Berezin, B. D.; Daniyarov, D. D.; Askarov, K. A., Russian Journal of Physical Chemistry, 1992, vol. 66, # 6, p. 867 - 870
作者:Berezin, B. D.、Daniyarov, D. D.、Askarov, K. A.、Berezin, M. B.
DOI:——
日期:——
Kinetics of the metal-ligand exchange of cadmium rhodo- and pyrroporphyrins with cobalt and zinc chlorides in organic solvents
作者:B. D. Berezin、S. V. Zvezdina、M. B. Berezin
DOI:10.1134/s0036023613060065
日期:2013.6
Experimental data on electron absorption spectra (EASs) and the kinetics of substitution of Co2+ for the central Cd2+ ion in rhodoporphyrin complexes (CdRodP) in the reaction with CoCl2 in acetonitrile (AN) and ZnCl2 in dimethyl sulfoxide (DMSO) and the substitution of Zn2+ for Cd2+ in pyrroporphyrin complexes (CdPyrP) in the reaction with ZnCl2 in DMSO are reported and discussed. The evolution of EASs in the reaction of metal-ligand exchange and the effective and true rate constants of the exchange reaction are reported. The activation energies and activation entropies are estimated.
Berezin, B. D.; Rashidova, S. T.; Koifman, O. I., Russian Journal of Physical Chemistry, 1984, vol. 58, # 7, p. 1012 - 1015
作者:Berezin, B. D.、Rashidova, S. T.、Koifman, O. I.、Koifman, E. P.、Askarov, K. A.、Enikolopov, N. S.