4,4'-(tridec-2-ylidene)diphenol | 95872-28-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-(tridec-2-ylidene)diphenol
• 英文别名: 4-[2-(4-Hydroxyphenyl)tridecan-2-yl]phenol
• CAS: 95872-28-9
• 化学式: C₂₅H₃₆O₂
• 分子量: 368.56
• InChiKey: WZBHALGYPYRUNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  27
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4,4'-(tridec-2-ylidene)diphenol 在 palladium on activated charcoal 吡啶 、 bis-triphenylphosphine-palladium(II) chloride 、 氢氧化钾 、 氢气 、 三乙胺 、 lithium chloride 作用下， 以 乙醇 、 乙酸乙酯 、 N,N-二甲基甲酰胺 为溶剂， 25.0~75.0 ℃ 、4.05 MPa 条件下， 反应 51.0h， 生成 4,4'-(tridec-2-ylidene)bis(dihydrocinnamic acid)
  参考文献：
  名称：

  Remarkably Strong, Uncharged Hydrogen-Bonding Interactions of Polypyridine-Macrocyclic Receptors for Deoxyribofuranosides

  摘要：

  Novel macrocyclic saccharide receptors that possess a pyridine-pyridone-pyridine arrangement as a hydrogen-bonding motif are presented. The artificial receptors exhibited a remarkably strong binding affinity for deoxyribofuranoside derivatives in CDCl3 (K-a = 19 000 M-1 -Delta G(298) = 24.4 kJ/mol), one of the highest values of artificial receptors having only uncharged hydrogen-bonding sites for monosaccharide derivatives. Selective extraction of deoxyribose by the receptors was also observed; the extractabilities,;or affinities to the receptors of various pentoses and hexoses, decreased in the following order: deoxyribose > lyxose congruent to ribose > arabinose congruent to fructose congruent to xylose > glucose > mannose > galactose.

  DOI：

  10.1021/ja983539u
• 作为产物：
  描述：

  2-十三烷酮 、 苯酚 在 盐酸 作用下， 反应 168.0h， 以60%的产率得到4,4'-(tridec-2-ylidene)diphenol
  参考文献：
  名称：

  Remarkably Strong, Uncharged Hydrogen-Bonding Interactions of Polypyridine-Macrocyclic Receptors for Deoxyribofuranosides

  摘要：

  Novel macrocyclic saccharide receptors that possess a pyridine-pyridone-pyridine arrangement as a hydrogen-bonding motif are presented. The artificial receptors exhibited a remarkably strong binding affinity for deoxyribofuranoside derivatives in CDCl3 (K-a = 19 000 M-1 -Delta G(298) = 24.4 kJ/mol), one of the highest values of artificial receptors having only uncharged hydrogen-bonding sites for monosaccharide derivatives. Selective extraction of deoxyribose by the receptors was also observed; the extractabilities,;or affinities to the receptors of various pentoses and hexoses, decreased in the following order: deoxyribose > lyxose congruent to ribose > arabinose congruent to fructose congruent to xylose > glucose > mannose > galactose.

  DOI：

  10.1021/ja983539u

文献信息

• Optical parts and sulfur-containing poly (thio)ester (co)polymer
  申请人：——

  公开号：US20030204030A1

  公开（公告）日：2003-10-30

  A poly(thio)ester (co)polymer which comprises a repeating structural unit represented by the formula (1-A) as an essential structural unit: 1 [wherein R 11 is a divalent aliphatic hydrocarbon group which may contain at least one sulfur atom in a sulfide group; R 12 is a mono- or poly-cyclic aliphatic or aromatic dicarboxylic acid residue; and X 11 and X 12 are each independently an oxygen atom or sulfur atom, and when X 11 and X 12 are the oxygen atoms, R 11 is a divalent aliphatic hydrocarbon group containing at least one sulfur atom in the sulfide group]; and an optical component obtainable by molding the poly(thio)ester (co)polymer. The poly(thio)ester (co)polymer is excellent in transparency and optical characteristics (e.g., a higher refractive index, higher Abbe number, and lower birefringence), and has also good mechanical characteristics and thermal characteristics, and further is excellent in melt fluidity and injection moldability.

