2,2-Diaethyl-tetrahydro-furan | 1193-35-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧唑烯
• 英文名称: 2,2-Diaethyl-tetrahydro-furan
• 英文别名: 2,2-Diethyl-tetrahydro-furan；2,2-diethyloxolane
• CAS: 1193-35-7
• 化学式: C₈H₁₆O
• 分子量: 128.214
• InChiKey: WNSPFMGXOCUATQ-UHFFFAOYSA-N

物化性质

• 沸点：
  157.67°C (estimate)
• 密度：
  0.8703

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-hydroxy-1,1-diethyl-2-butyn-1-ol 在 乙醚 、 硫酸 、 镍 作用下， 生成 2,2-Diaethyl-tetrahydro-furan
  参考文献：
  名称：

  Gouge, Annales de Chimie (Cachan, France), 1951, vol. <12> 6, p. 648,682

  摘要：

  DOI：

文献信息

• [EN] CHIRAL DIAMINE COMPOUNDS FOR THE PREPARATION OF CHIRAL ALCOHOL AND CHIRAL AMINE<br/>[FR] COMPOSÉS DE DIAMINE CHIRALE POUR LA PRÉPARATION D'ALCOOL CHIRAL ET D'AMINE CHIRALE
  申请人：UNIV DUBLIN

  公开号：WO2015181182A1

  公开（公告）日：2015-12-03

  A process for the stereoselective preparation of a chiral alcohol or a chiral amine, the process comprising reacting a first prochiral reactant selected from the group consisting of a ketone, an aldehyde, and an inline, with a second reactant comprising a Grignard reagent, in the presence of a chiral trans-diamim of formula (1) as defined herein. Also provided is the use of the chiral trans-diamine of formula (1) in a Grignard reaction and the chiral trans-diamines per se.

  一种用于立体选择性制备手性醇或手性胺的方法，该方法包括在存在本文所定义的式（1）的手性转二胺的情况下，将从酮、醛和内酰胺组成的一组中选择的第一个原始手性反应物与包含格氏试剂的第二个反应物反应。还提供了手性转二胺在格氏反应中的应用以及手性转二胺本身。
• Haloalkylmethyleneoxyphenyl-substituted ketoenols
  申请人：Fischer Reiner

  公开号：US20100311593A1

  公开（公告）日：2010-12-09

  The invention relates to novel compounds of the formula (I), in which W, X, Y, Z and CKE are each as defined above, to several methods and intermediates for preparation thereof and to the use thereof as pesticides and/or herbicides. The invention also relates to selective herbicidal compositions which comprise firstly haloalkylmethyleneoxyphenyl-substituted ketoenols and secondly a compound which improves crop plant compatibility. The present invention further relates to the enhancement of the action of crop protection compositions comprising especially haloalkylmethyleneoxyphenyl-substituted ketoenols, by the addition of ammonium or phosphonium salts and optionally penetration enhancers, to the corresponding compositions, to methods for production thereof and to the use thereof in crop protection as insecticides and/or acaricides and/or for preventing undesired plant growth.

  该发明涉及公式（I）中的新化合物，其中W、X、Y、Z和CKE各自如上所定义，以及其制备的几种方法和中间体，以及将其用作杀虫剂和/或除草剂的用途。该发明还涉及选择性除草剂组合物，其首先包括卤代烷基亚甲氧基苯基取代酮烯醇，其次包括改善作物植物相容性的化合物。本发明还涉及通过添加铵盐或磷盐以及必要时的渗透增效剂，增强特别是卤代烷基亚甲氧基苯基取代酮烯醇的作物保护组合物的作用，以及相应组合物的制备方法和将其用于作物保护作为杀虫剂和/或螨虫剂和/或预防不受欢迎的植物生长。
• Bonding compositions for dental use
  申请人：KURARAY CO., LTD

  公开号：US20020035169A1

  公开（公告）日：2002-03-21

  An antibacterial bonding compositions for dental use, which comprises (A) an antibacterial primer that comprises an antibacterial polymerizable monomer having an ethylenic unsaturated group and at least one or more cationic groups selected from the group consisting of ammonium bases, pyridinium bases and phosphonium bases, and a volatile solvent, and(B) an adhesive composition comprising an acid group having polymerizable monomer, a polymerizable monomer, and a polymerization initiator; and an adhesive compositions for dental use, which comprises (P) an adhesive primer comprising an acid group having polymerizable monomer, a hydrophilic polymerizable monomer, and water, and (Q) a bonding agent comprising a polymerizable monomer, and an acylphosphine oxide compound and an &agr;-diketone compound both serving as a polymerization initiator. The bonding compositions can inhibit the growth of cariogenic bacteria in the bonded area of a tooth as restored with a restorative dental material in dental treatment thereby preventing secondary caries and odontitis around that area, and can enhance the bonding strength, especially the bonding durability of the restorative dental material to the tooth.

  一种牙科用抗菌粘合剂组合物，它包括(A)抗菌底漆，该底漆由具有乙烯不饱和基团和至少一个或多个阳离子基团的抗菌可聚合单体组成，阳离子基团选自由铵基、吡啶基和鏻基组成的组，以及挥发性溶剂；(B)粘合剂组合物，该粘合剂组合物由具有可聚合单体的酸基、可聚合单体和聚合引发剂组成；以及一种牙科用粘合剂组合物，它包括（P）由具有可聚合单体的酸性基团、亲水性可聚合单体和水组成的粘合剂底漆，以及（Q）由可聚合单体、酰基氧化膦化合物和用作聚合引发剂的&agr;-二酮化合物组成的粘合剂。这些粘接组合物可以抑制在牙科治疗中用牙科修复材料修复的牙齿粘接区域内的致龋细菌的生长，从而防止该区域周围的继发性龋齿和牙周炎，并可以增强牙科修复材料与牙齿的粘接强度，特别是粘接耐久性。
• Barluenga, Jose; Rubiera, Covadonga; Fernandez, Jose R., Journal of Chemical Research, Miniprint, 1987, # 12, p. 3242 - 3264
  作者：Barluenga, Jose、Rubiera, Covadonga、Fernandez, Jose R.、Florez, Josefa、Yus, Miguel

  DOI：——

  日期：——
• Colonge; Garnier, Bulletin de la Societe Chimique de France, 1948, p. 436,438
  作者：Colonge、Garnier

  DOI：——

  日期：——