5-[2-(4-methoxyphenyl)diazen-1-yl]-4-phenyl-N-[2-(triethoxysilyl)ethyl]-1,3-thiazol-2-amine | 1227310-70-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-[2-(4-methoxyphenyl)diazen-1-yl]-4-phenyl-N-[2-(triethoxysilyl)ethyl]-1,3-thiazol-2-amine
• 英文别名: 5-[(4-methoxyphenyl)diazenyl]-4-phenyl-N-(2-triethoxysilylethyl)-1,3-thiazol-2-amine
• CAS: 1227310-70-4
• 化学式: C₂₄H₃₂N₄O₄SSi
• 分子量: 500.694
• InChiKey: NQSLLYJAOJWKOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.69
• 重原子数：
  34
• 可旋转键数：
  14
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  115
• 氢给体数：
  1
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  2-氨基-4-苯基噻唑 、 甲氧苯胺 在 盐酸 、 硫酸 、 sodium nitrite 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 6.0h， 生成 5-[2-(4-methoxyphenyl)diazen-1-yl]-4-phenyl-N-[2-(triethoxysilyl)ethyl]-1,3-thiazol-2-amine
  参考文献：
  名称：

  Sol–gel synthesis of organic–inorganic hybrid materials comprising boehmite, silica, and thiazole dye

  摘要：

  A hybrid material was prepared from a boehmite sol and a thiazole derived azo dye. The thiazole azo dyes were subjected to hydrolytic polycondensation with vinyltriethoxysilane, tetraethoxysilane, and aluminium isopropoxide in different ratios to afford a hybrid of boehmite, silica, and the thiazole heterocycle azo dye. The structures of these hybrid materials were characterized using X-ray diffraction, Fourier-transform infrared analysis, Si-29- and Al-27-nuclear magnetic resonance, ultraviolet-visible absorption spectrophotometry, and an energy-dispersive X-ray spectroscopy. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.01.020

文献信息

• The synthesis of vinyltriethoxysilane-modified heteroaryl thiazole dyes and silica hybrid materials
  作者：Ming-Shien Yen、Chien-Wen Chen

  DOI：10.1016/j.dyepig.2009.12.006

  日期：2010.7

  Hybrid materials composed of tetraethoxysilane and heteroaryl 4-substituent-2-aminothiazoles were prepared. 4-Substituted acetophenone, thiourea and iodide were used to generate the intermediate, 4-substituted-2-aminothiazole, as coupling component, which was then coupled with p-nitroaniline and p-methoxyaniline to yield heteroaryl 4-substitued thiazole azo dyes. The dyes subsequently underwent hydrolytic polycondensation with vinyltriethoxysilane and tetraethoxysilane to yield hybrid, heteroaryl thiazole azo dyes, whose chemical structure was characterized using FT-IR, Si-29 NMR, H-1 NMR and EDS. (C) 2009 Elsevier Ltd. All rights reserved.