  一种聚（硫）酯（共）聚合物，其包括由公式（1-A）表示的重复结构单元作为必要的结构单元：1 [其中，R11是一个双价的脂肪族碳氢基团，可以在硫化物基团中含有至少一个硫原子；R12是一个单环或多环的脂肪族或芳香族二羧酸残基；X11和X12分别是氧原子或硫原子，当X11和X12是氧原子时，R11是一个含有至少一个硫原子的双价脂肪族碳氢基团]；以及通过模塑聚（硫）酯（共）聚合物获得的光学组件。该聚（硫）酯（共）聚合物在透明度和光学特性（例如更高的折射率、更高的阿贝数和更低的双折射率）方面表现出色，同时具有良好的机械特性和热特性，并且在熔融流动性和注塑性方面表现出色。
• Thermoplastische aromatische Copolycarbonate, Verfahren zu deren Herstellung aus 2,2-Bis-(4-hydroxyphenyl)-1,1,1,3,3,3,-hexafluorpropan und deren Verwendung
  申请人：Mobay Chemical Corporation

  公开号：EP0029111A1

  公开（公告）日：1981-05-27

  Gegenstand der vorliegenden Erfindung sind neue thermoplastische aromatische Copolycarbonate aus 2,2-Bis-(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluorpropan, ihre Herstellung und ihre Verwendung zur Herstellung von Formkörpern und Folien.

  本发明涉及 2,2-双（4-羟基苯基）-1,1,1,3,3,3-六氟丙烷的新型热塑性芳香族共聚碳酸酯、其生产及其在模塑制品和薄膜生产中的应用。
• Optical component and spirobiindan polymer therefor
  申请人：MITSUI TOATSU CHEMICALS, INCORPORATED

  公开号：EP0822545A2

  公开（公告）日：1998-02-04

  There is provided a low-birefringent organic optical component comprising a polymer prepared by polymerizing a racemic mixture of the monomer with an asymmetric spiro ring represented by general formula (1) as an essential ingredient;    wherein ring A represents a monocyclic or polycyclic organic group, wherein two ring As are mutually bound each other via a spiro bond to form a spiro ring which has a molecular asymmetric structure; n is an integer of 0 to 10; X1 and Y1 are binding groups; Z1 is a polymerization-active group. The component has excellent transparency, mechanical strength and heat resistance, as well as a low birefringence.

  本发明提供了一种低双折射有机光学元件，其包含一种聚合物，该聚合物是通过聚合以通式（1）为代表的不对称螺环为基本成分的单体外消旋混合物而制备的； 其中，环 A 代表单环或多环有机基团，两个环 As 通过螺键相互结合形成具有分子不对称结构的螺环；n 为 0 至 10 的整数；X1 和 Y1 为结合基团；Z1 为聚合活性基团。 该成分具有出色的透明度、机械强度和耐热性，以及较低的双折射。
• A polycarbonate copolymer and applications thereof
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0926180A2

  公开（公告）日：1999-06-30

  A polycarbonate copolymer comprising the repeating structural unit represented by general formula (1-a) and at least one of the repeating structural units represented by general formulas (2-a) and (3-a) is provided. It may be used for optical components.

  提供一种聚碳酸酯共聚物，它包含通式（1-a）所代表的重复结构单元和通式（2-a）和（3-a）所代表的至少一种重复结构单元。 它可用于光学元件。
• DYED MOLDING
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1142938A1

  公开（公告）日：2001-10-10

  The present invention provides a dyed molded article obtained by dyeing a polycarbonate molded article having repeating structural units represented by the following formula (1-a): Since the polycarbonate molded article is dyed easily, the present invention has made it possible to provide a lens made of a dyed polycarbonate.

  本发明提供了一种染色模塑品，它是通过对具有下式（1-a）所代表的重复结构单元的聚碳酸酯模塑品进行染色而得到的： 由于该聚碳酸酯模制品易于染色，因此本发明能够提供由染色聚碳酸酯制成的镜片。