p-[(pent-4-enyl)oxy]aniline hydrochloride | 1404455-74-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: p-[(pent-4-enyl)oxy]aniline hydrochloride
• CAS: 1404455-74-8
• 化学式: C₁₁H₁₅NO*ClH
• 分子量: 213.707
• InChiKey: NZHLLXVWTSTZGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.04
• 重原子数：
  14.0
• 可旋转键数：
  5.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  35.25
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  p-[(pent-4-enyl)oxy]aniline hydrochloride 、 2-hydroxy-3-(1-methyl-1-phenylethyl)benzaldehyde 在 三乙胺 作用下， 以 甲醇 、 二氯甲烷 、 甲苯 为溶剂， 反应 24.0h， 生成 bis[2-{[4-(pent-4-enyloxy)phenylimino]methyl}-6-(2-phenylpropan-2-yl)phenoxy]titanium(IV) dichloride
  参考文献：
  名称：

  基于各种苯氧基亚胺钛卤化物配合物的乙烯聚合自固定催化剂

  摘要：

  研究了乙烯在十种甲基铝氧烷活化的自固定化双(苯氧基亚胺)配合物上的乙烯聚合动力学特征，该络合物具有各种结构的含氧烯丙基官能团。该系统的催化活性在 20-60°C 的温度范围内和 0.4 MPa 的乙烯压力下测定。配合物的氧烯丙基和苯氧基中的取代基的位置和结构显着改变了基于这些配合物的催化体系的活性、催化剂在聚合物上的自固定速率以及分子量和分子量所得聚乙烯的分布。

  DOI：

  10.1007/s11172-012-0116-4

文献信息

• Multicentered self-immobilized ethylene polymerization catalysts based on functionalized titanium halide salicylaldiminate complexes for the synthesis of ultra-high-molecular-weight polyethylene
  作者：N. I. Ivancheva、S. Ya. Khaikin、E. V. Sviridova、S. P. Fedorov、D. V. Sanieva、O. V. Molev、I. V. Oleinik、S. S. Ivanchev

  DOI：10.1134/s1070427212090170

  日期：2012.9

  Specific features of ethylene polymerization using a new group of catalytic systems based on ten methylalumoxane-activated titanium halide salicylaldiminato complexes functionalized with omega-vinylalkoxy groups and containing tert-butyl substituents in the phenoxide moiety were studied. The catalytic activity of the new group of activated complexes is strongly affected by the position of the omega-vinylalkoxy functional group and by the number and position of substituents in the phenoxide moiety. These factors determine the ratio of the homogeneous and heterogeneous steps of the polymerization as a result of the catalyst self-immobilization onto the polymer formed, and also the molecular characteristics of the polymer obtained at 20, 40, and 60 degrees C and ethylene pressure of 0.4 MPa. The possibility and conditions of preparing ultra-high-molecular-weight polyethylene with improved morphology were revealed.