或四价有机基团，Y 是二价有机基团，n 等于 1 或 2，以及具有式 ( II ) 脲键的化合物： 其中 R¹ 是具有官能团的基团，该官能团在暴露于辐射时能够形成二聚体或聚合物，R² 和 R³ 独立地为氢原子或一价有机基团。