1-[4-(3-N,N-diethylaminopropyl)phenyl]-1-phenylethylene | 929220-09-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-[4-(3-N,N-diethylaminopropyl)phenyl]-1-phenylethylene
• 英文别名: N,N-Diethyl-3-[4-(1-phenylethenyl)phenyl]propan-1-amine；N,N-diethyl-3-[4-(1-phenylethenyl)phenyl]propan-1-amine
• CAS: 929220-09-7
• 化学式: C₂₁H₂₇N
• 分子量: 293.452
• InChiKey: PPWUSVFSUIGEJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-溴-3-苯基丙烷 在 三氯化铝 、 potassium tert-butylate 、 potassium carbonate 作用下， 以 四氢呋喃 、 乙腈 为溶剂， 反应 46.83h， 生成 1-[4-(3-N,N-diethylaminopropyl)phenyl]-1-phenylethylene
  参考文献：
  名称：

  Synthesis of Block Copolymers and Asymmetric Star-Branched Polymers Comprised of Polyacetylene and Polystyrene Segments via Ionic Bond Formation

  摘要：

  Novel ion-bonded AB diblock copolymers and three-arm AB(2) asymmetric star-branched polymers comprised of polyacetylene (A) and polystyrene (B) segments have been synthesized by the stoichiometric reaction of tert-amine-chain-end-functionalized poly(phenyl vinyl sulfoxide)s with either chain-end- or in-chain-carboxylated polystyrenes to link the two polymer segments via ionic bond, followed by thermal treatment to convert their poly(phenyl vinyl sulfoxide)s to polyacetylene segments. Periodic lamellar morphologies were observed in the cast films of such polymers by TEM measurement. The isolation of the nano-size sheet consisting of polyacetylene lamellar layers was attempted.

  DOI：

  10.1007/s00706-006-0482-4

文献信息

• Synthesis of Block Copolymers and Asymmetric Star-Branched Polymers Comprised of Polyacetylene and Polystyrene Segments via Ionic Bond Formation
  作者：Kenji Sugiyama、Yasunori Karasawa、Tomoya Higashihara、Youling Zhao、Akira Hirao

  DOI：10.1007/s00706-006-0482-4

  日期：2006.7

  Novel ion-bonded AB diblock copolymers and three-arm AB(2) asymmetric star-branched polymers comprised of polyacetylene (A) and polystyrene (B) segments have been synthesized by the stoichiometric reaction of tert-amine-chain-end-functionalized poly(phenyl vinyl sulfoxide)s with either chain-end- or in-chain-carboxylated polystyrenes to link the two polymer segments via ionic bond, followed by thermal treatment to convert their poly(phenyl vinyl sulfoxide)s to polyacetylene segments. Periodic lamellar morphologies were observed in the cast films of such polymers by TEM measurement. The isolation of the nano-size sheet consisting of polyacetylene lamellar layers was attempted.