1,1-bis[4-hydroxy-3-(2-propenyl)phenyl]cyclohexane | 112770-95-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1-bis[4-hydroxy-3-(2-propenyl)phenyl]cyclohexane
• 英文别名: 1,1-bis(3-allyl-4-hydroxyphenyl)cyclohexane；1,1-bis(4-hydroxy-3-allylphenyl)cyclohexane；1,1-bis(3-allyl-4-hydroxyphenyl)cyclohexan；Phenol, 4,4'-cyclohexylidenebis[2-(2-propenyl)-；4-[1-(4-hydroxy-3-prop-2-enylphenyl)cyclohexyl]-2-prop-2-enylphenol
• CAS: 112770-95-3
• 化学式: C₂₄H₂₈O₂
• 分子量: 348.485
• InChiKey: JLVDUKBUUBWTQG-UHFFFAOYSA-N

物化性质

• 沸点：
  483.9±45.0 °C(Predicted)
• 密度：
  1.092±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1-bis[4-hydroxy-3-(2-propenyl)phenyl]cyclohexane 在 dihydrogen hexachloroplatinate 、 sodium hydroxide 作用下， 以 水 、 异丙醇 、 甲苯 为溶剂， 反应 11.0h， 生成
  参考文献：
  名称：

  알콕시실릴기를 갖는 비스페놀계 에폭시 화합물 및 그 제조방법, 및 그 경화 생성물을 포함하는 유기-무기재료 복합체 및 그 복합체 제조방법

  摘要：

  这项发明涉及具有烷氧基苯环的双酚类环氧化合物及其制备方法，以及包含硬化产物的有机-无机材料复合物及其制备方法，更详细地说，涉及一种新型具有改进耐热性和热膨胀特性以及提供优越硬化度的复合物，可用于制造下一代半导体基板、PCB等高密度和高性能电子元件的有机-无机材料复合物及其制备方法。

  公开号：

  KR20160143996A
• 作为产物：
  描述：

  双酚Z 在 三氯化硼 、 potassium carbonate 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 生成 1,1-bis[4-hydroxy-3-(2-propenyl)phenyl]cyclohexane
  参考文献：
  名称：

  Synthesis, cytotoxicity, and antiviral activities of new neolignans related to honokiol and magnolol

  摘要：

  A series of new bisphenol derivatives bearing allylic moieties were synthesized as potential analogs of honokiol and/or magnolol. Certain compounds exhibited specific anti-proliferation activity against SVR cells and moderate anti-HIV-1 activity in primary human lymphocytes. Compound 5h was the most potent compound and its anti-tumor activity was evaluated in vivo. Published by Elsevier Ltd.

  DOI：

  10.1016/j.bmcl.2007.06.024

文献信息

• Optically active compound and photosensitive resin composition
  申请人：——

  公开号：US20030211421A1

  公开（公告）日：2003-11-13

  A photoactive compound is used in combination with a photosensitizer, represented by the following formula (1): A −[( J ) m −( X-Pro )] n (1) wherein A represents a hydrophobic unit comprising at least one kind of hydrophobic groups selected from a hydrocarbon group and a heterocyclic group, J represents a connecting group, X-Pro represents a hydrophilic group protected by a protective group Pro which is removable by light exposure, m represents 0 or 1, and n represents an integer of not less than 1. The protective group Pro may be removable by light exposure in association with the photosensitizer (especially, a photo acid generator), or may be a hydrophobic protective group. The hydrophilic group may be a hydroxyl group or a carboxyl group. The photoactive compound has high sensitivity to a light source of short wavelength beams, for resist application, therefore, the photoactive compound is advantageously used for forming a pattern with high resolution.

