烯丙基苯基二硫 | 35379-07-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 烯丙基苯基二硫
• 英文名称: Allylphenyldisulfid
• 英文别名: Phenyl allyl disulfide；(prop-2-enyldisulfanyl)benzene
• CAS: 35379-07-8
• 化学式: C₉H₁₀S₂
• 分子量: 182.31
• InChiKey: INVJVUWALAAFCF-UHFFFAOYSA-N

物化性质

• 沸点：
  239.0±23.0 °C(Predicted)
• 密度：
  1.11±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  烯丙基苯基亚砜 在 三硫化硼 作用下， 以 二硫化碳 为溶剂， 反应 0.42h， 以70%的产率得到烯丙氧基苯硫酚
  参考文献：
  名称：

  结构对硫代亚砜中间体竞争性分解途径的影响

  摘要：

  当三硫化硼与一系列烯丙基芳基适合的氧化物反应时，可得到硫化物和二硫化物的混合物，其产物分布取决于中间体硫代亚砜的结构。

  DOI：

  10.1016/s0040-4039(01)92471-2

文献信息

• Structural effects upon competitive decomposition pathways of Thiosulfoxide intermediates
  作者：Raymond D. Baechler、Lynn James San Filippo、Alayne Schroll

  DOI：10.1016/s0040-4039(01)92471-2

  日期：——

  Mixtures of sulfides and disulfides are obtained upon reaction of boron trisulfide with a series of allyl aryl suit oxides, with the product distributions dependent upon the structures of the intermediate thiosulfoxides.

  当三硫化硼与一系列烯丙基芳基适合的氧化物反应时，可得到硫化物和二硫化物的混合物，其产物分布取决于中间体硫代亚砜的结构。
• Golf ball
  申请人：Bridgestone Sports Co. Ltd.

  公开号：EP1358914A1

  公开（公告）日：2003-11-05

  A golf ball is characterized by comprising a molded and vulcanized product of a rubber composition as a constituent component, the rubber composition comprising 100 pbw of a base rubber composed primarily of a polybutadiene containing at least 60 wt% of cis-1,4-bond, having a Mooney viscosity (ML1+4, 100°C) of at least 30, and synthesized using a rare-earth catalyst, 15-50 pbw of an unsaturated carboxylic acid and/or a metal salt thereof, at least 2 pbw of a processing aid having a highest melting point of up to 115°C, and at least two organic peroxides including an organic peroxide having the shortest half-life at 155°C designated (a) and another organic peroxide having the longest half-life at 155°C designated (b), a ratio of half-lives (bt/at) being at least 7 wherein at is the half-life of (a) and bt is the half-life of (b), a total content of the organic peroxides being 0.1-0.9 pbw per 100 pbw of the base rubber.

  一种高尔夫球，其特征在于包括作为组成成分的橡胶组合物的模塑和硫化产品，该橡胶组合物包括 100 pbw 的基础橡胶，主要由含有至少 60 wt%顺式-1,4-键的聚丁二烯组成，其门尼粘度（ML1+4，100°C）至少为 30，并使用稀土催化剂合成；15-50 pbw 的不饱和羧酸和/或其金属盐、15-50 pbw 的不饱和羧酸和/或其金属盐，至少 2 pbw 的最高熔点不超过 115°C 的加工助剂，以及至少两种有机过氧化物，包括一种在 155°C 下半衰期最短的有机过氧化物（a）和另一种在 155°C 下半衰期最长的有机过氧化物（b），半衰期之比 (bt/at) 至少为 7，其中 at 为 (a) 的半衰期，bt 为 (b) 的半衰期，有机过氧化物的总含量为 0.1-0.9 pbw/100pbw的基础橡胶。
• RUBBER COMPOSITE COMPOSITION FOR HIGHLY THERMALLY CONDUCTIVE BLADDER COMPRISING CARBON NANOTUBES AND PRODUCTION METHOD FOR SAME
  申请人：Hanwha Chemical Corporation

  公开号：EP2930204A1

  公开（公告）日：2015-10-14

  The present invention relates to a rubber composite composition comprising aligned carbon nanotube bundles and to a production method for same. As compared with existing rubber composites comprising carbon nanotubes, the rubber composite according to the present invention has outstanding carbon nanotube dispersion properties, with uniform formation of same inside a butyl rubber matrix, and thus the invention has enhanced thermal conductivity and provides improved mechanical properties such as tensile strength and durability in spite of the enhanced thermal conductivity.

  本发明涉及一种包含排列整齐的碳纳米管束的橡胶复合材料组合物及其生产方法。与现有的包含碳纳米管的橡胶复合材料相比，本发明的橡胶复合材料具有出色的碳纳米管分散特性，在丁基橡胶基体内均匀形成碳纳米管，因此本发明具有更强的导热性，并在增强导热性的同时提供更好的机械特性，如拉伸强度和耐久性。
• METHOD FOR MANUFACTURING FLEXOGRAPHIC PRINTING ORIGINAL PLATE FOR LASER ENGRAVING, METHOD FOR MANUFACTURING FLEXOGRAPHIC PRINTING PLATE, AND LASER ENGRAVING RESIN COMPOSITION
  申请人：Fujifilm Corporation

  公开号：EP3045320A1

  公开（公告）日：2016-07-20

  Provided are a resin composition for laser engraving having excellent roll detachability and sheet appearance when the resin composition is subjected to calender processing, and a method for producing a flexographic printing plate precursor for laser engraving and a method for producing a flexographic printing plate, which use the resin composition for laser engraving. Disclosed is a method for producing a flexographic printing plate precursor for laser engraving, the method including, in the following order, a layer forming step of forming a relief forming layer using a resin composition for laser engraving, through sheet molding using a calender roll; and a crosslinking step of crosslinking the relief forming layer by means of heat, and obtaining a flexographic printing plate precursor for laser engraving having a crosslinked relief forming layer, in which the resin composition for laser engraving is a resin composition including a diene-based polymer, a thermal polymerization initiator, carbon black, and a filler other than carbon black.

  本发明提供了一种激光雕刻用树脂组合物，该树脂组合物在进行压光机加工时具有优异的辊脱离性和薄片外观，还提供了一种生产激光雕刻用柔性版印刷板前体的方法和一种生产柔性版印刷板的方法，其中使用了激光雕刻用树脂组合物。本发明公开了一种用于生产激光雕刻用柔版印刷板前体的方法，该方法按以下顺序包括使用激光雕刻用树脂组合物通过压延机辊片成型形成浮雕成型层的层成型步骤，以及使用激光雕刻用树脂组合物通过压延机辊片成型形成交联层的交联步骤；和交联步骤，通过加热使浮雕形成层交联，并获得具有交联浮雕形成层的激光雕刻用柔性版印刷板原版，其中激光雕刻用树脂组合物是一种树脂组合物，包括二烯基聚合物、热聚合引发剂、炭黑和除炭黑以外的填料。
• Compositions and methods for inhibiting the biological activity of soluble biomolecules
  申请人：NaNotics, LLC

  公开号：US10420817B2

  公开（公告）日：2019-09-24

  The disclosure provides, among other things, compositions that bind to and inhibit the biological activity of soluble biomolecules, as well as pharmaceutical compositions thereof. Also provided herein are a number of applications (e.g., therapeutic applications) in which the compositions are useful.

  除其他外，本公开提供了与可溶性生物分子结合并抑制其生物活性的组合物及其药物组合物。本文还提供了这些组合物的一些应用（如治疗应用）。