multistriatin | 60018-96-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: multistriatin
• 英文别名: α-Multistriatin；5-ethyl-2,4-dimethyl-6,8-dioxabicyclo[3.2.1]octane
• CAS: 60018-96-4
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: YMBRJMLOGNZRFY-UHFFFAOYSA-N

物化性质

• 沸点：
  207.1±8.0 °C(Predicted)
• 密度：
  0.959±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-甲基-1-戊烯-3-酮 在 N-甲基吡咯烷酮 、 叔丁基过氧化氢 、 锌 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 190.0 ℃ 、1000.0 MPa 条件下， 反应 106.0h， 生成 multistriatin
  参考文献：
  名称：

  Pheromones of coleoptera Communication 4. Synthesis of multistriatin with the application of the thermal hydroxy-cope rearrangement under high pressure

  摘要：

  DOI：

  10.1007/bf01474218

文献信息

• HETEROCYCLIC COMPOUND, AND HARMFUL-ARTHROPOD-CONTROLLING AGENT CONTAINING SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP3514155A1

  公开（公告）日：2019-07-24

  The present invention relates to a compound represented by Formula (I): in the formula, Q represents a group represented by Formula Q1, Q2, or Q3, and T represents a chain hydrocarbon group, an alkoxyalkyl group, an alkylsulfanylalkyl group, an alkylsulfinylalkyl group, or an alkylsulfonylalkyl group, which has a halogen atom; a cycloalkylalkyl group or a cycloalkyl group, which has a substituent; OR1, S(O)mR1, OS(O)2R1, CH2OR1, NR1R29, C(O)R1, C(O)NR1R29, NR21C(O)R1, N=CR1R30, or a group represented by any one of Formulae T-1 to T-12,

  本发明涉及一种由式（I）表示的化合物： 式中，Q 代表式 Q1、Q2 或 Q3 所代表的基团，T 代表链烃基、烷氧基烷基、烷硫基烷基、烷亚磺酰基烷基或烷磺酰基烷基，其中有一个卤原子；具有取代基的环烷基烷基或环烷基； OR1、S(O)mR1、OS(O)2R1、CH2OR1、NR1R29、C(O)R1、C(O)NR1R29、NR21C(O)R1、N=CR1R30 或由式 T-1 至 T-12 中任何一个所代表的基团、
• HETEROCYCLIC COMPOUND AND COMPOSITION CONTAINING SAME
  申请人：Sumitomo Chemical Company Limited

  公开号：EP3632900A1

  公开（公告）日：2020-04-08

  The present invention provides a heterocyclic compound represented by formula (I): wherein, R2 represents a C1-C6 alkyl group optionally having one or more halogen atoms etc., n is 0 etc., R3 represents a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group B etc., q is 0 etc., Het represents a group represented by the formulae Het 1 or Het 2, A1 represents a nitrogen atom etc., Q2 represents an oxygen atom etc., which has an excellent efficacy for controlling harmful arthropods; an intermediate compound; and a composition comprising the same compound and one or more kinds of ingredients selected from the group consisting of Group (a), Group (b), Group (c), Group (d) and Group (e), each which is described in the Description.

  本发明提供了一种由式 (I) 表示的杂环化合物： 其中，R2代表任选具有一个或多个卤原子等的C1-C6烷基，n为0等，R3代表任选具有一个或多个选自B组等的取代基的C1-C6链烃基，q为0等，Het代表由式Het 1或Het 2代表的基团，A1代表氮原子等、Q2 代表氧原子等，对控制有害节肢动物具有优异功效；中间化合物；以及由相同化合物和一种或多种选自(a)组、(b)组、(c)组、(d)组和(e)组的成分组成的组合物。
• HETEROCYCLIC COMPOUND AND HARMFUL ARTHROPOD CONTROLLING AGENT CONTAINING SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP3689872A1

  公开（公告）日：2020-08-05

  The present invention provides: a compound having an excellent controlling effect against a harmful arthropod and represented by formula (I): and a composition containing the compound, wherein, in formula (I), Q represents a group represented by formula Q1; a group represented by formula Q2 or a group represented by formula Q3; a combination of A2 and A3 represents a combination in which A2 is a nitrogen atom and A3 is CR4b, or a combination in which A2 is CR4a and A3 is a nitrogen atom; Z represents an oxygen atom or a sulfur atom; and T represents a C2-C10 chain hydrocarbon group having one or more halogen atoms, etc.