  一种光活性化合物与光敏剂结合使用，由以下公式（1）表示： A −[( J ) m −( X-Pro )] n (1) 其中，A代表至少包括一种从烃基和杂环基中选择的疏水基的疏水单元，J代表连接基团，X-Pro代表由光照可去除的保护基团Pro保护的亲水基团，m代表0或1，n代表不少于1的整数。 保护基团Pro可以与光敏剂（特别是光酸发生剂）一起通过光照可去除，也可以是疏水保护基团。亲水基团可以是羟基或羧基。光活性化合物对短波长光源具有很高的敏感性，用于光刻应用，因此，该光活性化合物有利于形成具有高分辨率的图案。
• 티올-엔 반응을 이용한 비스페놀계 에폭시 화합물 및 그 제조방법, 및 그 경화 생성물을 포함하는 유기-무기재료 복합체 및 그 복합체 제조방법
  申请人：SAMYANG CORPORATION 주식회사 삼양사(120110515934) Corp. No ▼ 110111-4720945BRN ▼101-86-66838

  公开号：KR20170075105A

  公开（公告）日：2017-07-03

  본 발명은 알콕시실릴알킬-S-알킬기를 갖는 비스페놀계 에폭시 화합물 및 그 제조방법, 및 그 경화 생성물을 포함하는 유기-무기재료 복합체 및 그 복합체 제조방법에 관한 것으로서, 더욱 상세하게는, 차세대 반도체 기판 및 PCB 등의 고집적화 및 고성능의 전자부품 제조에 사용시 개선된 내열성 및 열팽창 특성을 나타내며 경화도도 우수한 복합체를 제공할 수 있는 신규한 비스페놀계 에폭시 화합물 및 그 제조방법, 및 그 경화 생성물을 포함하는 유기-무기재료 복합체 및 그 복합체 제조방법에 관한 것이다.

  本发明涉及具有알科西基-烷基-S-烷基基团的双酚类环氧化合物及其制备方法，以及包含硬化产物的有机-无机材料复合物及其制备方法，更详细地说，本发明涉及新型双酚类环氧化合物及其制备方法，以及包含硬化产物的有机-无机材料复合物，该复合物在制造下一代半导体基板和PCB等高密度和高性能电子元件时表现出改善的耐热性和热膨胀特性，同时提供优异的硬化度。
• Electrophotographic photoconductor
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0566423A1

  公开（公告）日：1993-10-20

  An electrophotographic photoconductor comprising : a conductive substrate ; a charge-generation layer formed on said conductive substrate ; and a charge-transport layer formed on said charge-generation layer, said charge-transport layer comprising a charge-transport material and a binder resin which comprises a polycarbonate comprising at least one structural unit of formula I : wherein R1, R2, R3, R4, R5, R6, R7 and R8 each represent independently a hydrogen atom, a saturated or unsaturated aliphatic hydrocarbon group having 1 to 6 carbon atoms, a halogen atom or a phenyl group ; and at least one structural unit of formula II : wherein R9, R10, R11, R12, R13, R14, R15 and R16 each represent independently a hydrogen atom, a saturated or unsaturated aliphatic hydrocarbon group having 1 to 6 carbon atoms, a halogen atom or a phenyl group, and R17 and R18 each represent independently a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or a phenyl group, or R17 and R18 together form, with the carbon atom to which they are attached, a saturated or unsaturated aliphatic hydrocarbon ring or an aliphatic hydrocarbon ring to which an aromatic ring is fused.

  电致发光感光元件，包括 ： 导电基板 在所述导电基板上形成的电荷生成层；以及 在所述电荷发生层上形成的电荷传输层，所述电荷传输层包括电荷传输材料和粘结剂树脂，所述粘结剂树脂包括聚碳酸酯，其中包含至少一个式 I 的结构单元： 其中 R1、R2、R3、R4、R5、R6、R7 和 R8 各自独立地代表氢原子、具有 1 至 6 个碳原子的饱和或不饱和脂族烃基、卤素原子或苯基；以及至少一个式 II 的结构单元： 其中 R9、R10、R11、R12、R13、R14、R15 和 R16 各自独立地代表氢原子、具有 1 至 6 个碳原子的饱和或不饱和脂族烃基、卤素原子或苯基，以及 R17 和 R18 各自独立地代表氢原子、具有 1 至 6 个碳原子的烷基或苯基，或 R17 和 R18 与它们所连接的碳原子一起形成饱和或不饱和脂族烃环或与芳香环融合的脂族烃环。
• POLYCARBONATE, AND MOLDING AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR PREPARED THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0896975A1

