1H,10H-全氟癸烷 | 3492-24-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 1H,10H-全氟癸烷
• 中文别名: 1H,10H-全氟葵烷
• 英文名称: 1H,10H-Eicosafluor-decan
• 英文别名: α,ω-Dihydro-perfluor-decan；1H,10H-eicosafluoro-decane；1H,10H-Perfluorodecane；1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-icosafluorodecane
• CAS: 3492-24-8
• 化学式: C₁₀H₂F₂₀
• mdl: MFCD00155783
• 分子量: 502.094
• InChiKey: VDMQXMQJUHCJLX-UHFFFAOYSA-N

物化性质

• 熔点：
  42 °C
• 沸点：
  153 °C
• 密度：
  1.653±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  30
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  20

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S23,S24/25
• 海关编码：
  2903399090

反应信息

• 作为产物：
  描述：

  1,10-Bis-methylmercapto-eicosafluor-decan 在 sodium hydroxide 、 双氧水 、 溶剂黄146 作用下， 生成 1H,10H-全氟癸烷
  参考文献：
  名称：

  The Hydrolysis and Oxidation of α,ι-Bis(methylthio)polyfluoroalkanes

  摘要：

  DOI：

  10.1021/jo01020a028

文献信息

• Conformational energies of perfluoroalkanes. 5. Dipole moments of H(CF2)nH and H(CF2)nI
  作者：Keizo Matsuo、Walter H. Stockmayer

  DOI：10.1021/j150622a020

  日期：1981.10
• BLOCK COPOLYMERS FOR DIRECTED SELF-ASSEMBLY APPLICATIONS
  申请人：International Business Machines Corporation

  公开号：US20170114246A1

  公开（公告）日：2017-04-27

  Block copolymers (BCPs) for self-assembly applications comprise a linear fluorinated linking group L′ joining a pair of adjacent blocks. A film layer comprising a BCP, which is disposed on an underlayer and in contact with an atmosphere, is capable of forming a perpendicularly oriented domain pattern when the underlayer is preferentially wetted by one domain of an otherwise identical self-assembled BCP in which all fluorines of L′ are replaced by hydrogen. The BCP can be a low-chi or high-chi BCP. In a preferred embodiment, the BCP comprises a styrene-based first block, and a second block comprises a carbonate and/or ester repeat unit formed by ring opening polymerization of a cyclic carbonate and/or cyclic ester monomer. The linking group L′ has a lower surface energy than each of the polymer blocks.
• HIGH-CHI BLOCK COPOLYMERS FOR INTERCONNECT STRUCTURES BY DIRECTED SELF-ASSEMBLY
  申请人：International Business Machines Corporation

  公开号：US20170294341A1

  公开（公告）日：2017-10-12

  High-chi diblock copolymers are disclosed whose self-assembly properties are suitable for forming hole and bar openings for conductive interconnects in a multi-layered structure. The hole and bar openings have reduced critical dimension, improved uniformity, and improved placement error compared to the industry standard poly(styrene)-b-poly(methyl methacrylate) block copolymer (PS-b-PMMA). The BCPs comprise a poly(styrene) block, which can optionally include repeat units derived from trimethylsilyl styrene, and a second block that can be a polycarbonate block or a polyester block. Block copolymers comprising a fluorinated linking group L′ comprising 1-25 fluorines between the blocks can provide further improvement in uniformity of the openings.
• US9768059B1
  申请人：——

  公开号：US9768059B1

  公开（公告）日：2017-09-19
• The Hydrolysis and Oxidation of α,ι-Bis(methylthio)polyfluoroalkanes
  作者：R. B. Ward

  DOI：10.1021/jo01020a028

  日期：1965.9