2-(2-(4-ethoxyphenyl)telluroethyl)-1,3-dioxane | 270914-40-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-(2-(4-ethoxyphenyl)telluroethyl)-1,3-dioxane
• 英文别名: 2-{2-[(4-Ethoxyphenyl)tellanyl]ethyl}-1,3-dioxane；2-[2-(4-ethoxyphenyl)tellanylethyl]-1,3-dioxane
• CAS: 270914-40-4
• 化学式: C₁₄H₂₀O₃Te
• 分子量: 363.911
• InChiKey: QOOPMDKWDDUMKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.99
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  二氯(p-甲基异丙苯)钌(II) 二聚体 、 2-(2-(4-ethoxyphenyl)telluroethyl)-1,3-dioxane 以 氯仿 为溶剂， 以85%的产率得到[RuCl2(p-cymene)(2-(2-(4-ethoxyphenyl)telluroethyl)-1,3-dioxane)]
  参考文献：
  名称：

  2-(4-Ethoxyphenlytelluromethyl)tetrahydro-2H-pyran (L1) and 2-(2-{4-ethoxyphenyl}telluroethyl)-1,3-dioxane (L2): synthesis, reactions of L1 with iodine and ligation of L1 with Ru(II), Cu(I), and Hg(II) and L2 with Ru(II). Crystal structures of [RuCl2(p-cymene)·L1/L2]

  摘要：

  2-(4-Ethoxyphenlytelluromethyl)tetrahydro-2H-pyran (L-1) and 2-(2-{4-ethoxyphenyl}telluroethyl)-1,3-dioxane (L-2) have been synthesized by reacting in situ generated ArTe-Na+ with an appropriate organic halide. The reaction of L-1 with iodine results in its diiodo derivative [L-1(I)(2)] (1). The complexes of stoichiometries [CuBrL1] (2), [HgBr2L1] (3) and [RuCl2(p-cymene)-L-1/L-2] (4/5) are synthesized. The NMR (H-1 and C-13) in conjunction with elemental analyses, molecular weight and conductance measurements were used to characterize L, L 2, 1 and the complexes 2-5. The ligands coordinate in all the complexes through Te, as indicated by the deshielding of CH2Te signals (up to similar to0.8 ppm) with respect to those of free ligands, except in the case of 2 in which bonding through CH2O has also to be invoked. Complexes 4 and 5 are characterized structurally (Ru-Te bond length: 2.619(8) and 2.642(1) Angstrom, respectively). The Ru-Cl bond lengths are in the range 2.404(3)-2.420(6) Angstrom. The Te-C(aryl) bond is shorter than the Te-C(alkyl) bond in 4 but similar in 5. The two Ru(Il) complexes are the first examples with potential (Te, O) ligands of Ar(R)Te type, which have been structurally characterized. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00491-1

文献信息

• 2-(4-Ethoxyphenlytelluromethyl)tetrahydro-2H-pyran (L1) and 2-(2-{4-ethoxyphenyl}telluroethyl)-1,3-dioxane (L2): synthesis, reactions of L1 with iodine and ligation of L1 with Ru(II), Cu(I), and Hg(II) and L2 with Ru(II). Crystal structures of [RuCl2(p-cymene)·L1/L2]
  作者：Ajai K. Singh、M. Kadarkaraisamy、M. Mishra、J. Sooriyakumar、J.E. Drake、M.B. Hursthouse、M.E. Light、Jerry P. Jasinski

  DOI：10.1016/s0020-1693(01)00491-1

  日期：2001.8

  2-(4-Ethoxyphenlytelluromethyl)tetrahydro-2H-pyran (L-1) and 2-(2-4-ethoxyphenyl}telluroethyl)-1,3-dioxane (L-2) have been synthesized by reacting in situ generated ArTe-Na+ with an appropriate organic halide. The reaction of L-1 with iodine results in its diiodo derivative [L-1(I)(2)] (1). The complexes of stoichiometries [CuBrL1] (2), [HgBr2L1] (3) and [RuCl2(p-cymene)-L-1/L-2] (4/5) are synthesized. The NMR (H-1 and C-13) in conjunction with elemental analyses, molecular weight and conductance measurements were used to characterize L, L 2, 1 and the complexes 2-5. The ligands coordinate in all the complexes through Te, as indicated by the deshielding of CH2Te signals (up to similar to0.8 ppm) with respect to those of free ligands, except in the case of 2 in which bonding through CH2O has also to be invoked. Complexes 4 and 5 are characterized structurally (Ru-Te bond length: 2.619(8) and 2.642(1) Angstrom, respectively). The Ru-Cl bond lengths are in the range 2.404(3)-2.420(6) Angstrom. The Te-C(aryl) bond is shorter than the Te-C(alkyl) bond in 4 but similar in 5. The two Ru(Il) complexes are the first examples with potential (Te, O) ligands of Ar(R)Te type, which have been structurally characterized. (C) 2001 Elsevier Science B.V. All rights reserved.