| 1428743-58-1

• 分子结构分类: 有机化合物
• CAS: 1428743-58-1
• 化学式: C₂₆H₂₀N₄NiO₃
• 分子量: 495.16
• InChiKey: ODVSLLDQYUEEES-CLSOAGJSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) acetate tetrahydrate 、 2-((pyridin-2-ylmethyleneamino)methyl)phenol 以 甲醇 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Formation of C C and C O bonds via solvothermal in situ metal–ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands

  摘要：

  Under solvothermal conditions, complexes Ni(HL2) (1) and Ni(L3)center dot MeOH (2 center dot MeOH) (H(3)L2=N-(2-(2-hydroxybenzylideneamino)-1-(2-hydroxyphenyl)-2-(pyridin-2-yl)ethyl)picolinamide; H(2)L3=1-(pyridin-2-yl)prop-1-ene-1,2-diyl)bis(azan-1-yl-1-ylidene)bis((methan-1-yl-1-ylidene)diphenol) have been synthesized from the reaction of Ni(CH3COO)(2)center dot 4H(2)O with 2-((pyridin-2-ylmethyleneamino)methyl)phenol (HL1) at 70 and 90 degrees C, respectively. The complexes were characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. The plausible mechanisms for the formation of H(3)L2 and H(3)L3 via solvothermal in situ metal-ligand reactions were proposed. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.01.026