4-octyl-2,6-bispyrazolylpyridine | 1369968-56-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-octyl-2,6-bispyrazolylpyridine
• 英文别名: 4-[4-[4-[4-[2,6-Bis(4-octylpyrazol-1-yl)pyridin-4-yl]phenyl]phenyl]phenyl]-2,6-bis(4-octylpyrazol-1-yl)pyridine
• CAS: 1369968-56-8
• 化学式: C₇₂H₉₂N₁₀
• 分子量: 1097.59
• InChiKey: SOCCOWPJETWAHP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  23.7
• 重原子数：
  82
• 可旋转键数：
  36
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  97.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  ferrous perchlorate 、 4-octyl-2,6-bispyrazolylpyridine 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Lithographically organized 1D nano-tape arrays composed of solution processable above room temperature spin cross-over Fe(ii) coordination polymer

  摘要：

  一种新型、高溶解度和可溶液加工的铁（II）自旋交叉（SCO）配位聚合物显示出SCO温度为T1/2 ∼ 302 K。这种超分子聚合物在THF-水中的自组装形成了几微米长的纳米带网络。进一步使用光刻控制的润湿技术进行溶液加工，产生了有序的SCO纳米带束一维阵列。

  DOI：

  10.1039/c4ra06726f
• 作为产物：
  描述：

  4,4''-二碘对三联苯 在 四(三苯基膦)钯 、 正丁基锂 、 sodium carbonate 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 正己烷 为溶剂， 反应 73.25h， 生成 4-octyl-2,6-bispyrazolylpyridine
  参考文献：
  名称：

  Micropatterning of Metallopolymers: Syntheses of Back-to-Back Coupled Octylated 2,6-Bis(pyrazolyl)pyridine Ligands and Their Solution-Processable Coordination Polymers

  摘要：

  This paper presents a 10-step synthetic route for the preparation of a series of new back-to-back coupled 2,6-bis(pyrazol-l-yl)pyridine (bpp) ligands (L0-L3) decorated with tetraoctyl chains. Ligand L1 self-assembles with Zn2+ ion to form a highly soluble metallo-supramolecular polymer 1 with M-n similar to 9600 g/mol. To demonstrate the processability of polymer 1, by following a "top-down" approach periodic one-dimensional fluorescent microstripes were fabricated on a silica substrate.

  DOI：

  10.1021/jo300050m

文献信息

• Micropatterning of Metallopolymers: Syntheses of Back-to-Back Coupled Octylated 2,6-Bis(pyrazolyl)pyridine Ligands and Their Solution-Processable Coordination Polymers
  作者：Supratim Basak、Pramiti Hui、Sathyanarayana Boodida、Rajadurai Chandrasekar

  DOI：10.1021/jo300050m

  日期：2012.4.6

  This paper presents a 10-step synthetic route for the preparation of a series of new back-to-back coupled 2,6-bis(pyrazol-l-yl)pyridine (bpp) ligands (L0-L3) decorated with tetraoctyl chains. Ligand L1 self-assembles with Zn2+ ion to form a highly soluble metallo-supramolecular polymer 1 with M-n similar to 9600 g/mol. To demonstrate the processability of polymer 1, by following a "top-down" approach periodic one-dimensional fluorescent microstripes were fabricated on a silica substrate.
• Lithographically organized 1D nano-tape arrays composed of solution processable above room temperature spin cross-over Fe(<scp>ii</scp>) coordination polymer
  作者：Ajay Kumar Botcha、Supratim Basak、Rajadurai Chandrasekar

  DOI：10.1039/c4ra06726f

  日期：——

  A novel, highly soluble and solution processable Fe(II) spin cross-over (SCO) coordination polymer shows an SCO temperature at T1/2 ∼ 302 K. Bottom-up self-assembly of this supramolecular polymer in THF–water formed a several micron long nano-tape network. Further solution processing using a lithographically controlled wetting technique produced aligned 1D arrays of SCO nano-tape bundles.

  一种新型、高溶解度和可溶液加工的铁（II）自旋交叉（SCO）配位聚合物显示出SCO温度为T1/2 ∼ 302 K。这种超分子聚合物在THF-水中的自组装形成了几微米长的纳米带网络。进一步使用光刻控制的润湿技术进行溶液加工，产生了有序的SCO纳米带束一维阵列。