Sb(3,5-di-tert-butylcatecholate)I(1,10-phenantroline) | 149477-90-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: Sb(3,5-di-tert-butylcatecholate)I(1,10-phenantroline)
• 英文别名: 4,6-ditert-butyl-2-iodo-1,3,2-benzodioxastibole;1,10-phenanthroline
• CAS: 149477-90-7
• 化学式: C₂₆H₂₈IN₂O₂Sb
• 分子量: 649.175
• InChiKey: KSYWAPGIFUMPIC-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 Sb(3,5-di-tert-butylcatecholate)I 以 乙醚 为溶剂， 生成 Sb(3,5-di-tert-butylcatecholate)I(1,10-phenantroline)
  参考文献：
  名称：

  Oxidation of elemental antimony by substituted ortho-benzoquinones

  摘要：

  The oxidation of elemental antimony by the o-quinones Y4C6O2-o (Y = Cl or Br) in diethyl ether gives the unusual antimony(v) products Sb(O2C6Y4)2.5.nEt2O (Y = Cl, n = 1.5; Y = Br, n = 1). The same quinones, and 3,5-di-tert-butyl-1,2-benzoquinone, upon treatment with Sb + 1/2X2 (X = Br or 1) in toluene, give the antimony(III) derivatives Sb(cat)X (cat = substituted catecholate anion). The oxidations are shown by electron spin resonance spectroscopy to proceed via the o-semiquinone intermediates. Adducts of Sb(cat)l with bidentate neutral donors have been prepared. The structure of Sb(dbc)I(bipy) (dbc = 3,5-di-tert-butylcatecholate, bipy = 2,2'-bipyridine) has been shown to be that of a pseudo-octahedral molecule with a stereochemically active lone pair of electrons. Crystal parameters for Sb(dbc)I(bipy).0.5bipy: triclinic, space group P1BAR, a = 9.779(4), b = 18.554(7), c = 8.944(3) angstrom, alpha = 100.94(3), beta = 115.11(3). gamma = 86.82(4)-degrees, Z = 2 and R = 0.044 for 3307 unique reflections.

  DOI：

  10.1039/dt9930001381