mer-hydrido-(1-carbonyl-2-oxo-1,2-diphenylethenediyl)tris(trimethylphosphane)cobalt(III) | 210900-98-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: mer-hydrido-(1-carbonyl-2-oxo-1,2-diphenylethenediyl)tris(trimethylphosphane)cobalt(III)
• 英文别名: mer-hydrido(1-carbonyl-2-oxo-1,2-diphenylethenediyl)tris(trimethylphosphine)cobalt(III)；mer-Ph2C3O2Co(H)(PMe3)3；mer-hydrido(1-carbonyl-2-oxo-1,2-diphenylethenyl)tris(trimethylphosphine)cobalt(III)
• CAS: 210900-98-4
• 化学式: C₂₄H₃₈CoO₂P₃
• 分子量: 510.479
• InChiKey: OOZSEOLOHDZAHW-HXTYYFCZSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  mer-hydrido-(1-carbonyl-2-oxo-1,2-diphenylethenediyl)tris(trimethylphosphane)cobalt(III) 、 1,4-双(三甲硅基)-1,3-丁二炔 以 正戊烷 为溶剂， 以36%的产率得到mer-(1-Carbonyl-2-oxo-1,2-diphenylethen-diyl)[(Z)-1-trimethylsilylethinyl-2-trimethylsilylethenyl]tris(trimethylphosphan)cobalt(III)
  参考文献：
  名称：

  Klein, Hans-Friedrich; Li, Xiaoyan; Floerke, Ulrich, Zeitschrift fur Naturforschung, B: Chemical Sciences, 2000, vol. 55, # 8, p. 707 - 717

  摘要：

  DOI：
• 作为产物：
  描述：

  methyltetrakis(trimethylphosphine)cobalt(I) 、 Formyldesoxybenzoin 以 正戊烷 为溶剂， 以77%的产率得到mer-hydrido-(1-carbonyl-2-oxo-1,2-diphenylethenediyl)tris(trimethylphosphane)cobalt(III)
  参考文献：
  名称：

  Klein, Hans-Friedrich; Haller, Stefan; Sun, Hongjian, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1998, vol. 53, # 5-6, p. 587 - 598

  摘要：

  DOI：

文献信息

• Reaction of Acyl(hydrido)cobalt(III) Complexes with (2-Diphenylphosphanyl)phenol and Influence of Chelating Ligands Containing Hard/Soft Donor Atoms on the Stability of Cobalt Complexes
  作者：Hongjian Sun、Xiaoyan Li、Hans-Friedrich Klein、Ulrich Flörke、Hans-Jürgen Haupt

  DOI：10.1021/om0489960

  日期：2005.5.1

  (Acylphenolato)hydridocobalt(III) complexes by reaction with (2-diphenylphosphanyl) phenol deliver (2-diphenylphosphanyl)phenolatocobalt(III) complexes with a 2-acylphenolato chelating ligand as co-ligand (complexes 2, 4−6, and 10−12). Depending on the substituents in the chelating ligands trans/cis-isomers were detected by NMR and IR spectroscopy. Complex 2 was shown by X-ray crystallography to attain

  （Acylphenolato）hydridocobalt（III）配合物通过与（2-二苯基膦基）苯酚递送（2-二苯基膦基）phenolatocobalt（III）配合物用2-acylphenolato螯合配体作为助配位体（复合物2，4 - 6，和10 - 12）。根据螯合配体中的取代基，通过NMR和IR光谱检测反式/顺式异构体。复杂2通过X射线晶体学显示获得八面体结构。在特定条件下，获得了取代的（2-羟甲基）苯酚和（2-二苯基膦基）苯酚-钴（I）配合物。提出了可能的反应途径。将讨论含硬/软供体原子的螯合配体对钴配合物稳定性的影响。
• Formation and Crystal Structure of Stable Five-coordinate Diorgano Cobalt(III) Complexes
  作者：Xiaoyan Li、Hongjian Sun、Hans-Friedrich Klein、Ulrich Flörke

  DOI：10.1002/zaac.200500182

  日期：2005.8

  mer-octahedral complexes(2-carbonyl)(4-Me)(6-tBu)phenolato[C,O]hydridotris(trimethylphosphine)cobalt(III) (1) or -(1-carbonyl)(2-oxo)(1,2-diphenylethene)[C,O]hydridotris(trimethylphosphine)cobalt(III) (2) via formal insertion of propynoic acid ethyl ester into Co-H functions afford pentacoordinate vinylcobalt(III) 3 and 4, respectively, that are diamagnetic and attain a square pyramidal structure as exemplified

  mer-八面体配合物（2-羰基）（4-Me）（6-tBu）苯酚[C，O]氢化三（三甲基膦）钴（III）（1）或 -（1-羰基）（2-氧代）（ 1,2-二苯基乙烯) [C, O] 氢化三 (三甲基膦) 钴 (III) (2) 通过丙炔酸乙酯形式插入 Co-H 官能团，分别提供抗磁性的五配位乙烯基钴 (III) 3 和 4并获得方形金字塔结构，如 3 的 X 射线衍射分析所示。
• Novel stable five-coordinate diorgano cobalt(III) complexes: Formation, structure, and reaction with carbon monoxide
  作者：Xiaoyan Li、Fengli Yu、Hongjian Sun、Haoqing Hou

  DOI：10.1016/j.ica.2006.03.029

  日期：2006.7

  A series of new five-coordinate acyl vinyl cobalt(III) complexes Coeta(1)-C(C CPh)=CHPh}[C(O)-C=C-O]L-2(L=PMe3) (6-10) were prepared via formal insertion of diphenylbutadiyne into Co-H function of mer-octahedral hydrido-acyl(phenolato)-cobalt(III) complexes. The complexes are diamagnetic. One square pyramidal structure of complex 6 was confirmed by X-ray diffraction analysis. These complexes are stable in solid state. In solution, six-coordinate acyl vinyl carbonyl cobalt(III) complex 11 is approved through the reaction of complex 7 with CO and the structure of complex 11 was determined by X-ray method. (c) 2006 Elsevier B.V. All rights reserved.
• Reaction of acyl(hydrido)cobalt(III) complexes with (2-diphenylphosphanyl)thiophenol and the influence of chelating ligands containing hard/soft donor atoms on the stability of cobalt complexes
  作者：Hongjian Sun、Lei She、Shimin Fang、Xiaoyan Li

  DOI：10.1016/j.poly.2007.11.010

  日期：2008.2

  The reaction of acyl(hydrido)cobalt(III) complexes Co-III (O boolean AND C=O)(H)(PMe3)(3) (1-5) with (2-diphenylphosphanyl)thiophenol afforded four types of complexes Co-III (O boolean AND C=O)(P boolean AND S)(PMe3)(2) (6-7), Co-III (O boolean AND C=O)(O boolean AND OHC)(2) (11-15), Co-III (P boolean AND S)(PMe3)(3) (16), and Co-II (P boolean AND S-2)(PMe3) (17). A mechanism for the formation of these complexes is proposed. The influences of chelating ligands containing hard/soft donor atoms on the stability of the cobalt complexes in different oxidation states are discussed with respect to the HSAB concept. (c) 2007 Elsevier Ltd. All rights reserved.