3-fluoro-N'-[(E)-(2-hydroxyphenyl)methylidene]benzohydrazide | 116324-94-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-fluoro-N'-[(E)-(2-hydroxyphenyl)methylidene]benzohydrazide
• 英文别名: 3-fluoro-N-[(E)-(2-hydroxyphenyl)methylideneamino]benzamide
• CAS: 116324-94-8
• 化学式: C₁₄H₁₁FN₂O₂
• 分子量: 258.252
• InChiKey: WTWVVIBXTUCBBW-CXUHLZMHSA-N

物化性质

• 熔点：
  178-179 °C(Solv: ethanol (64-17-5))
• 密度：
  1.24±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.7
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-氟苯甲酰肼 、 水杨醛 在 溶剂黄146 作用下， 以 乙醇 为溶剂， 生成 3-fluoro-N'-[(E)-(2-hydroxyphenyl)methylidene]benzohydrazide
  参考文献：
  名称：

  新型酰基hydr作为铁螯合物的合成

  摘要：

  DOI：

  10.1021/je00054a044

文献信息

• USE OF METAL HYDRAZIDE COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
  申请人：BASF SE

  公开号：EP3524347A1

  公开（公告）日：2019-08-14

  The present invention relates to the use of selected metal complex compounds as oxidation catalysts as well as to a process for removing stains and soil on textiles and hard surfaces. The metal complex compounds have hydrazide ligands, preferably with electron withdrawing groups in the phenyl ring adjacent to the acyl group. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands.

  本发明涉及使用选定的金属络合物作为氧化催化剂，以及去除纺织品和硬表面污渍和污垢的工艺。金属络合物具有酰肼配体，最好是在邻近酰基的苯基环上具有取电子基团。本发明的其他方面是包含此类金属络合物、新型金属络合物和新型配体的制剂。
• EDWARD, JOHN T.;GAUTHLER, MARIO;CHUBB, FRANCIS L.;PONKA, PREMYSL, J. CHEM. AND ENG. DATA, 33,(1988) N 4, C. 538-540
  作者：EDWARD, JOHN T.、GAUTHLER, MARIO、CHUBB, FRANCIS L.、PONKA, PREMYSL

  DOI：——

  日期：——
• USE OF HYDRAZIDE COMPOUNDS AS OXIDATION CATALYSTS
  申请人：BASF SE

  公开号：EP2271426B1

  公开（公告）日：2019-02-20
• Use of Metal Hydrazide Complex Compounds as Oxidation Catalysts
  申请人：BASF SE

  公开号：US20130281353A1

  公开（公告）日：2013-10-24

  The present invention relates to the use of selected metal complex compounds and ligands as oxidation catalysts as well as to a process for removing stains and soil on textiles and hard surfaces. The metal complex compounds have hydrazide ligands, preferably with electron withdrawing groups in the phenyl ring adjacent to the acyl group. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands.
• US8492324B2
  申请人：——

  公开号：US8492324B2

  公开（公告）日：2013-07-23