二苄基氨基甲基醇 | 297140-35-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二苄基氨基甲基醇
• 英文名称: Dibenzylamino-methanol
• 英文别名: Oxymethyl-dibenzylamin；Dibenzylaminomethylalkohol；(Dibenzylamino)methanol
• CAS: 297140-35-3
• 化学式: C₁₅H₁₇NO
• 分子量: 227.306
• InChiKey: GWOYKNWCEOIGIC-UHFFFAOYSA-N

物化性质

• 沸点：
  334.3±30.0 °C(Predicted)
• 密度：
  1.113±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  23.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  二苄基氨基甲基醇 、 二苄胺 生成 N,N,N',N'-四苄基甲烷二胺
  参考文献：
  名称：

  Henry, vol. <3> 28, p. 376

  摘要：

  DOI：
• 作为产物：
  描述：

  聚合甲醛 、 二苄胺 在 水 作用下， 生成 二苄基氨基甲基醇
  参考文献：
  名称：

  Henry, vol. <3> 28, p. 376

  摘要：

  DOI：

文献信息

• Asymmetric Petasis Reactions Catalyzed by Chiral Biphenols
  作者：Sha Lou、Scott E. Schaus

  DOI：10.1021/ja8018934

  日期：2008.6.1

  Chiral biphenols catalyze the enantioselective Petasis reaction of alkenyl boronates, secondary amines, and ethyl glyoxylate. The reaction requires the use of 15 mol % of (S)-VAPOL as the catalyst, alkenyl boronates as nucleophiles, ethyl glyoxylate as the aldehyde component, and 3 A molecular sieves as an additive. The chiral alpha-amino ester products are obtained in good yields (71-92%) and high

  手性双酚催化烯基硼酸酯、仲胺和乙醛酸乙酯的对映选择性 Petasis 反应。该反应需要使用15mol%的(S)-VAPOL作为催化剂，硼酸烯基作为亲核试剂，乙醛酸乙酯作为醛组分，3A分子筛作为添加剂。以良好的产率 (71-92%) 和高对映体比率 (89:11-98:2) 获得手性 α-氨基酯产物。机理研究表明无环硼酸酯与 VAPOL 和四配位硼酸酯中间体的单配体交换。
• INK COMPOSITION, INK SET, AND IMAGE FORMING METHOD
  申请人：FUJIFILM CORPORATION

  公开号：US20150175819A1

  公开（公告）日：2015-06-25

  An ink composition, including: water; a polymerizable compound; a polymerization initiator; and a β-alkoxypropionamide compound represented by the following Formula (A): wherein, in Formula (A), R 1 represents a linear or branched alkyl group having from 1 to 6 carbon atoms; each of R 2 and R 3 independently represents a hydrogen atom or a linear or branched alkyl group having from 1 to 4 carbon atoms; and R 2 and R 3 may be the same or different.

  一种墨水组合物，包括：水；可聚合化合物；聚合引发剂；以及由以下式子（A）表示的β-烷氧基丙酰胺化合物：其中，在式（A）中，R1表示具有1至6个碳原子的线性或支链烷基；每个R2和R3独立地表示氢原子或具有1至4个碳原子的线性或支链烷基；且R2和R3可以相同也可以不同。
• Henry, vol. <3> 28, p. 376
  作者：Henry

  DOI：——

  日期：——
• IMAGE FORMING METHOD
  申请人：FUJIFILM CORPORATION

  公开号：US20130222467A1

  公开（公告）日：2013-08-29

  An image forming method including applying a treatment liquid; and applying a first ink containing a pigment, water, and polymer particles of with the content is 1.0 mass % to 3.0 mass %, and applying a second ink having a different hue to the first ink onto the applied first ink at an ink droplet speed of 6 m/sec to 10 m/sec to form a multi-color image, in which an interval from a landing time point of the first ink to a landing time point of the second ink is 200 msec or less, and a dot diameter φ2 of the second ink, and a dot diameter φ1 of the second ink in an ink droplet amount equal to an ink droplet amount in the forming of the multi-color image satisfy a relationship of 0.90≦φ2/φ1≦1.10.
• INK COMPOSITION AND IMAGE FORMING METHOD
  申请人：FUJIFILM Corporation

  公开号：US20140132685A1

  公开（公告）日：2014-05-15

  An ink composition having excellent storage stability and curing properties after an image formation and an image forming method using the ink composition are provided. An ink composition including (A) a polymerizable compound represented by the following general formula (1) and (B) a polymerization initiator and an image forming method using the ink composition. In the general formula (1), R 1 represents a hydrogen atom or a methyl group. R 2 represents a liner or branched alkylene group having 2 to 4 carbon atoms. However, in R 2 , it is not possible to have a structure in which an oxygen atom and a nitrogen atom which are bonded to both ends of R 2 are bonded to the same carbon atom of R 2 . R 3 represents a divalent linking group. k represents 2 or 3. x, y and z each independently represent an integer of 0 to 6 and x+y+z satisfies 0 to 18.