5-benzyloxymethyl-2-norbornene | 146623-18-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-benzyloxymethyl-2-norbornene
• 英文别名: 5-[(Benzyloxy)methyl]bicyclo[2.2.1]hept-2-ene；5-(phenylmethoxymethyl)bicyclo[2.2.1]hept-2-ene
• CAS: 146623-18-9
• 化学式: C₁₅H₁₈O
• 分子量: 214.307
• InChiKey: ABUDOMSLEKPEEV-UHFFFAOYSA-N

物化性质

• 沸点：
  301.6±11.0 °C(Predicted)
• 密度：
  1.054±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-benzyloxymethyl-2-norbornene 在 氯磺酰异氰酸酯 、 sodium carbonate 、 sodium hydroxide 作用下， 以 二氯甲烷 、 甲醇 为溶剂， 反应 21.0h， 以83%的产率得到5-降冰片烯-2-甲醇
  参考文献：
  名称：

  Deprotection of benzyl and p-methoxybenzyl ethers by chlorosulfonyl isocyanate–sodium hydroxide

  摘要：

  CSI-NaOH procedure provided a new and mild methodology for the deprotection of benzyl and p-methoxybenzyl ethers without affecting the other functional groups under similar reaction conditions. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)02648-5

文献信息

• MASS POLYMERIZABLE POLYCYCLOOLEFIN COMPOSITIONS CONTAINING SOLUBLE PHOTOACID GENERATORS
  申请人：PROMERUS, LLC

  公开号：US20210380733A1

  公开（公告）日：2021-12-09

  Embodiments in accordance with the present invention encompass compositions comprising a soluble photoacid generator, a organopalladium compound, a photosensitizer and one or more olefinic monomers which undergo vinyl addition polymerization when said composition is exposed to a suitable actinic radiation to form a substantially transparent film. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, among others.

  根据本发明的实施例，包括可溶性光酸发生剂、有机钯化合物、光敏剂和一种或多种烯烃单体的组合物被涵盖在内，当该组合物暴露于适当的光辐射下时，这些单体会经历乙烯基加成聚合反应，形成一个基本透明的薄膜。其中使用的单体具有不同的光学和机械性能，因此这些组合物可以定制成具有各种光电性能的薄膜。因此，本发明的组合物在各种应用中都是有用的，包括作为涂料、封装材料、填充剂、平整剂等。
• Polycycloolefin polymer compositions as optical materials
  申请人：PROMERUS, LLC

  公开号：US10266720B2

  公开（公告）日：2019-04-23

  Embodiments in accordance with the present invention encompass compositions encompassing components A and B which are kept separately and respectively contain a procatalyst and an activator along with one or more monomers which undergo vinyl addition polymerization when both components are mixed together to form a substantially transparent film. The monomers employed therein have a range of refractive index from 1.4 to 1.8 and thus these compositions can be tailored to form transparent films of varied refractive indices. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as coatings, encapsulants, fillers, leveling agents, among others.

  根据本发明的实施方案，组合物包括单独保存的组分 A 和组分 B，它们分别含有催化剂和活化剂以及一种或多种单体，当两种组分混合在一起形成基本透明的薄膜时，这些单体发生乙烯基加成聚合反应。其中使用的单体的折射率范围为 1.4 至 1.8，因此这些组合物可以定制以形成不同折射率的透明薄膜。因此，本发明的组合物可用于各种光电子应用，包括用作涂层、封装剂、填料、匀染剂等。
• POLYCYCLOOLEFIN POLYMER COMPOSITIONS AS OPTICAL MATERIALS
  申请人：Promerus, LLC

  公开号：EP3344671A1

  公开（公告）日：2018-07-11
• UV ACTIVE DERIVATIVES OF Pd(AcAc)2 CATALYZED POLYCYCLOOLEFIN COMPOSITIONS AS OPTICAL MATERIALS
  申请人：PROMERUS, LLC

  公开号：US20210198392A1

  公开（公告）日：2021-07-01

  Embodiments in accordance with the present invention encompass compositions comprising a organopalladium compound, a photoacid generator, a photosensitizer and one or more olefinic monomers which undergo vinyl addition polymerization when said composition is exposed to a suitable actinic radiation to form a substantially transparent film. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, among others.
• UV ACTIVE DERIVATIVES OF Pd(AcAc)2L CATALYZED POLYCYCLOOLEFIN COMPOSITIONS AS OPTICAL MATERIALS
  申请人：PROMERUS, LLC

  公开号：US20210198393A1

  公开（公告）日：2021-07-01

  Embodiments in accordance with the present invention encompass compositions comprising a organopalladium compound, a photoacid generator, a photosensitizer and one or more olefinic monomers which undergo vinyl addition polymerization when said composition is exposed to a suitable actinic radiation to form a substantially transparent film. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, among others.