bis(4-azido-2-oxo-2H-chromene-3-carbonyl)sulfide | 1207162-91-1

• 分子结构分类: 有机化合物
• 英文名称: bis(4-azido-2-oxo-2H-chromene-3-carbonyl)sulfide
• CAS: 1207162-91-1
• 化学式: C₂₀H₈N₆O₆S
• 分子量: 460.386
• InChiKey: WPSSQFLQJYPXHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  33.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  192.08
• 氢给体数：
  0.0
• 氢受体数：
  9.0

反应信息

• 作为产物：
  描述：

  4-azido-2-oxo-2H-chromene-3-carbaldehyde 在 ammonium thiocyanate 作用下， 以 四氢呋喃 为溶剂， 反应 7.0h， 以65%的产率得到bis(4-azido-2-oxo-2H-chromene-3-carbonyl)sulfide
  参考文献：
  名称：

  The Behavior of 4-Azidocoumarin-3-carboxaldehyde Towards Certain Sulfur Reagents and Primary Amines

  摘要：

  The behavior of 4-azidocoumarin-3-carboxaldehyde (1) towards certain sulfur reagents such as isothiocyanates (2a-c), thionyl chloride, Lawesson's reagent (LR, 3), and phosphorus pentasulfide as well as towards primary amines such as glycine (4) and towards anthranilic acid (5) was investigated. The structures of the new products were attested by suitable analytical and spectroscopic measurements.

  DOI：

  10.1080/10426500902855133