2-chlor(4'-chlor)-perfluorostyren | 101306-34-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-chlor(4'-chlor)-perfluorostyren
• 英文别名: 4-chloro-α-chlorohexafluorostyrene；α-chloro-p-chloroperfluorostyrene；p-Chloro-α-chlorohexafluorostyrol；4,α-dichloro-perfluoro-styrene；4-Chloro-alpha-chlorohexafluorostyrene；1-chloro-4-(1-chloro-2,2-difluoroethenyl)-2,3,5,6-tetrafluorobenzene
• CAS: 101306-34-7
• 化学式: C₈Cl₂F₆
• 分子量: 280.984
• InChiKey: NYHAGWKXWXYHID-UHFFFAOYSA-N

物化性质

• 沸点：
  192.3±35.0 °C(Predicted)
• 密度：
  1.671±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-chlor(4'-chlor)-perfluorostyren 生成 4-(α,α,β-trichlorodifluoroethyl)chlorotetrafluorobenzene
  参考文献：
  名称：

  Dwornikowa K. W., Platonow W. E., Isw. AN. Ser. khim, (1994) N 12, S 2199-2202

  摘要：

  DOI：
• 作为产物：
  描述：

  4-(α,α,β-trichlorodifluoroethyl)chlorotetrafluorobenzene 、 氟里昂-22 生成 2-chlor(4'-chlor)-perfluorostyren
  参考文献：
  名称：

  Dwornikowa K. W., Platonow W. E., Isw. AN. Ser. khim, (1994) N 12, S 2199-2202

  摘要：

  DOI：

文献信息

• Thermolytic transformations of polyfluoroorganic compounds XXIX. Formation of fluorine-containing styrenes by reactions of benzotrichloride and related compounds with dihalocarbene sources
  作者：K.V. Dvornikova、V.E. Platonov、G.G. Yakobson

  DOI：10.1016/s0022-1139(00)85196-9

  日期：1985.5

  Reactions of polyfluorobenzotrichlorides, benzotrichloride and α,α-dichloroperfluoroethylbenzene with sources of difluorocarbene and other dihalocarbenes lead to the formation of polyfluorostyrenes. Formation of polyfluorostyrenes is shown to proceed possibly by initial dihalocarbene insertion into the CCl bond of the benzylic position with subsequent dechlorination of the resulting product.

  多氟苯并三氯化物，苯并三氯化物和α，α-二氯全氟乙基苯与二氟卡宾和其他二卤卡宾的来源的反应导致形成多氟苯乙烯。已表明可能通过首先将二卤卡宾插入苄基位置的CCl键并随后将所得产物脱氯来进行聚氟苯乙烯的形成。
• Reaktionen terminaler Perfluoralkene mit Diaminen und Diphenolen
  作者：Wolfgang Bürger、Klaus Lunkwitz

  DOI：10.1016/s0022-1139(00)80026-3

  日期：1993.2

  Model compounds related to the reaction products of perfluoroalkenes produced by the electron-beam irradiation of poly(tetrafluoroethylene) with dinucleophilic reactants have been synthesized. Such model compounds, in reaction with diphenols or diamines, give information relating to the mechanism of crosslinking reactions. Results obtained with perfluorohept-1-ene show that terminal perfluoroalkenes react preferentially with dinucleophilic reactants to give unsaturated ether and amide structures.
• Thermolytic transformations of polyfluoroorganic compounds
  作者：K. V. Dvornikova、V. E. Platonov

  DOI：10.1007/bf00700174

  日期：1994.12

  Copyrolysis of 4-chlorotetrafluorobenzotrichloride with chlorodifluoromethane (as the source of difluorocarbene) gave 4-chlorodifluoromethyl-alpha-chlorohexafluorostyrene, 1,4-dichlorotetrafluorobenzene, and 4-(chlorodifluoromethyl)chlorotetrafluorobenzene along with 4-chloro-alpha-chlorohexafluorostyrene. Possible routes for the formation of these products have been offered.
• DVORNIKOVA, K. V.;PLATONOV, V. E.;YAKOBSON, G. G., J. FLUOR. CHEM., 1985, 28, N 1, 99-113
  作者：DVORNIKOVA, K. V.、PLATONOV, V. E.、YAKOBSON, G. G.

  DOI：——

  日期：——