O-新戊烷-S-三苯甲锡烷基黄酸盐 | 143037-51-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: O-新戊烷-S-三苯甲锡烷基黄酸盐
• 英文名称: O-neopentyl S-triphenylstannyl dithiocarbonate
• 英文别名: 2,2-dimethylpropoxymethanedithioate;triphenylstannanylium
• CAS: 143037-51-8
• 化学式: C₂₄H₂₆OS₂Sn
• 分子量: 513.312
• InChiKey: RIKVTIZLQNLEBA-UHFFFAOYSA-M

物化性质

• 熔点：
  93-97 °C
• 沸点：
  516.7±33.0 °C(Predicted)
• 稳定性/保质期：
  遵照规定使用和储存，则不会发生分解。

计算性质

• 辛醇/水分配系数(LogP)：
  4.73
• 重原子数：
  28
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  66.6
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险品标志：
  T,N-T,N
• 安全说明：
  S61
• 危险类别码：
  R50/53

SDS

Name:	o-Neopentyl-s-triphenylstannyl xanthate Material Safety Data Sheet
Synonym:	Non
CAS:	143037-51-8

Section 1 - Chemical Product MSDS Name:o-Neopentyl-s-triphenylstannyl xanthate Material Safety Data Sheet
Synonym:Non

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
143037-51-8	O-Neopentyl-S-triphenylstannyl xanthat	100	unlisted

Hazard Symbols: T N
Risk Phrases: 23/24/25 50/53

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.The toxicological properties of this material have not been fully investigated.Stench.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be absorbed through the skin in harmful amounts.
Ingestion:
May cause irritation of the digestive tract. Poison by ingestion.
The toxicological properties of this substance have not been fully investigated.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Toxic if inhaled.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Use only under a chemical fume hood.
Exposure Limits CAS# 143037-51-8: United Kingdom, WEL - TWA: (listed as tin organic compounds): 0.1 mg/m3 TWA (except cyhexatin, as Sn) United Kingdom, WEL - STEL: (listed as tin organic compounds): 0.
mg/m3 STEL (except cyhexatin, as Sn) United States OSHA: 0.1 mg/m3 TWA (as Sn) (listed under Tin orga compounds).
Belgium - TWA: (listed as tin organic compounds): 0.1 mg/m3 VLE ( Sn) Belgium - STEL: (listed as tin organic compounds): 0.2 mg/m3 VLE Sn) France - VME: (listed as tin organic compounds): 0.1 mg/m3 VME (a Sn) France - VLE: (listed as tin organic compounds): 0.2 mg/m3 VLE (a Sn) Germany: (listed as tin organic compounds): 0.1 mg/m3 VME (as Sn) Germany: (listed as tin organic compounds): Skin absorber Malaysia: (listed as tin organic compounds): 0.1 mg/m3 TWA (as Sn Netherlands: (listed as tin organic compounds): 0.2 mg/m3 STEL (a Sn) Netherlands: (listed as tin organic compounds): 0.1 mg/m3 MAC (as Spain: (listed as tin organic compounds): 0.1 mg/m3 VLA-ED (as Sn Spain: (listed as tin organic compounds): 0.2 mg/m3 VLA-EC (as Sn Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: yellow
Odor: Stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 94 - 95 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C24H26OS2Sn
Molecular Weight: 513.30

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 143037-51-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
O-Neopentyl-S-triphenylstannyl xanthate - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: ORGANOTIN COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 3146
Packing Group: III
IMO
Shipping Name: ORGANOTIN COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 3146
Packing Group: III
RID/ADR
Shipping Name: ORGANOTIN COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 3146
Packing group: III

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28 After contact with skin, wash immediately
with...
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 143037-51-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 143037-51-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 143037-51-8 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  5-chloro-7-iodo-8-allyloxyquinoline 、 O-新戊烷-S-三苯甲锡烷基黄酸盐 在 六苯基二锡 作用下， 以 环己烷 为溶剂， 反应 8.0h， 以63%的产率得到O-(2,2-dimethylpropyl) (5-chloro-2,3-dihydrofuro[3,2-h]quinolin-3-yl)methylsulfanylmethanethioate
  参考文献：
  名称：

  Novel radical chain reactions based on O-alkyl tin dithiocarbonates

  摘要：

  DOI：

  10.1021/ja00046a045
• 作为产物：
  描述：

  O-neopentyl S-tributylstannyl dithiocarbonate 、 六苯基二锡 在 对甲氧基苯乙酮 作用下， 以 苯 为溶剂， 生成 O-新戊烷-S-三苯甲锡烷基黄酸盐
  参考文献：
  名称：

  Crich, David; Beckwith, Athelstan L. J.; Chen, Chen, Journal of the American Chemical Society, 1995, vol. 117, # 34, p. 8757 - 8768

  摘要：

  DOI：

文献信息

• Crich, David; Beckwith, Athelstan L. J.; Chen, Chen, Journal of the American Chemical Society, 1995, vol. 117, # 34, p. 8757 - 8768
  作者：Crich, David、Beckwith, Athelstan L. J.、Chen, Chen、Yao, Qingwei、Davison, Ian G. E.、Longmore, Robert W.、De Parrodi, Cecilia Anaya、Quintero-Cortes, Leticia、Sandoval-Ramirez, Jésus

  DOI：——

  日期：——
• Novel radical chain reactions based on O-alkyl tin dithiocarbonates
  作者：Jean Boivin、Jose Camara、Samir Z. Zard

  DOI：10.1021/ja00046a045

  日期：1992.9