[Co₂{SSi(OtBu)₃}₄(μ-C₁₂H₁₀N₂)] | 1620394-07-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Co₂{SSi(OtBu)₃}₄(μ-C₁₂H₁₀N₂)]
• CAS: 1620394-07-1
• 化学式: C₆₀H₁₁₈Co₂N₂O₁₂S₄Si₄
• 分子量: 1418.2
• InChiKey: ANYABXIGINCIKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 1,2-双吡啶基乙烯 以 甲醇 为溶剂， 生成 [Co₂{SSi(OtBu)₃}₄(μ-C₁₂H₁₀N₂)]
  参考文献：
  名称：

  Binuclear Co(II), Zn(II) and Cd(II) tri-tert-butoxysilanethiolates. Synthesis, crystal structure and spectroscopic studies

  摘要：

  A series of Co(II), Zn(II) and Cd(II) complexes have been synthesized in reaction of respective metal tri-tert-butoxysilanethiolates with pyrazine 1 and 2 and 1,2-bis(2-pyridyl)ethylene 3-5. All compounds have been characterized by single-crystal X-ray structure determination, elemental analysis, FT-IR and thermogravimetry. Obtained complexes are bimetallic with the formula of [M{SSi(OtBu)(3)}(2)(mu-L)](2) and metal ions bridged by N,N'-spacer. The penta-coordinated spheres of the metallic atoms are completed by tri-tert-butoxysilanethiolate residue playing the role of O,S-chelating ligand. Luminescent properties of 1, 2, 4 and 5 complexes have also been investigated in solid state. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2014.04.049