1-benzoylamino-2,2-bis[p-chlorophenylthio]ethenyl(triphenyl)phosphonium chloride | 76621-65-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-benzoylamino-2,2-bis[p-chlorophenylthio]ethenyl(triphenyl)phosphonium chloride
• 英文别名: [1-Benzamido-2,2-bis[(4-chlorophenyl)sulfanyl]ethenyl]-triphenylphosphanium;chloride
• CAS: 76621-65-3
• 化学式: C₃₉H₂₉Cl₂NOPS₂*Cl
• 分子量: 729.13
• InChiKey: OZEHUFJRWSHGGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.43
• 重原子数：
  47
• 可旋转键数：
  10
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  79.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-benzoylamino-2,2-bis[p-chlorophenylthio]ethenyl(triphenyl)phosphonium chloride 在 sodium hydroxide 、 sodium perchlorate 、 silver carbonate 作用下， 以 甲醇 、 水 为溶剂， 反应 21.0h， 生成 5-[(4-Chlorophenyl)sulfanyl]-2-phenyl-1,3-oxazole
  参考文献：
  名称：

  Brovarets, V. S.; Lobanov, O.P.; Drach, B. S., Journal of general chemistry of the USSR, 1983, vol. 53, # 9, p. 1819 - 1823

  摘要：

  DOI：
• 作为产物：
  描述：

  1-benzoylamino-2,2-dichloroethenyltriphenylphosphonium chloride 、 4-氯苯硫酚 在 三乙胺 作用下， 生成 1-benzoylamino-2,2-bis[p-chlorophenylthio]ethenyl(triphenyl)phosphonium chloride
  参考文献：
  名称：

  Brovarets, V. S.; Lobanov, O.P.; Drach, B. S., Journal of general chemistry of the USSR, 1983, vol. 53, # 9, p. 1819 - 1823

  摘要：

  DOI：

文献信息

• Thermoplastic molding material and moulded bodies produced therefrom
  申请人：Papke Nicolai

  公开号：US20050119396A1

  公开（公告）日：2005-06-02

  A thermoplastic molding composition is described comprising a) from 20 to 99% by weight of a thermoplastic polymer other than a polyoxymethylene homo- or copolymer, from 0.1 to 80% by weight of a filler and/or reinforcing material, and c) 0.00001 to 1.0% by weight of a catalyst which catalyzes the formation of covalent bonds between the thermoplastic polymer and the surface of the additive. The inventive molding compositions have improved properties.

  本发明描述了一种热塑性模塑组合物，该组合物包括 a) 20-99%（按重量计）的热塑性聚合物（聚甲醛均聚物或共聚物除外），0.1-80%（按重量计）的填料和/或增强材料，以及 c) 0.00001-1.0%（按重量计）的催化剂，该催化剂可催化热塑性聚合物与添加剂表面之间共价键的形成。本发明的模塑组合物具有更好的性能。
• Polyoxymethylene molding compound and molded body produced therefrom
  申请人：Papke Nicolai

  公开号：US20050107513A1

  公开（公告）日：2005-05-19

  The invention relates to a polyacetal molding compound that contains a polyacetal homo- or copolymer, an additive and 0.0001% by weight to 1.0% by weight of a substance that catalyzes a chemical reaction between the polyacetal matrix polymer and the surface of the additive, and that contains the element Bor and is no Brønsted acid.

  本发明涉及一种聚缩醛模塑化合物，它含有聚缩醛均聚物或共聚物、添加剂和 0.0001%（重量）至 1.0%（重量）的物质，这种物质可催化聚缩醛基体聚合物与添加剂表面之间的化学反应，它含有 Bor 元素，并且不是布氏酸。
• Lobanov, O. P.; Martynyuk, A. P.; Drach, B. S., Journal of general chemistry of the USSR, 1980, vol. 50, p. 1816 - 1824
  作者：Lobanov, O. P.、Martynyuk, A. P.、Drach, B. S.

  DOI：——

  日期：——
• ——
  作者：S. G. Pil'o

  DOI：10.1023/a:1023333011230

  日期：——

  Enamides of the general formula Cl2C=C(X)NHCOR1, where X = CN, COOAlk, CONH2, P(O)(OEt)(2), P(O)Ph-2, PPh3 Cl-, were treated in succession with alkane- or arenethiols and silver carbonate to obtain 5-alkyl(aryl)thio-2-R-1-4-X-1,3-oxazoles with high selectivity. The latter were converted into the corresponding sulfonyl derivatives. Unlike 2-acylamino-3,3-dichloroacrylonitriles which react with sodium hydrogen sulfide in a nonselective fashion, reactions of derivatives like Cl(ArS)C=C(CN)NHCOR1 with NaHS lead to hitherto unknown 5-arylthio-4-thiocarbamoyl-2-R-1-1,3-oxazoles whose structure was confirmed both by spectral methods and by cyclocondensation with bromoacetophenone according to Hantzsch. Heating of some 2-aryl-5-mercapto-4-X-1,3-oxazoles with benzenethiols results in recyclization into the corresponding 2,4-disubstituted 5-arylthio-1,3-thiazoles, presumably due to prototropic tautomerism in the 5-mercapto-oxazole fragment.
• EP1483333A1
  申请人：——

  公开号：EP1483333A1

  公开（公告）日：2004-12-08