  本发明提供了：一种对有害节肢动物具有优异防治效果并由式（I）表示的化合物：以及含有该化合物的组合物，其中，在式(I)中，Q代表由式Q1代表的基团；由式Q2代表的基团或由式Q3代表的基团；A2和A3的组合代表A2为氮原子和A3为CR4b的组合，或A2为CR4a和A3为氮原子的组合；Z代表氧原子或硫原子；以及T代表具有一个或多个卤原子的C2-C10链烃基等。
• HETEROCYCLIC COMPOUND AND HARMFUL ARTHROPOD-CONTROLLING AGENT CONTAINING SAME
  申请人：SUMITOMO CHEMICAL COMPANY LIMITED

  公开号：EP3730493A1

  公开（公告）日：2020-10-28

  The present invention provides a compound having an excellent control effect on a harmful arthropod. A compound represented by formula (I) [wherein: A represents a CH or a nitrogen atom; R1 represents a hydrogen atom or a NR2R3; R2 and R3 are identical to or different from each other, and each represent a C1-C6 alkyl group, a hydrogen atom, or the like; and n represents 0, 1, or 2] has an excellent control effect on a harmful arthropod.

  本发明提供了一种对有害节肢动物具有极佳防治效果的化合物。由式（I）代表的化合物 其中 A代表CH或氮原子； R1 代表氢原子或 NR2R3； R2 和 R3 彼此相同或不同，各自代表 C1-C6 烷基、氢原子或类似物；以及 n 代表 0、1 或 2］ 对有害节肢动物具有极佳的防治效果。
• HETEROCYCLIC COMPOUNDS AND NOXIOUS ARTHROPOD CONTROL AGENT CONTAINING SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP3733672A1

  公开（公告）日：2020-11-04

  The present invention provides a compound having an excellent control effect on a harmful arthropod. A compound represented by formula (I) [wherein Q represents a group represented by Q1 or a group represented by Q2; Z represents an oxygen atom or a sulfur atom; A1 represents a nitrogen atom or the like; A2 represents a CR4a or the like; A3 represents a nitrogen atom, a CR4b, or the like; B1 represents a CR1 or the like; B2 represents a nitrogen atom, a CR6b, or the like; B3 represents a nitrogen atom, a CR6c, or the like; R1 represents a C1-C6 chain hydrocarbon group having one or more substituent(s) selected from the group consisting of a cyano group and a halogen atom, or the like; R2 represents a C1-C6 chain hydrocarbon group or the like; R3 represents a C1-C6 chain hydrocarbon group or the like; R4a, R4b, R6b, and R6c are identical to or different from each other, and each represent a hydrogen atom or the like; n represents 0, 1, or 2; and q represents 0, 1, 2, or 3] or an N-oxide compound thereof has an excellent control effect on a harmful arthropod.

  本发明提供了一种对有害节肢动物具有极佳防治效果的化合物。由式（I）代表的化合物 其中 Q 代表 Q1 所代表的基团或 Q2 所代表的基团； Z 代表氧原子或硫原子； A1 代表氮原子或类似物 A2 代表 CR4a 或类似物； A3 代表氮原子、CR4b 或类似物； B1 代表 CR1 或类似物； B2 代表氮原子、CR6b 或类似物； B3 代表氮原子、CR6c 或类似物； R1 代表具有一个或多个取代基的 C1-C6 链烃基，取代基可选自氰基和卤素原子或类似基团； R2 代表 C1-C6 链烃基或类似基团； R3 代表 C1-C6 链烃基或类似基团； R4a、R4b、R6b 和 R6c 彼此相同或不同，各自代表氢原子或类似物； n 代表 0、1 或 2；以及 q 代表 0、1、2 或 3]。 或其 N-氧化物化合物对有害节肢动物有很好的防治效果。