T(p-OCH₃)PPCoCl | 82150-28-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: T(p-OCH₃)PPCoCl
• 英文别名: 5,10,15,20-tetra(4-methoxyphenyl) porphyrinato cobalt chloride；chloro[meso-tetrakis(p-methoxyphenyl)porphyrinato]cobalt(III)；(tetrakis(4-methoxyphenyl)porphyrinato)chlorocobalt(III)；CoT(4-OCH3)PPCl
• CAS: 82150-28-5
• 化学式: C₄₈H₃₆ClCoN₄O₄
• 分子量: 827.284
• InChiKey: LIDBVEKAMFWEGM-HTMHXADGSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  T(p-OCH₃)PPCoCl 、 Na[(tris(pentafluorophenyl)corrole(-3H))Sn^II] 以 苯 为溶剂， 反应 12.0h， 以77%的产率得到
  参考文献：
  名称：

  锡堇-钴卟啉异双金属配合物的热力学和反应性研究†

  摘要：

  合成了异双金属配合物 (TPFC)Sn–Co(TAP) (TPFC = 5,10,15-三(五氟苯基)corrole, TAP = 5,10,15,20-四(对甲氧基苯基)卟啉)。该配合物具有 Sn-Co 键，键解离焓 (BDE) 为 30.2 ± 0.9 kcal mol -1，键解离吉布斯自由能 (BDFE) 为 21.0 ± 0.2 kcal mol -1，经过均裂产生（ TPFC)Sn 自由基和 (TAP)Co II在热或可见光照射下。新的锡自由基（TPFC）Sn是第一个在室温下观察到的四坐标锡自由基，通过光谱和计算进行了研究。(TPFC)Sn-Co(TAP)促进芳基炔烃的低聚反应生成插入产物(TPFC)Sn-(CH C(Ar))n –Co(TAP)（n= 1、2 或 3）以及 1,3,5-三芳基苯。机理研究揭示了一种以（TPFC）Sn自由基为关键中间体的自由基链机制。

  DOI：

  10.1039/c8sc01269e
• 作为产物：
  描述：

  (5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II) 在 盐酸 作用下， 以 氯仿 为溶剂， 生成 T(p-OCH₃)PPCoCl
  参考文献：
  名称：

  Structural studies of metalloporphyrins. 7. Proton NMR and electrochemical investigation of the (meso-5,10,15,20-tetraarylporphine)cobalt(III) complexes XCoIII(TPP-p-R)

  摘要：

  DOI：

  10.1021/ic00139a029

文献信息

• Electronic effects of para-substituents on the electron configuration of dicyano[meso-tetrakis(p-substituted phenyl)porphyrinato]iron(III) complexes
  作者：Akira Ikezaki、Takahisa Ikeue、Mikio Nakamura

  DOI：10.1016/s0020-1693(02)00819-8

  日期：2002.6

  and (dxz, dyz)4(dxy)1, in low spin iron(III) porphyrin complexes. In order to reveal how the electronic effect of substituents affects the electron configuration of low spin iron(III) porphyrin complexes, we have examined the 13C NMR, 1H NMR, and EPR spectra of a series of tetrabutylammonium (dicyano)[meso-tetrakis(p-substituted phenyl)porphyrinato]ferrate(III), [Fe(p-X–TPP)(CN)2]−Bu4N+, in both CD2Cl2

  在低自旋铁（III）卟啉配合物中，有两种类型的电子构型，（d xy）2（d xz，d yz）3和（d xz，d yz）4（d xy）1。为了揭示的取代基的电子效应如何影响低自旋铁（III）卟啉配合物的电子结构，我们已经研究了13 C NMR，1 H NMR，和一系列四丁基铵（二氰基）的EPR谱内消旋-四（对位取代苯基）卟啉铁]高铁酸盐（III），[Fe（对-X–TPP）（CN）2 ] -卜4 Ñ +，在这两个CD 2氯2和CD 3 OD溶液。取决于对位取代基的给电子或吸电子能力，内消旋碳信号的化学位移（在很大程度上反映了低旋铁（III）的电子构型）已发生很大变化。所述的各向同性位移内消旋的α-碳的信号的[Fe（p -X-TPP）（CN）2 ] -卜4 Ñ +是本的基础上确定的内消旋碳上的相应反磁性钴（III）络合物，[CO（的化学位移p -X-TPP）（CN）2 ] -卜4 Ñ +。针对哈米特各向同性位移的曲线σ
• A Green Process for Oxidation of <i>p</i>-Nitrotoluene Catalyzed by Metalloporphyrins under Mild Conditions
  作者：Lanzhi Wang、Yuanbin She、Rugang Zhong、Hongbing Ji、Yanhui Zhang、Xufeng Song

  DOI：10.1021/op060056z

  日期：2006.7.1

  A novel synthetic technology of p-nitrobenzoic acid has been investigated with dioxygen by using metalloporphyrins RTPP-(MCl)-Cl-III (M = Fe, Co, Mn) as biomimetic catalysts. Oxidation of p-nitrotoluene to p-nitrobenzoic acid under 2.0 MPa of O-2 in the presence of a microamount of metalloporphyrins (RTPP-(MCl)-Cl-III) at 55 degrees C was achieved with the highest ( up to 90.4%) yield. Further research results show that the catalytic activities were relative to the nature of the substituted groups and the central metal ions of metalloporphyrins. For the metalloporphyrins with the same center metal ions, the greater the electron-withdrawing degree of groups in the porphyrin ring, the higher the catalytic activities of the metalloporphyrins. The catalytic activities for metalloporphyrins with different center metal ions followed the order RTPPMn Cl-III > RTPP (FeCl)-Cl-III > RTPP (CoCl)-Cl-III.
• Kinetic parameters of the electroreduction of oxygen on a graphitized carbon electrode activated by tetrakis(4-methoxyphenyl)porphyrin and its cobalt complexes
  作者：M. V. Tesakova、A. V. Noskov、M. I. Bazanov、N. M. Berezina、V. I. Parfenyuk

  DOI：10.1134/s0036024411120326

  日期：2012.1

  Electrochemical and electrocatalytic properties of tetrakis(4-methoxyphenyl)porphyrin, tetrakis(4-methoxyphenyl)porphyrinatocobalt(II), and (tetrakis(4-methoxyphenyl)porphyrinato)chlorocobalt(III) are studied using the method of cyclic voltammetry. The redox-potentials of the electrode processes, the potentials of the half-wave and stationary rate constants for electroreduction of molecular oxygen are determined from an analysis of the voltammetric curves. The cobalt complex is found to be characterized by higher electrocatalytic activity than other analyzed compounds.
• PROCESS FOR PREPARING POLYPROPYLENE CARBONATE
  申请人：ENI S.P.A.

  公开号：US20220220253A1

  公开（公告）日：2022-07-14

  There is a process for the preparation of polypropylene carbonate having the step of copolymerization of propylene oxide and carbon dioxide (CO 2 ) in the presence of a catalytic system including: at least one catalyst selected from complexes of a transition metal having general formula (I): at least one co-catalyst selected from: (a) ionic compounds having general formula (II): and (b) ionic compounds having general formula (III)