13,13-dimethyl-13H-indeno[1,2-b]anthracene | 1205546-01-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 13,13-dimethyl-13H-indeno[1,2-b]anthracene
• 英文别名: 10,10-dimethylpentacyclo[11.8.0.03,11.04,9.015,20]henicosa-1(21),2,4,6,8,11,13,15,17,19-decaene
• CAS: 1205546-01-5
• 化学式: C₂₃H₁₈
• 分子量: 294.396
• InChiKey: TWHBXDQJJOIEEH-UHFFFAOYSA-N

物化性质

• 沸点：
  485.9±15.0 °C(Predicted)
• 密度：
  1.154±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  13,13-dimethyl-13H-indeno[1,2-b]anthracene 在 tris-(dibenzylideneacetone)dipalladium(0) 、 N-溴代丁二酰亚胺(NBS) 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 四氯化碳 、 甲苯 为溶剂， 反应 32.0h， 生成 10,10-dimethyl-14-N,14-N,21-N,21-N-tetraphenylpentacyclo[11.8.0.03,11.04,9.015,20]henicosa-1(21),2,4,6,8,11,13,15,17,19-decaene-14,21-diamine
  参考文献：
  名称：

  JP5781506

  摘要：

  公开号：
• 作为产物：
  描述：

  9,9-二甲基芴 在 aluminum chloride HI 、 PPA 、 碘 作用下， 以 正己烷 、 二氯甲烷 、 水 、 溶剂黄146 、 甲苯 为溶剂， 生成 13,13-dimethyl-13H-indeno[1,2-b]anthracene
  参考文献：
  名称：

  AMINOANTHRACENE DERIVATIVE AND AN ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME

  摘要：

  揭示了一种新型氨基蒽衍生物及其所使用的有机电致发光器件。具体来说，所揭示的氨基蒽衍生物具有一个核心（例如，吲哚蒽核心），该核心是蒽基（具有高设备特性）连接到萘基（具有高荧光特性），其中核心被至少一个由化学式2表示的胺基取代，所揭示的有机电致发光器件使用氨基蒽衍生物作为发光层材料，以提高效率、工作电压和寿命。

  公开号：

  US20120161615A1

文献信息

• AMINOANTHRACENE DERIVATIVE AND AN ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME
  申请人：Hong Jin-Seok

  公开号：US20120161615A1

  公开（公告）日：2012-06-28

  Disclosed are a novel amino anthracene derivative and an organic electro-luminescence device using the same. More specifically, the disclosed amino anthracene derivative has a core (e.g., indenoanthracene core) of an anthracene moiety (with a high device characteristic) linked to a fluorene moiety (with a high fluorescence characteristic), in which in the core is substituted with at least one amine group represented by Formula 2 and the disclosed organic electro-luminescence device uses the amino anthracene derivative as a light emitting layer material so as to be enhanced in efficiency, operating voltage, and life span.

  揭示了一种新型氨基蒽衍生物及其所使用的有机电致发光器件。具体来说，所揭示的氨基蒽衍生物具有一个核心（例如，吲哚蒽核心），该核心是蒽基（具有高设备特性）连接到萘基（具有高荧光特性），其中核心被至少一个由化学式2表示的胺基取代，所揭示的有机电致发光器件使用氨基蒽衍生物作为发光层材料，以提高效率、工作电压和寿命。
• ANTHRACENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE ELEMENT USING THE SAME
  申请人：Shin Chang-Ju

  公开号：US20110210320A1

  公开（公告）日：2011-09-01

  The present invention relates to an anthracene derivative and an organic electroluminescent device using the same. More specifically, the present invention relates to: a novel compound which has a core (for example, an indenoanthracene core) where both an anthracene moiety with excellent device characteristics and a fluorene moiety with excellent fluorescent properties are fused, wherein substituents (for example, a heterocyclic group such as a benzimidazole group, a benzothiazole group, a benzoxazole group, a pyridinyl group or a bipyridinyl group) with an electron transfer capacity are substituted to the core; and an organic electroluminescence element which has improved luminous efficiency, brightness, thermal stability, driving voltage, and lifetime, by comprising an organic layer which is positioned between a positive electrode and negative electrode and contains the novel compound.

  本发明涉及一种蒽衍生物及其应用于有机电致发光器件中。更具体地，本发明涉及一种新型化合物，其具有一个核心（例如，一个茚并蒽核心），其中蒽基具有优异的器件特性，荧光基团具有优异的荧光性能，并且向核心取代基（例如，带有电子转移能力的杂环基团，如苯并咪唑基团、苯并噻唑基团、苯并噁唑基团、吡啶基团或联吡啶基团）被取代；以及一种有机电致发光元件，通过包含新型化合物的有机层位于正电极和负电极之间，其具有改善的发光效率、亮度、热稳定性、驱动电压和寿命。
• Anthracene derivative and organic electroluminescence element using the same
  申请人：Shin Chang-Ju

  公开号：US08525158B2

  公开（公告）日：2013-09-03

  The present invention relates to an anthracene derivative and an organic electroluminescent device using the same. More specifically, the present invention relates to: a novel compound which has a core (for example, an indenoanthracene core) where both an anthracene moiety with excellent device characteristics and a fluorene moiety with excellent fluorescent properties are fused, wherein substituents (for example, a heterocyclic group such as a benzimidazole group, a benzothiazole group, a benzoxazole group, a pyridinyl group or a bipyridinyl group) with an electron transfer capacity are substituted to the core; and an organic electroluminescence element which has improved luminous efficiency, brightness, thermal stability, driving voltage, and lifetime, by comprising an organic layer which is positioned between a positive electrode and negative electrode and contains the novel compound.

  本发明涉及一种蒽衍生物及其在有机电致发光器件中的应用。更具体地说，本发明涉及一种新型化合物，其具有一个核心（例如，一个茚并蒽核心），其中蒽基具有优异的器件特性，荧光基具有优异的荧光性能，并且核心上取代基（例如，具有电子转移能力的杂环基，如苯并咪唑基、苯并噻唑基、苯并噁唑基、吡啶基或联吡啶基）被取代；以及一种有机电致发光元件，其通过包含所述新型化合物的有机层，位于正极和负极之间，从而提高了发光效率、亮度、热稳定性、驱动电压和寿命。
• Aminoanthracene derivative and an organic electroluminescent element employing the same
  申请人：Hong Jin-Seok

  公开号：US09115112B2

  公开（公告）日：2015-08-25

  Disclosed are a novel amino anthracene derivative and an organic electro-luminescence device using the same. More specifically, the disclosed amino anthracene derivative has a core (e.g., indenoanthracene core) of an anthracene moiety (with a high device characteristic) linked to a fluorene moiety (with a high fluorescence characteristic), in which in the core is substituted with at least one amine group represented by Formula 2 and the disclosed organic electro-luminescence device uses the amino anthracene derivative as a light emitting layer material so as to be enhanced in efficiency, operating voltage, and life span.

  本发明涉及一种新型氨基蒽衍生物及其所使用的有机电致发光器件。具体而言，所披露的氨基蒽衍生物具有蒽基（具有高器件特性）的核心（例如，茚蒽核心）与芴基（具有高荧光特性）连接，其中该核心被至少一个由公式2表示的胺基取代，所披露的有机电致发光器件使用该氨基蒽衍生物作为发光层材料，以提高效率、工作电压和寿命。
• JP5781506
  申请人：——

  公开号：——

  公开（公告）日：——