Sn(OH)2(5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin) | 1279642-12-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Sn(OH)2(5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin)
• 英文别名: dihydroxytin(IV) 2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-diphenylporphyrin
• CAS: 1279642-12-4
• 化学式: C₅₂H₆₂N₄O₂Sn
• 分子量: 893.8
• InChiKey: VHLIIMNMJUGYIL-KWYGDJLISA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  5-(4'-hydroxyphenyl)-15-phenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin 、 Sn(OH)2(5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin) 以 苯 为溶剂， 生成 Sn(5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin)(5-(4'-hydroxyphenyl)-15-phenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin(1-))2
  参考文献：
  名称：

  Supramolecular ensembles based on the donor-acceptor interactions of porphyrins

  摘要：

  Dimeric and trimeric supramolecular structures were synthesized on the basis of donor-acceptor interactions of manganese(III) and tin(IV) complexes of 5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin with 5-(4'-oxyphenyl)-15-phenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin. The structure of the compounds was studied by NMR spectroscopy and TLC.

  DOI：

  10.1134/s1070363211010221
• 作为产物：
  描述：

  2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-diphenylporphyrin 在 氨 、 水 、 四氯化锡 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 生成 Sn(OH)2(5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin)
  参考文献：
  名称：

  Supramolecular ensembles based on the donor-acceptor interactions of porphyrins

  摘要：

  Dimeric and trimeric supramolecular structures were synthesized on the basis of donor-acceptor interactions of manganese(III) and tin(IV) complexes of 5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin with 5-(4'-oxyphenyl)-15-phenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin. The structure of the compounds was studied by NMR spectroscopy and TLC.

  DOI：

  10.1134/s1070363211010221

文献信息

• Dimeric and Trimeric Supramolecular Systems Formed by Donor‒Acceptor Interactions of ZnII, MnIII, and SnIV Porphyrin Complexes
  作者：E. M. Kuvshinova、O. V. Gornukhina、A. S. Semeikin、O. A. Golubchikov

  DOI：10.1134/s1070363217120556

  日期：2017.12

  The paper presents the methods of synthesis of dimeric and trimeric compounds formed by donor-acceptor interactions of Zn-II, Mn-III, and Sn-IV porphyrin complexes. The structure of the porphyrin ensembles was determined by H-1 NMR spectroscopy. The extra coordination properties of the synthesized dimeric and trimeric supramolecular systems in relation to nitrogen-containing compounds were studied and the stability constants of the resulting porphyrin extra complexes were determined.