2,3,6,7-tetraphenylanthracene | 857907-34-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2,3,6,7-tetraphenylanthracene
• CAS: 857907-34-7
• 化学式: C₃₈H₂₆
• 分子量: 482.624
• InChiKey: BSZJMGNPVHNWCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  38
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,3,6,7-tetraphenylanthracene 以 苯 为溶剂， 反应 13.0h， 以55%的产率得到
  参考文献：
  名称：

  Wavelength-Dependent Selectivity in [4 + 4]-Cycloaddition Reactions

  摘要：

  Selective excitation of a variety of anthracene derivatives in the presence of anthracene led to the formation of only the cross-cyclomer products, while irradiating these mixtures at wavelengths where anthracene also absorbs led to both dianthracene and the mixed cyclomers being formed. This method was shown to be general, so long as the chromophore was inert toward forming its homodimer and could be irradiated at wavelengths at which anthracene does not absorb.

  DOI：

  10.1021/jo060838q
• 作为产物：
  描述：

  2,3,6,7-tetraphenylanthraquinone 在 palladium on activated charcoal lithium aluminium tetrahydride 、 三氯化铝 、 氧气 作用下， 以 四氢呋喃 、 xylene 为溶剂， 反应 141.0h， 生成 2,3,6,7-tetraphenylanthracene
  参考文献：
  名称：

  Complementarity in bimolecular photochromism

  摘要：

  在 9,10-二甲基蒽存在的情况下，辐照 2,3,6,7-四苯基蒽会完全形成交叉二聚体。在没有另一种发色团的情况下，辐照这两种发色团中的任何一种，都不会发生光化学反应。

  DOI：

  10.1039/b502183a

文献信息

• Synthesis, photophysical properties and color tuning of highly fluorescent 9,10-disubstituted-2,3,6,7-tetraphenylanthracene
  作者：Sheng-Hsun Lin、Fang-Iy Wu、Rai-Shung Liu

  DOI：10.1039/b912289c

  日期：——

  We report the synthesis of 9,10-disubstituted-2,3,6,7-tetraphenylanthracenes, of which the photophysical properties are altered significantly by the 9,10-functionalities; the emission wavelengths range from 410 to 610 nm with outstanding quantum yields for most fluorophores.

  我们报道了9,10-二取代-2,3,6,7-四苯基蒽的合成，其中9,10-功能基显著改变了其光物理性质；绝大多数荧光体的发射波长范围为410到610纳米，量子产率非常高。
• Steric effects on [4+4]-photocycloaddition reactions between complementary anthracene derivatives
  作者：David Bailey、Nasim Seifi、Vance E. Williams

  DOI：10.1016/j.dyepig.2010.05.016

  日期：2011.6

  peripheral functional groups on the [4+4]-photocycloaddition between substituted anthracene derivatives was examined. The reactivity of 2,3,6,7-tetraphenylanthracene (TPA) with 2-phenylanthracene (PA), 2,9,10-trimethylanthracene (TMA) and 9,10-dimethyl-2,3-diphenylanthracene (DMDPA) was investigated. In all cases, the photodimers were formed in high yield despite the steric bulk of the peripheral substituents

  检查了外围官能团对取代的蒽衍生物之间的[4 + 4]-光环加成反应的空间效应。研究了2,3,6,7-四苯基蒽（TPA）与2-苯基蒽（PA），2,9,10-三甲基蒽（TMA）和9,10-二甲基-2,3-二苯基蒽（DMDPA）的反应性。在所有情况下，尽管周围取代基的空间体积很大，但仍以高收率形成了光二聚体。进一步表明，尽管PA能够形成其同二聚体，但当TPA在301 nm激发时，它会与TPA选择性反应。
• Complementarity in bimolecular photochromism
  作者：David Bailey、Vance E. Williams

  DOI：10.1039/b502183a

  日期：——

  Irradiating 2,3,6,7-tetraphenylanthracene in the presence of 9,10-dimethylanthracene leads to exclusive formation of the cross-dimer. No photochemical reaction is observed when either of these chromophores is irradiated in the absence of the other.

  在 9,10-二甲基蒽存在的情况下，辐照 2,3,6,7-四苯基蒽会完全形成交叉二聚体。在没有另一种发色团的情况下，辐照这两种发色团中的任何一种，都不会发生光化学反应。
• Wavelength-Dependent Selectivity in [4 + 4]-Cycloaddition Reactions
  作者：David Bailey、Vance E. Williams

  DOI：10.1021/jo060838q

  日期：2006.7.1

  Selective excitation of a variety of anthracene derivatives in the presence of anthracene led to the formation of only the cross-cyclomer products, while irradiating these mixtures at wavelengths where anthracene also absorbs led to both dianthracene and the mixed cyclomers being formed. This method was shown to be general, so long as the chromophore was inert toward forming its homodimer and could be irradiated at wavelengths at which anthracene does not absorb.