manganese glycine sulfate | 52139-31-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: manganese glycine sulfate
• 英文别名: Mn(μ4,η3-sulfate)(μ2-glycine)；2-aminoacetic acid;manganese(2+);sulfate
• CAS: 52139-31-8
• 化学式: C₂H₅NO₂*Mn*O₄S
• 分子量: 226.069
• InChiKey: XBGDMFYRJNSTFN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.31
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  152
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  硫酸锰水合物 、 聚甘氨酸 以 水 为溶剂， 生成 manganese glycine sulfate
  参考文献：
  名称：

  Crystallization and characterization of the compounds Gly·MSO4·mH2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+, Zn2+; m= 0, 3, 5, 6)

  摘要：

  The equilibrium crystallization of complex compounds of the type Gly center dot MSO4 center dot 5H(2)O with a structure derived from those of the crystallized double salts MSO4 center dot xH(2)O, where x = 6, 7 was predicted and proven in the systems Gly-MSO4-H2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+ and Zn2+). It was predicted that stable octahedral complexes [M(H2O)(6)](2+) and trans-[M(H2O)(4)(O-gly)(2)](2+), as well as [SO4](2-) tetrahedra, which were the main building units of the crystallizing Gly center dot MSO4 center dot 5H(2)O compounds (triclinic crystal system, space group P - 1), were predominating in these solutions. The vibrational spectra and the thermal behavior of the Gly center dot MSO4 center dot 5H(2)O compounds (M = Mg2+, Co2+, Zn2+) are in accord with the refined crystal structures. The cobalt compound displays antiferromagnetic behavior whereas the nickel and manganese compounds are ferromagnetic.In the manganese system where MnSO4 center dot H2O (308 K) crystallizes, the only complex compound is the anhydrous Gly center dot MnSO4 with a polymeric type structure (trans-[Mn(SO4)(4)(O-gly)(2)](n)(2-)).A new compound Gly center dot CoSO4 center dot 3H(2)O was found in the cobalt system under unstable equilibrium conditions. Gly center dot CoSO4 center dot 3H(2)O was proven to consist of two types of octahedra, trans-[Co(H2O)(4)(O-gly)(2))(2+) and trans-[Co(H2O)(2)(SO4)(2)(O-gly)(2)](2-), forming a chain structure (monoclinic crystal system, space group P2(1)/c). (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2012.02.068

文献信息

• Glycine-Templated Manganese Sulfate with New Topology and Canted Antiferromagnetism
  作者：Zhehui Weng、Zilu Chen、Fupei Liang

  DOI：10.1021/ic9006444

  日期：2009.9.21

  A new glycine-templated manganese(II) sulfate, (C2NO2H5)MnSO4 (1), has been solvothermally synthesized and characterized crystallographically and magnetically. Crystal data for 1: monoclinic, space group P2(1)/m, a = 4.8884(10) angstrom, b = 7.8676(14) angstrom, c= 8.0252(15) angstrom, beta = 106.524(2)degrees, V = 295.90(10) angstrom(3), Z=2. The glycine bridges Mn-II ions in mu(2) mode and sulfate in eta(3),mu(4) mode. Along the b direction, the neighboring Mn-II ions were bridged to each other by two sulfate ions and one glycine ligand to form a triple-stranded braid. The adjacent braids were connected via the sulfate ions to give a two-dimensional framework with a novel binodal 4,6-connected (3(2);4(2);5(2)) (3(4);4(4);5(4);6(3)) topology. The compound exhibits a spin-canted antiferromagnetic behavior with a weak ferromagnetic transition below 9 K, and the estimated canting angle is 0.13 degrees.
• Crystallization and characterization of the compounds Gly·MSO4·mH2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+, Zn2+; m= 0, 3, 5, 6)
  作者：S. Tepavitcharova、D. Rabadjieva、D. Havlíček、I. Němec、P. Vojtíšek、J. Plocek、Z. Koleva

  DOI：10.1016/j.molstruc.2012.02.068

  日期：2012.6

  The equilibrium crystallization of complex compounds of the type Gly center dot MSO4 center dot 5H(2)O with a structure derived from those of the crystallized double salts MSO4 center dot xH(2)O, where x = 6, 7 was predicted and proven in the systems Gly-MSO4-H2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+ and Zn2+). It was predicted that stable octahedral complexes [M(H2O)(6)](2+) and trans-[M(H2O)(4)(O-gly)(2)](2+), as well as [SO4](2-) tetrahedra, which were the main building units of the crystallizing Gly center dot MSO4 center dot 5H(2)O compounds (triclinic crystal system, space group P - 1), were predominating in these solutions. The vibrational spectra and the thermal behavior of the Gly center dot MSO4 center dot 5H(2)O compounds (M = Mg2+, Co2+, Zn2+) are in accord with the refined crystal structures. The cobalt compound displays antiferromagnetic behavior whereas the nickel and manganese compounds are ferromagnetic.In the manganese system where MnSO4 center dot H2O (308 K) crystallizes, the only complex compound is the anhydrous Gly center dot MnSO4 with a polymeric type structure (trans-[Mn(SO4)(4)(O-gly)(2)](n)(2-)).A new compound Gly center dot CoSO4 center dot 3H(2)O was found in the cobalt system under unstable equilibrium conditions. Gly center dot CoSO4 center dot 3H(2)O was proven to consist of two types of octahedra, trans-[Co(H2O)(4)(O-gly)(2))(2+) and trans-[Co(H2O)(2)(SO4)(2)(O-gly)(2)](2-), forming a chain structure (monoclinic crystal system, space group P2(1)/c). (C) 2012 Elsevier B.V. All rights reserved.