(98)Mo(17)O2(N,N'-dimethyl-N,N'-bis(2-mercaptophenyl)ethylenediamine(2-)) | 109309-21-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: (98)Mo(17)O2(N,N'-dimethyl-N,N'-bis(2-mercaptophenyl)ethylenediamine(2-))
• CAS: 109309-21-9
• 化学式: C₁₆H₁₈MoN₂O₂S₂
• 分子量: 434.464
• InChiKey: KJIYNWSGVVWACT-RPHDGEGKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (98)Mo(17)O2(N,N'-dimethyl-N,N'-bis(2-mercaptophenyl)ethylenediamine(2-)) 在 H₂O 作用下， 以 四氢呋喃 为溶剂， 生成 cis-(98)MoO(OH)(N,N'-dimethyl-N,N'-bis(2-mercaptophenyl)ethylenediamine(2-))
  参考文献：
  名称：

  Molybdenum(VI) and molybdenum(V) complexes with N,N'-dimethyl-N,N'-bis(2-mercaptophenyl)ethylenediamine. Electrochemical and electron paramagnetic resonance models for the molybdenum(VI/V) centers of the molybdenum hydroxylases and related enzymes

  摘要：

  DOI：

  10.1021/ja00253a016
• 作为产物：
  描述：

  monosodium monomolybdate-98Mo hydrate 、 乙酰丙酮 、 氧-17原子 在 HCl 作用下， 以 水 为溶剂， 生成 (98)Mo(17)O2(N,N'-dimethyl-N,N'-bis(2-mercaptophenyl)ethylenediamine(2-))
  参考文献：
  名称：

  Molybdenum(VI) and molybdenum(V) complexes with N,N'-dimethyl-N,N'-bis(2-mercaptophenyl)ethylenediamine. Electrochemical and electron paramagnetic resonance models for the molybdenum(VI/V) centers of the molybdenum hydroxylases and related enzymes

  摘要：

  DOI：

  10.1021/ja00253a016

文献信息

• Molybdenum(V) sites in xanthine oxidase and relevant analog complexes: comparison of oxygen-17 hyperfine coupling
  作者：Richard J. Greenwood、Graham L. Wilson、John R. Pilbrow、Anthony G. Wedd

  DOI：10.1021/ja00066a005

  日期：1993.6

  Electron paramagnetic resonance at 2-4 and 9 GHz has been used to examine O-17 (I = 5/2) hyperfine coupling in signals from Mo(V) centers in milk xanthine oxidase (Rapid Type 1, Rapid Type 2, Slow) and in the synthetic species [MoOXL]- and [MoO(XH)L] (X = O, S; LH-2 = N,N'-dimethyl-N,N'-bis(2-mercaptophenyl)-1,2-diaminoethane) generated in solution. Comparison of the new 170 data with available H-1, O-17, S-35, and Mo-95 information indicates that three ligands can be defined in each of the Mo(V) centers derived from active enzyme: Very Rapid, [Mo(V)OS(OR)] (OR, product anion); Rapid Type 1 and Type 2, [Mo(V)O(SH)(OH)]. Formulation of the oxidized resting center as fac-[Mo(VI)OS(OH)] allows derivation of a catalytic cycle consistent with known properties of the enzyme.