5-(4-(bis(4-(4-(diphenylamino)styryl)phenyl)amino)styryl)furan-2-carbaldehyde | 1402730-39-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 5-(4-(bis(4-(4-(diphenylamino)styryl)phenyl)amino)styryl)furan-2-carbaldehyde
• CAS: 1402730-39-5
• 化学式: C₆₅H₄₉N₃O₂
• 分子量: 904.123
• InChiKey: FQXHSJQKEHDXNW-YQJBTQAPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.01
• 重原子数：
  70.0
• 可旋转键数：
  16.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  39.93
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  5-(4-(bis(4-(4-(diphenylamino)styryl)phenyl)amino)styryl)furan-2-carbaldehyde 、 氰乙酸 在 ammonium acetate 、 溶剂黄146 作用下， 反应 12.0h， 以77%的产率得到(E)-3-(5-((E)-4-(Bis(4-((E)-4-(diphenylamino)styryl)phenyl)amino)styryl)furan-2-yl)-2-cyanoacrylic acid
  参考文献：
  名称：

  Synthesis of dendritic triphenylamine derivatives for dye-sensitized solar cells

  摘要：

  Three new donor-it-acceptor (D-pi-A) metal-free organic dyes, in which dendritic triphenylamine acts as donor, and furan, thiophene and benzene as pi-linkers, were synthesized, characterized and used for the application of dye sensitized solar cell (DSSC). Among the fabricated DSSCs, the device based on the furan as it-linker exhibited a short circuit current density of 14.56 mA cm(-2), an open circuit photo voltage of 0.71 V and a fill factor of 0.59, implying a power conversion efficiency (eta) of 6.10%. The devices sensitized by dyes with thiophene and benzene as it-linker possessed relative lower eta, 5.92% and 4.97%, respectively. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.09.015
• 作为产物：
  描述：

  4-bis{4-[2-(4-(4-diphenylamino)phenyl)vinyl]phenyl}aminobenzaldehyde 在 potassium tert-butylate 、 四丁基溴化铵 、 palladium diacetate 、 potassium carbonate 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 27.0h， 生成 5-(4-(bis(4-(4-(diphenylamino)styryl)phenyl)amino)styryl)furan-2-carbaldehyde
  参考文献：
  名称：

  Synthesis of dendritic triphenylamine derivatives for dye-sensitized solar cells

  摘要：

  Three new donor-it-acceptor (D-pi-A) metal-free organic dyes, in which dendritic triphenylamine acts as donor, and furan, thiophene and benzene as pi-linkers, were synthesized, characterized and used for the application of dye sensitized solar cell (DSSC). Among the fabricated DSSCs, the device based on the furan as it-linker exhibited a short circuit current density of 14.56 mA cm(-2), an open circuit photo voltage of 0.71 V and a fill factor of 0.59, implying a power conversion efficiency (eta) of 6.10%. The devices sensitized by dyes with thiophene and benzene as it-linker possessed relative lower eta, 5.92% and 4.97%, respectively. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.09.015