  公开（公告）日：1999-02-17

  A polycarbonate containing repeating units (1) represented by the general formula (1), a polycarbonate molding produced by molding the polycarbonate, and an electrophotographic photoreceptor having a photosensitive layer which has a surface layer containing the polycarbonate: wherein R is an aliphatic unsaturation-free monovalent hydrocarbon group, R1 is a halogen atom, an alkyl group, an alkoxy group or an aryl group, X is an alkylene group or an alkyleneoxyalkylene group, X' is an alkylene group of 2 or more carbon atoms, an alkyleneoxyalkylene group or oxygen atom, a is an integer of 0 to 4, na is 0 or 1, nb is 1 or 2, nc is 1 or 2, provided na+nb+nc=3, n1, n2, n3 and n4 are 0 or an integer of 1 or more, provided n1+n2+n3+n4 is an integer of 0 to 450.

  一种含有由通式(1)表示的重复单元(1)的聚碳酸酯，一种通过模塑该聚碳酸酯而制得的聚碳酸酯模塑件，以及一种具有感光层的电子照相感光器，该感光器具有含有该聚碳酸酯的表层： 其中 R 是脂肪族无饱和度单价烃基，R1 是卤素原子、烷基、烷氧基或芳基，X 是亚烷基或亚烷氧基烷基，X'是 2 个或 2 个以上碳原子的亚烷基、a 是 0 至 4 的整数，na 是 0 或 1，nb 是 1 或 2，nc 是 1 或 2，条件是 na+nb+nc=3，n1、n2、n3 和 n4 是 0 或 1 或 1 以上的整数，条件是 n1+n2+n3+n4 是 0 至 450 的整数。
• Polycarbonate, and molding and electrophotograpic photoreceptor prepared therefrom
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1288242A2

  公开（公告）日：2003-03-05

  A polycarbonate containing repeating units (1) represented by the general formula (1), a polycarbonate molding produced by molding the polycarbonate, and an electrophotographic photoreceptor having a photosensitive layer which has a surface layer containing the polycarbonate: wherein R is an aliphatic unsaturation-free monovalent hydrocarbon group, R1 is a halogen atom, an alkyl group, an alkoxy group or an aryl group, X is an alkylene group or an alkyleneoxyalkylene group, X' is an alkylene group of 2 or more carbon atoms, an alkyleneoxyalkylene group or oxygen atom, a is an integer of 0 to 4, na is 0 or 1, nb is 1 or 2, nc is 1 or 2, provided na+nb+nc=3, n1, n2, n3 and n4 are 0 or an integer of 1 or more, provided n1+n2+n3+n4 is an integer of 0 to 450.

  一种含有由通式(1)表示的重复单元(1)的聚碳酸酯，一种通过模塑该聚碳酸酯而制得的聚碳酸酯模塑件，以及一种具有感光层的电子照相感光器，该感光器具有含有该聚碳酸酯的表层： 其中 R 是脂肪族无饱和度单价烃基，R1 是卤素原子、烷基、烷氧基或芳基，X 是亚烷基或亚烷氧基烷基，X'是 2 个或 2 个以上碳原子的亚烷基、a 是 0 至 4 的整数，na 是 0 或 1，nb 是 1 或 2，nc 是 1 或 2，条件是 na+nb+nc=3，n1、n2、n3 和 n4 是 0 或 1 或 1 以上的整数，条件是 n1+n2+n3+n4 是 0 至 450 的整数。