5,5'-dibromo-4,4'-(6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-pentadecafluorododecyl)-2,2'-bithiophene | 1529770-44-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 5,5'-dibromo-4,4'-(6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-pentadecafluorododecyl)-2,2'-bithiophene
• 英文别名: 4,4'-Bis(6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-pentadecafluorododecyl)-5,5'-dibromo-2,2'-bithiophene；2-bromo-5-[5-bromo-4-(6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-pentadecafluorododecyl)thiophen-2-yl]-3-(6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-pentadecafluorododecyl)thiophene
• CAS: 1529770-44-2
• 化学式: C₃₂H₂₂Br₂F₃₀S₂
• 分子量: 1200.42
• InChiKey: UCPDKRXXFZBFSK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.4
• 重原子数：
  66
• 可旋转键数：
  23
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  32

反应信息

• 作为产物：
  描述：

  magnesium,pent-1-ene,bromide 在 potassium fluoride 、 sodium tetrahydroborate 、 N-溴代丁二酰亚胺(NBS) 、 二(氰基苯)二氯化钯 、 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 、 偶氮二异丁腈 、 silver nitrate 、 溶剂黄146 作用下， 以 乙醚 、 氯仿 、 二甲基亚砜 、 1,2-二氯乙烷 为溶剂， 生成 5,5'-dibromo-4,4'-(6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-pentadecafluorododecyl)-2,2'-bithiophene
  参考文献：
  名称：

  一种具有半氟化烷基链的新型热可逆可溶不溶共轭聚合物：通过疏水性自组织和正交疏水构图增强了晶体管的性能

  摘要：

  SFA-PQT通过在无氟溶剂中的疏水作用表现出自组装性，从而提高了电气性能。SFA-PQT具有独特的热可逆可溶不溶特性，可实现具有p型和n型双层的双极性晶体管和反相器。更重要的是，SFA-PQT的疏水性有利于正交疏水性图案化，而图案化的反相器则具有低电压耗散，狭窄的过渡区，高增益值和可忽略的滞后性。

  DOI：

  10.1002/adma.201301337

文献信息

• SEMI-FLUOROALKYL GROUP SUBSTITUTED ORGANIC SEMICONDUCTOR POLYMER AND ORGANIC THIN FILM TRANSISTOR INCLUDING THE SAME
  申请人：GWANGJU INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20140110689A1

  公开（公告）日：2014-04-24

  A semi-fluoroalkyl group substituted organic semiconductor polymer and an organic thin film transistor including the same are disclosed. A structure in which hydrogen of only a terminal of an alkyl group is substituted with fluorine exhibits significantly increased hole mobility, and significantly improved properties in terms of thermal stability and chemical stability, as compared to a structure in which all hydrogens coupled to a thiophene ring are substituted with fluorine, or a structure in which hydrogen of the terminal thereof is not substituted with fluorine and only hydrogens of the remaining portion are coupled to the thiophene ring.
• US9065056B2
  申请人：——

  公开号：US9065056B2

  公开（公告）日：2015-06-23
• A Novel Thermally Reversible Soluble-Insoluble Conjugated Polymer with Semi-Fluorinated Alkyl Chains: Enhanced Transistor Performance by Fluorophobic Self-Organization and Orthogonal Hydrophobic Patterning
  作者：Hyung-Gu Jeong、Bogyu Lim、Dongyoon Khim、Mingu Han、Jaewon Lee、Juhwan Kim、Jin-Mun Yun、Kilwon Cho、Ji-Woong Park、Dong-Yu Kim

  DOI：10.1002/adma.201301337

  日期：2013.11

  self‐assembly via a fluorophobic effect in a non‐fluorous solvent, which leads to an enhanced electrical performance. Ambipolar transistors and inverters with p‐ and n‐ type bilayers are enabled by the unique thermally reversible soluble‐insoluble properties of SFA‐PQT. More importantly, the hydrophobicity of SFA‐PQT facilitates orthogonal hydrophobic patterning and a patterned inverter exhibits low

  SFA-PQT通过在无氟溶剂中的疏水作用表现出自组装性，从而提高了电气性能。SFA-PQT具有独特的热可逆可溶不溶特性，可实现具有p型和n型双层的双极性晶体管和反相器。更重要的是，SFA-PQT的疏水性有利于正交疏水性图案化，而图案化的反相器则具有低电压耗散，狭窄的过渡区，高增益值和可忽略的滞后性。